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71.
72.
A new phase of ‘organic-inorganic’ composite system, polypyrrole polyantimonic acid, prepared by mixing the inorganic precipitate of hydrated antimony oxide with organic conducting polymer i.e., polypyrrole, providing a novel granular form hybrid cation-exchanger suitable for column operation with better chemical and thermal stability, good ion-exchange capacity, reproducibility and selectivity for heavy metals. The physicochemical properties of this material were studied using elemental analyses, AAS, SEM, XRD, FTIR and simultaneous TGA-DTA studies. Ion-exchange capacity, pH-titrations, elution and distribution behavior were also carried out to characterize the material. Distribution studies revealed the cation-exchange material to be highly selective for Hg(II) and its selectivity was performed by achieving some important binary separations like Hg2+-Zn2+, Hg2+-Ni2+, Hg2+-Cu2+, Hg2+-Fe3+, Hg2+-Cd2+, Hg2+-Mg2+ etc. on its column. Using this electroactive composite material, a new heterogeneous precipitate based selective ion-sensitive membrane electrode was fabricated for the determination of Hg(II) ions in solutions. The membrane electrode is mechanically stable, with a quick response time, and can be operated within a wide pH range. The selectivity coefficients for different cations determined by mixed solution method were found to be less than unity The electrode was also found to be satisfactory in electrometric titrations. 相似文献
73.
Synthesis, characterization and thermal properties of novel epoxy containing silicon and phosphorus nanocomposites by sol-gel method 总被引:3,自引:0,他引:3
Organic-inorganic hybrids were prepared using diglycidyl ether of bisphenol A (DGEBA) type epoxy and tetraethoxysilane via the sol-gel process. The DGEBA type epoxy was modified by a coupling agent to improve the compatibility of the organic and inorganic phases. The sol-gel technique was used successfully to incorporate silicon and phosphorus into the network of hybrids increasing flame retardance.Fourier transform infrared spectroscopy and 29Si nuclear magnetic resonance spectroscopy were used to characterize the structure of the hybrids. In condensed siloxane species for TEOS, silicon atoms through mono-, di-, tri-, and tetra-substituted siloxane bonds are designated as Q1, Q2, Q3, Q4, respectively. For 3-isocyanatopropyltriethoxysilane and diethylphosphatoethyltriethoxysilane, mono-, di-, tri-, tetra-substituted siloxane bonds are designated as T1, T2, T3. Results revealed that Q4, Q3, T3 are the major environments forming a network structure. The morphology of the ceramer was examined by scanning electron microscopy and Si mapping. Particle sizes were below 100 nm. The hybrids were nanocomposites. The char yield of pure epoxy resin was 14.8 wt.% and that of modified epoxy nanocomposite was 31 wt.% at 800 °C. A higher char yield enhances the flame retardance. Values of limiting oxygen index of pure epoxy and modified epoxy nanocomposites are 24 and 32, respectively, indicating that modified epoxy nanocomposites possess better flame retardance than the pure epoxy resin. 相似文献
74.
Ke Tao Hongjing Dou Kang Sun 《Colloids and surfaces. A, Physicochemical and engineering aspects》2006,290(1-3):70-76
Dextran-Fe3O4 hybrid clusters were fabricated by coprecipitating ferric and ferrous ions in the presence of dextran, and after characterization of these clusters combined with calculation based on classical nucleation theory, a structure model of these hybrid clusters was proposed. The hybrid cluster was believed including small Fe3O4 nanoparticles and dextran which acted as both nucleating agent and stabilizer, so that exist in both the inside of magnetite nanoparticles and the periphery of the hybrid clusters. Besides, the effects of WCD (weightiron cation:weightdextran) and molecular weight of dextran on the size, morphology and magnetic property of clusters were also investigated in this paper. It was found that the variation of WCD and molecular weight of dextran have great effect on the size of the hybrid clusters, but have almost no effect on the size of the Fe3O4 nanoparticles. The characterization of magnetic property demonstrated that the Fe3O4 nanoparticles are of a single domain and the saturation magnetization was affected by the size of dextran-Fe3O4 hybrid clusters. 相似文献
75.
Mohamed Ali Saada Annie Hémon-Ribaud Vincent Maisonneuve 《Journal of fluorine chemistry》2005,126(7):1072-1077
Tren amine cations [(C2H4NH3)3N]3+ and zirconate or tantalate anions adopt a ternary symmetry in two hydrates, [H3tren]2·(ZrF7)2·9H2O and [H3tren]6·(ZrF7)2·(TaOF6)4·3H2O, which crystallise in R32 space group with aH = 8.871 (2) Å, cH = 38.16 (1) Å and aH = 8.758 (2) Å, cH = 30.112 (9) Å, respectively. Similar [H3tren]2·(MX7)2·H2O (M = Zr, Ta; X = F, O) sheets are found in both structures; they are separated by a water layer (Ow(2)-Ow(3)) in [H3tren]2·(ZrF7)2·9H2O. Dehydration of [H3tren]2·(ZrF7)2·9H2O starts at room temperature and ends at 90 °C to give [H3tren]2·(ZrF7)2·H2O. [H3tren]2·(ZrF7)2·H2O layers remain probably unchanged during this dehydration and the existence of one intermediate [H3tren]2·(ZrF7)2·3H2O hydrate is assumed. Ow(1) molecules are tightly hydrogen bonded with -NH3+ groups and decomposition of [H3tren]2·(ZrF7)2·H2O occurs from 210 °C to 500 °C to give successively [H3tren]2·(ZrF6)·(Zr2F12) (285 °C), an intermediate unknown phase (320 °C) and ZrF4. 相似文献
76.
基于MATCOM的Visual C++与Matlab混合编程方法 总被引:3,自引:0,他引:3
郦丹芸 《阜阳师范学院学报(自然科学版)》2003,20(1):58-60
本文首先分析了工程设计和系统仿真软件包Matlab的优缺点,然后介绍一种将Matlab与C++结合的辅助工具—Matcom。Matcom可以将Matlab的M文件转换为CPP文件,为C++程序所使用,并能通过C++编译器编译连接成可执行文件,提高M文件的执行效率。最后用具体实例说明如何通过Matcom实现Matlab与visual C++的混合编程。 相似文献
77.
丁跃平 《贵州师范大学学报(自然科学版)》1997,15(2):57-60
采用适于计算镧系化合物的量子化学INDO方法,通过建立模型分子时镧-乙酰丙酮配合物进行了量化计算,计算结果能很好地解释配合物的晶体结构,同时对标题化合物的电子结构和化学键性质进行了讨论 相似文献
78.
R(G)=-1图的伴随唯一性 总被引:2,自引:0,他引:2
赵海兴 《青海师范大学学报(自然科学版)》1997,(4)
用R(G)表示G的特征标,本文证明了若干类R(G)=-1且p(G)≥q(G)的伴随唯一性。 相似文献
79.
石川 《宝鸡文理学院学报(自然科学版)》1996,16(2):1-6,13
本文在Menger概率度量空间中提出混合不动点概念,研究了集值映象序列的公共混合不动点定理,所得结果改进和推广了近期相关的重要结果。 相似文献
80.
任韩 《广西师范学院学报(自然科学版)》1996,(Z1)
设G是一个k-连通非Hamilton图.C是最长圈,H是G\C的分支。记yi∈NC+(H),1≤i≤k。有.由它可推出一组大次和充分条件。 相似文献