19F NMR study of relative polarities and reactivities of N-H,N-Hg,and N-Au bonds in 2-(4-fluorophenyl)benzimidazole and its PhHg and Ph3PAu derivatives in intermolecular exchange

It has been shown by the¹⁹F NMR method that the relative polarities of nitrogenelement bonds in 2-(4-fluorophenyl)benzimidazole and its PhHg and PPh₃Au derivatives increase in the order N-H19F NMR. It has been found that these reactions occur by a bimolecular associative mechanism and that the N-H bond is substantially less reactive than the N-Hg and N-Au bonds, which have identical reactivities within the limits of sensitivity of the method used.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1574–1580, August, 1995.This work was carried out with financial support from the Russian Foundation for Basic Research (Project No. 93-03-5528).     

NMR Study of the propagation center in the cationic polymerization of N-benzoyl-8-octanelactam. II. Investigation of the propagation center

The nature of the propagation center in the cationic polymerization of N-benzoyl-8-octanelactam initiated by octanoylium hexachlcroantimonate, SbCl₅, and Ph₃CAsF₆ in perdeuterated tetrachloroethane or its mixture with o-dichlorobenzene was studied using ¹H, ¹³C, ¹⁹F, ³¹P, ⁷⁵As, and ¹²¹Sb nuclear magnetic resonance (NMR) of model oligomers and the products of their end-capping with triphenylphosphine. In all cases, the nature of the propagation center has been found to be of an acylium ion pair with an SbCl₆^? or AsF₆^? counterion coordinated with the nearest benzoylamide group and cosolvated by the solvent. © 1994 John Wiley & Sons, Inc.     

M-M型纳米颗粒膜的巨磁电阻效应

探讨了M-M型纳米颗粒膜巨磁电阻效应的物理机制，指出了影响颗粒膜巨磁电阻效应的因素，推导出M-M型纳米颗粒膜巨磁电阻效应的计算公式。     

对城市供水行业改革的思考

分析了目前各地供水行业改革中遇到的问题,提出了加强政府对供水行业的监管力度,慎重选择投资主体和特许经营者,理顺供水价格调整机制等城市供水行业改革的措施。     

Collective mechanism for nuclear stopping and transverse flow in heavy-ion collisions

The role of filamentation instability of quark-gluon plasma, in explaining collective phenomena in relativistic heavy-ion collisions, has been analyzed. Using equations of SU(2) two fluid color hydrodynamics it is shown that this instability can significantly enhance nuclear stopping and might contribute to collective sideward flows.     

以中日韩自由贸易区为核心和先导的东北亚合作模式

2003年10月中日韩三国领导人在印尼巴厘岛《中日韩推进三方合作联合宣言》的签署之后，东北亚合作的问题日益成为人们关注的焦点，加强东北亚各国的合作不仅有利于促进亚太区域内各国经济的发展，促成亚太地区经济进一步崛起，还会化解东北亚各国之间的矛盾和冲突．东北亚的合作应当加强信任、走制度化的合作道路，创设以中日韩自由贸易区为核心和先导的东北亚合作模式．以次区域合作先行的模式来带动东北亚经济一体化的发展。     

Kinetics and mechanism of polymerization of methyl methacrylate initiated by stibonium ylide

Homopolymerization of methyl methacrylate (MMA) was carried out in the presence of triphenylstibonium 1,2,3,4-tetraphenyl-cyclopentadienylide as an initiator in dioxane at 65°C±0·l°C. The system follows non-ideal radical kinetics (R _p ∝ [M]^1·4 [I]^0·44 @#@) due to primary radical termination as well as degradative chain-transfer reaction. The overall activation energy and average value ofk ₂ ^p /k _t were 64 kJmol⁻¹ and 0.173 × 10⁻³ 1 mol⁻¹ s⁻¹ respectively     

高校学科文献资源的科学配置机制及管理体制研究

提出了高等学校实行学科文献资源科学配置的机理及原则,探讨了在网络环境下如何建立有核心竞争力的学科文献资源管理体制。     

移动通信系统安全机制发展的研究

从移动通信系统演进的角度介绍了安全机制的发展历程,分析研究了2G的安全性措施,阐述了3G认证签权方案及其优缺点,并对移动通信安全机制提出了一些见解。