全文获取类型
收费全文 | 4972篇 |
免费 | 326篇 |
国内免费 | 309篇 |
专业分类
化学 | 400篇 |
晶体学 | 7篇 |
力学 | 123篇 |
综合类 | 39篇 |
数学 | 119篇 |
物理学 | 422篇 |
综合类 | 4497篇 |
出版年
2024年 | 28篇 |
2023年 | 82篇 |
2022年 | 105篇 |
2021年 | 124篇 |
2020年 | 93篇 |
2019年 | 83篇 |
2018年 | 82篇 |
2017年 | 146篇 |
2016年 | 159篇 |
2015年 | 224篇 |
2014年 | 244篇 |
2013年 | 235篇 |
2012年 | 270篇 |
2011年 | 306篇 |
2010年 | 229篇 |
2009年 | 214篇 |
2008年 | 244篇 |
2007年 | 306篇 |
2006年 | 288篇 |
2005年 | 263篇 |
2004年 | 240篇 |
2003年 | 216篇 |
2002年 | 208篇 |
2001年 | 181篇 |
2000年 | 144篇 |
1999年 | 141篇 |
1998年 | 98篇 |
1997年 | 107篇 |
1996年 | 96篇 |
1995年 | 78篇 |
1994年 | 58篇 |
1993年 | 69篇 |
1992年 | 49篇 |
1991年 | 46篇 |
1990年 | 49篇 |
1989年 | 38篇 |
1988年 | 23篇 |
1987年 | 18篇 |
1986年 | 10篇 |
1985年 | 1篇 |
1984年 | 1篇 |
1983年 | 1篇 |
1982年 | 2篇 |
1981年 | 1篇 |
1979年 | 3篇 |
1975年 | 1篇 |
1966年 | 1篇 |
1955年 | 2篇 |
排序方式: 共有5607条查询结果,搜索用时 484 毫秒
41.
Bromide and iodide ions were determined simultaneously by capillary isotachophoresis using an aqueous electrolyte system; the separation principle was based on the ion-pairing equilibria between tetradecyldimethylbenzylammonium ion and these anions in the leading electrolyte. The interaction between iodide ion and tetradecyldimethylbenzylammonium ion was stronger than that for bromide ion. Thus complete separation of bromide and iodide ions could be obtained by using a leading electrolyte containing 1.5 mM tetradecyldimethylbenzylammonium ion. The pH of the leading electrolyte was adjusted to 5.0. The relative standard deviations of the zone length for bromide and iodide ions were 1.1 and 1.2%, respectively, when mixture of 3.0 mM of these ions was analysed. A 150-μl volume could be injected for the simultaneous determination of low concentrations of bromide and iodide ions. 相似文献
42.
The palladium-catalyzed regio- and diastereo-selective allylic alkylation of allyl acetates with carbon nucleophiles occurred. The stereochemistry was highly controlled by the palladium catalyst with 2-(diphenylphosphino)benzoic acid as the ligand, and vicinal quaternary and tertiary carbon centers were constructed. 相似文献
43.
Sara Busi Jarmo Ropponen Jussi Valkonen Kari Rissanen 《Journal of solid state chemistry》2004,177(10):3757-3767
Series of new aromatic R2R′2N+Br− (R=benzyl, 4-methylbenzyl, 2-phenylethyl, 3-phenylpropyl; R′=ethyl, methyl, isopropyl) or RR′2NH+Br−-type (R=benzyl, R′=isopropyl) quaternary ammonium bromides were prepared by using novel synthetic route in which a formamide (N,N-diethylformamide, N,N-dimethylformamide, N,N-diisopropylformamide) is treated with aralkyl halide in presence of a weak base. The compounds were characterized by 1H-NMR and 13C-NMR spectroscopy and mass spectrometry. Structures of the crystalline compounds were determined by X-ray single crystal diffraction, and in addition the powder diffraction method was used to study the structural similarities between the single crystal and microcrystalline bulk material. Three of the compounds crystallized in monoclinic, two in orthorhombic and one in triclinic crystal system, showing ion pairs, which are interconnected by weak hydrogen bonds and weak π-π interactions between the phenyl rings. Three of the compounds appeared as viscous oil or waxes. Finally, TG/DTA and DSC methods were used to analyze thermal properties of the prepared compounds. The lowest melting points were obtained for diethyldi-(2-phenylethyl)ammonium bromide (122.2 °C) and for diethyldi-(3-phenylpropyl)-ammonium bromide (109.1 °C). In general, decomposition of the compounds started at 170-190 °C without identifiable cleavages, thus liquid ranges of 30-70 °C were observed for some of the compounds. 相似文献
44.
