全文获取类型
收费全文 | 64080篇 |
免费 | 5628篇 |
国内免费 | 11414篇 |
专业分类
化学 | 45757篇 |
晶体学 | 1867篇 |
力学 | 634篇 |
综合类 | 418篇 |
数学 | 3311篇 |
物理学 | 13069篇 |
综合类 | 16066篇 |
出版年
2024年 | 185篇 |
2023年 | 1021篇 |
2022年 | 1925篇 |
2021年 | 1935篇 |
2020年 | 1981篇 |
2019年 | 1812篇 |
2018年 | 1534篇 |
2017年 | 1965篇 |
2016年 | 2107篇 |
2015年 | 1967篇 |
2014年 | 2706篇 |
2013年 | 5018篇 |
2012年 | 3969篇 |
2011年 | 4314篇 |
2010年 | 3721篇 |
2009年 | 4443篇 |
2008年 | 4264篇 |
2007年 | 4635篇 |
2006年 | 4294篇 |
2005年 | 3725篇 |
2004年 | 3511篇 |
2003年 | 2973篇 |
2002年 | 2463篇 |
2001年 | 2020篇 |
2000年 | 1896篇 |
1999年 | 1619篇 |
1998年 | 1269篇 |
1997年 | 1141篇 |
1996年 | 969篇 |
1995年 | 950篇 |
1994年 | 851篇 |
1993年 | 714篇 |
1992年 | 678篇 |
1991年 | 538篇 |
1990年 | 377篇 |
1989年 | 331篇 |
1988年 | 266篇 |
1987年 | 182篇 |
1986年 | 122篇 |
1985年 | 116篇 |
1984年 | 92篇 |
1983年 | 36篇 |
1982年 | 65篇 |
1981年 | 91篇 |
1980年 | 65篇 |
1979年 | 67篇 |
1978年 | 44篇 |
1977年 | 50篇 |
1976年 | 30篇 |
1973年 | 31篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
131.
Styrene (STY) is now produced industrially in fairly large quantities by the dehydrogenation of ethylbenzene (EB) using promoted iron oxide catalyst with superheated steam.In this case, small amount of carbon dioxide formed as a by-product was known to inhibit the catalytic activity of commercial catalyst. Recently, there have been some reports which carbon dioxide showed positive effects to promote catalytic activities on the reaction over several catalysts.In this study, we attempted to combine the dehydrogenation of EB to STY with the carbon dioxide shift-reaction. The combine reaction (EB + CO2 → STY + H2O + CO) can be considered as one of the ways of using CO2 resources and can yield simultaneously STY and Carbon oxide.Alumina oxide catalysts such as Al2O3, Na2O/Al2O3 and K2O/Al2O3 were prepared by the usual impregnation method with an aqueous solution of NaNO3 and KNO3, and then calcined at 650℃ for 5 h in a stream of air. The reaction condition is 600℃, flow of CO2 38ml/mon and space velocity (EB) 1.28h-1. 相似文献
132.
The catalytic activities of SO42-/TiO2-MoO3 in synthesizing cyclohexanone ethylene ketal,cyclohexanone 1,2-propanediol ketal, 2-propyl-1,3-dioxolane, 4-methyl-2-isopropyl-1,3-dioxolane,2-isopropyl-1,3-dioxolane, 4-methyl-2-isopropyl-1,3-dioxolane, butanone ethy-lene ketal and butanone 1,2-propanediol ketal were reported. It has been demonstrated that SO42-/TiO2-MoO3 is an excellent catalyst. Various factors concerned in this reaction have been investigated. The optimum conditions have been found, that is, the molar ratio of aldehyde/ketone to alcohol was 1:1.5 or 1:1.3,the mass ratio of the catalyst used to the reactants was 0.25~1.5%, and the reaction time was 45~60 min. Under this conditions, the yield of cyclohexanone ethylene ketal is 82.7%, cyclohexanone 1,2-propanediol ketal is 83.4%, the yield of 2-propyl-1,3-dioxolane is 68.1%,4-methyl-2-isopropyl-1,3-dioxolane is 87.5%, the yield of 2-isopropyl-1,3-dioxolane is 70.7%,4-methyl-2-isopropyl-1,3-dioxolane is 82.5%, the yield of butanone ethylene ketal is 74.1%, and butanone 1,2-propanediol ketal is 94.9%.Some equation and experiment results concerned of the synthetic acetals or ketals were listed as follows. 相似文献
133.
