High‐performance liquid chromatographic enantioseparation of (RS)‐bupropion using isothiocyanate‐based chiral derivatizing reagents

A high‐performance liquid chromatographic (HPLC) method for enantioseparation of bupropion was developed using two isothiocyanate‐based chiral derivatizing reagents, (S)‐1‐(1‐naphthyl) ethyl isothiocyanate, (S)‐NEIT, and (R)‐α‐methyl benzyl isothiocyanate, (R)‐MBIT. The diastereomers synthesized with (S)‐NEIT were enantioseparated by reversed‐phase HPLC using gradient elution with mobile phase containing water and acetonitrile, whereas diastereomers synthesized with (R)‐MBIT were enantioseparated using triethyl amine phosphate buffer and methanol. Derivatization conditions were optimized and the method was validated for accuracy, precision and limit of detection. The limit of detection was found to be 0.040–0.043 µg/mL for each of the diastereomers prepared with (S)‐NEIT. Copyright © 2013 John Wiley & Sons, Ltd.     

Application of Non-Destructive X-Ray Fluorescence Spectrometry to the Analysis of Suspended Matter in Sea Water

Abstract

In the framework of remote sensing studies concerning coastal transport of pollution in the Northern Adriatic Sea, a method has been developed for the quantitative determination of sulphur, iron, titanium, calcium, phosphorus, silicon, aluminium, magnesium in suspended matter of sea water.

The suspended material was collected by filtering on millipore membrane filters with pore width of 0.45 μ and directly analysed by X-ray spectroscopy. For calibration dried solution and particulate standard samples were used. Limits of sensitivity and precision of the method are reported.

Correlations between the concentration of these elements and the total suspended matter/chlorophyll are discussed.

The aim is to study the geochemical composition of particulate matter and its variations within the geographical site of the sea basin and the seasonal conditions. The approach is to consider aluminium and the other elements normalized on Al. On the basis of a matrix correlation analyses of some sets of data chosen in the restricted area for investigation, some hypothesis on superficial distribution of clay, carbonate, iron hydrous oxides and other mineral detrites, are taken into account. The results confirm the complex situation existing in the offshore area of the Venice lagoon from a geochemical point of view.

The suspended matter seem to be argillaceous in the Southern part of the investigated area and semi-argillaceous with hydrous oxides and carbonates in the Northern part which is influenced by the Piave river.     

基于非同步替代光谱定标的地表下垫面影响分析

对760nm附近的氧气吸收带,选用植被、枯萎植被、人工地物、沙地和雪地五种典型地表类型,基于模拟数据进行非同步替代光谱定标方法的误差分析,比较不同地表类型得到的光谱定标准确度,为高光谱成像仪的非同步替代光谱定标提供定标图像选择策略.结果表明:运用两种光谱匹配方法——光谱角度匹配和欧氏距离法得到的定标误差基本一致;730~800nm的地表反射率曲线标准差在0.05nm以内时,定标误差集中在±0.5nm范围内;人工地物类型中个别地物如橄榄绿光泽涂料和植被大面积覆盖的图像数据不适合用于非同步替代光谱定标.     

基于ARM的可编程数显表的设计

以ARM微控制器LPC 1114为核心,设计了一种可编程多功能测控数显表。通过按键可设置参数,以适应不同的工作情况和使用要求。该数显表可对输入直流电压、电流标准信号进行采样;采用热电阻或热电偶测温;可设置上下限过温报警;带有MODBUS协议的RS 485通信接口。与传统数显表相比,该数显表可一表多用,测量精度高,工作可靠。     

基于MCU的三相功率检测设计

针对目前越来越多的地方需要测出工作机的功率的情况下,本文介绍了一种基于MCU的三相功率检测的方法,运用该原理设计出一个用于检测三相电的电功率的系统。该系统具有高精度、适用范围广、能够适合多种环境等特点。     

CAN总线在石化仪表通讯改造中的应用

介绍了石油化工领域的通讯总线的现状,提出了应用CAN总线进行工业化现场总线改造的方案,并结合CAN总线优点对其进行分析,对其应用发展前景做出了展望。     

"3 S"集成及其应用

介绍了“3S”（RS,GIS,GPS）技术的内容、发展历史与动态;根据深度、广度和同步性三个标准详细地论述了“3S”集成的确切含义和各种集成模式对应的实现方式之间的差异;阐述广度标准下的四种集成方式（RS与GIS,GIS与GPS,RS与GPS,GIS与RS和GPS）的特点和主要应用领域;论证“3S”集成应用的本质是提供不同层次的空间信息服务,并提出多学科协同配合研究“3S”集成的思路。     

基于GIS和RS技术的集约与节约利用土地研究

介绍了基于GIS和RS技术的土地集约与节约利用研究,根据城市土地利用现实情况及其发展趋势,分析土地集约利用潜力评价信息系统。     

地理信息/地理信息空间系统在全球经济应用中的关键问题

地理空间信息系统和遥感技术是全球经济的两大主要技术.其应用者不再限制在科学研究和政府服务中.地理信息系统被广泛应用在以下领域:市场开发、场地选择、零售商业、金融和银行业、房地产业等等.遥感被应用到保险业务、风险管理、精密农业等等.所有这些应用都发生在全球经济的背景下.全球经济的主要趋势在供货连锁管理方面得以体现出来.一些问题很关键,即教育问题、法律问题、政策与安全问题和经济问题.本文将根据高等教育的历史发展和源于供货连锁管理的原则进一步探讨教育问题.