Fourier transform Raman spectra of eight mixtures of four organic solids, namely dicyandiamide, melamine, acetamide and urea were measured. Matrices formed from these spectra were first subjected to singular value decomposition to obtain the right singular vectors. The right singular vectors were then subjected to blind source separation using band-target entropy minimization (BTEM), thus no a priori information (i.e. involving the nature of the components present, their spectra, nor their concentrations) was included in the analysis. The recovered pure component spectra are of exceptionally high quality and are consistent with pure reference spectra. Various empirical and statistical tests, such as the Euclidean norm and target transform factor analysis, were employed to assess the quality of the recovered spectra. The present results indicate the applicability of combined Raman and BTEM analysis for solid mixtures. 相似文献
45.
C12-s-C12•2Br和C12En混合水溶液的胶团化行为 总被引:3,自引:0,他引:3
季铵盐二聚表面活性剂C12 s C12•2Br(s=2、3、4、6)和非离子表面活性剂C12E10或C12E23在水溶液中生成混合胶团.其临界胶团总浓度cmcT值介于二元复配体系中各组分的临界胶团浓度和之间.当添加少量非离子型表面活性剂(在水溶液中的摩尔分数α2=0.1)时,混合胶团中C12E10或C12E23的摩尔分数均已超过0.35;随着溶液中非离子型表面活性剂含量的增大,混合胶团中逐渐以C12E10或C12E23成分为主. 相似文献
46.
测定了四元体系ErCl3-CdCl2-HCl-H2O(298.15K)的相平衡溶度数据, 绘制了相应的溶度图. 该四元体系是由4 个固相区CdCl2·H2O(原始盐)、9CdCl2·2ErCl3·29H2O、CdCl2·7ErCl3·42H2O、ErCl3·6H2O(原始盐)组成的复杂
体系. 对两个新物相化合物9CdCl2·2ErCl3·29H2O 和CdCl2·7ErCl3·42H2O 进行了XRD、TG-DTG 和荧光光谱研究.结果表明, 两个新物相化合物均具有荧光和上转换发光性能; 化合物9CdCl2·2ErCl3·29H2O通过3 步失去其结晶水, CdCl2·7ErCl3·42H2O 则1 步失去其结晶水. 相似文献
47.
Twenty-one R2R′2N+X− -type (R=methyl or ethyl, R′=alkyl, X=Br or I) quaternary ammonium (QA) halides have been prepared by using a novel one-pot synthetic route in which a formamide (dimethyl-, diethylformamide, etc.) is treated with alkyl halide in the presence of sodium or potassium carbonate. The formation of QA halides was verified with 1H-NMR, 13C-NMR, MS and elemental analysis. The crystal structures of four QA halides (two bromide and two iodide) were determined using X-ray single crystal diffraction, and the powder diffraction method was used to study the structural similarities between the single crystal and microcrystalline bulk material. The thermal properties of all compounds were studied using TG/DTA and DSC methods. The smallest compounds decomposed during or before melting. The decreasing trend of melting points was observed when the alkyl chain length was increased. The liquid ranges of 120-180 °C were observed for compounds with 5-6 carbon atoms in the alkyl chain. The low melting points and wide liquid ranges suggest potential applicability of these compounds for example as ionic liquids precursors. 相似文献
48.
稳态荧光探针法测定三聚季铵盐表面活性剂的胶束聚集数 总被引:5,自引:0,他引:5
以芘为荧光探针, 十六烷基氯化吡啶(CPC)为猝灭剂, 以芘的饱和水溶液为溶剂配制表面活性剂溶液, 根据芘的荧光强度之比I1/I3随表面活性剂水溶液浓度的变化, 测定了三聚季铵盐表面活性剂CTTTA的cmc值, 测定值与表面张力法测定的cmc值一致;当猝灭剂CPC的浓度取0.1~0.3 mmol·L-1范围时, 用稳态荧光探针法测定了CTTTA的胶束聚集数. 实验数据表明, 表面活性剂溶液浓度为6~10倍cmc时, 胶束聚集数N随表面活性剂浓度增大而线性增大, 并用外推法得到CTTTA的临界胶束聚集数. 相似文献
49.
电力系统单相接地故障对线损影响的研究 总被引:1,自引:0,他引:1
提出了一种单相接地故障对线路线损影响的简便分析方法,并就接地故障对线损的影响情况进行了定性分析。 相似文献
50.
针对指令重试时难以合理选择重试时机和冗余资源问题,并根据星载系统的特点,提出了系统致命失效概率最小的单故障重试恢复策略.该策略以星载系统所有出现的故障均为单故障这一假设为前提,建立了指令重试时间与系统资源备份数及系统的致命失效概率间的关系.通过最小化系统的致命失效概率,可得出在系统资源备份一定时的最佳指令重试时间.同时,若系统存在最大致命失效概率,则可得到在最佳指令重试时系统所需的资源备份数.分析该策略可以发现,星载系统的致命失效概率随着系统的运行期的延长而增大,并且随着错误检测率的提高,星载系统的可靠性增加。 相似文献