2H-1,2,3-Diazaphospholes 3a-3h were prepared from various ketone acylhydrazones and phosphorus trichloride in the presence of triethylamine. Compounds 3 underwent feasible hetero-Diels-Alder reactions with cyclopentadiene to afford the respective anellated [1,2,3]diazaphospholes 4a--4d as well as 4a‘--4d‘ in moderate yields. The endo rule in the reaction was observed under kinetic control conditions. 相似文献
134.
JiangMinCHEN LuLingWU XianHUANG 《中国化学快报》2004,15(2):143-144
2,5-Disubstituted oxazoles were prepared conveniently by treatment of aromatic α-methyl ketones and nitriles with poly[styrene(iodosodiacetate)] in one-pot process. 相似文献
135.
Ri Cheng XUAN* Wei Xiao HU Zhong Yu YANG Ya Ping LU College of Pharmaceutical Sciences Zhejiang University of Technology Hangzhou 《中国化学快报》2004,(2)
2-Chloro-5-methylpyridine is an important intermediate for the preparation of biological active compounds, especially insecticides1, e.g. imidacloprid2, and is usually manufac- tured from 3-methylpyridine N-oxide. However, the manufacturing process also forms the by-products: 3-methylpyridine and its isomer 2-chloro-3-methylpyridine3. The pro- perties of the isomers are similar, it is difficult to separate by ordinary methods, such as distillation. Scheme 1 79.4%13.6%5.2%NClCH3NCH3ClNC… 相似文献
136.
FengSHI HongYangLI XiaoJunPENG RongZHANG XiaoQiangCHEN JiangLiFAN LiChengSUN 《中国化学快报》2004,15(12):1407-1410
As photosensitizer for solar cell, a new ruthenium (Ⅱ) complex with four ester groups had been synthesized, in which a phenol substituted by {[(2-hydroxy-5-tert-butylbenzyl)(pyridyl-2-methyl)amino]methyl} is covalently linked to ruthenium (Ⅱ) tris-bipyridine. The structures of the new compounds were confirmed by NMR and ESI-MS spectra. The electrochemical and photochemical properties were also studied. 相似文献
137.
The First Intramolecular Charge Transfer Transition Based on 2-Ureido-4[1H]-pyrimidinone Binding Module 总被引:1,自引:0,他引:1
The first intramolecular charge transfer transition based on 2-ureido-4[1H]-pyrimidinone binding module was reported. 相似文献
138.
In this note we show how 1-factors in the middle two layers of the discrete cube can be used to construct 2-factors in the
Odd graph (the Kneser graph of (k − 1)-sets from a (2k − 1)-set). In particular, we use the lexical matchings of Kierstead and Trotter, and the modular matchings of Duffus, Kierstead
and Snevily, to give explicit constructions of two different 2-factorisations of the Odd graph.
This revised version was published online in September 2006 with corrections to the Cover Date. 相似文献
139.
多小波子空间上的单小波表示 总被引:1,自引:0,他引:1
本文在较弱的条件下,建立了2重多小波子空间与单小波子空间的关系.即由2重多小波构造出单小波.一方面,这种单小波的平移伸缩与2重多小波的平移伸缩生成的子空间是完全相同的;另一方面,它具有插值性.因此通过构造出的单小波建立了多小波子空间上的Shannon型采样定理. 相似文献
140.
本文通过研究匹配问题的实例空间,匈牙利算法和解空间三者之间的关系,指出S实例空间的数目与问题复杂度之间的关系既不是充分也不是必要的,而如何对问题的解空间进行合理的分解才能是问题的关键。 相似文献