互换性与测量技术基础试题库及软件开发

本着操作简单、方便、实用、功能强的原则,开发了《互换性与测量技术基础题库系统》软件,用此软件,使略有Ｗｉｎｄｏｗｓ操作基础的教师,在不到一的时间内就可以自动生成一份试卷。     

基于CSCW的中文超媒体技术的研究实现

讨论了基于ＣＳＣＷ的新一代中超媒体技术,主要介绍超媒体系统数据结构模型,分布与协作技术,超链自动链接技术,超媒体系统的中检索技术,超媒体系统的用户界面等,并介绍了一个基于工作组网络系统Ｗｉｎｄｏｗｓ ｆｏｒ Ｗｏｒｋｇｒｏｕｐｓ的超媒体原型的系统实现,该系统是一个面向大容量超媒体中档案的协作写作系统,适用皇大中型中电子图书和档资料库的光盘出版物的制作。     

代数结构与几何基础Ⅳ——仿射几何的公理体系

在公理化方法定义的几何中引进“平行”关系,然后把结合公理I;改成“平行公理”,我们就得到一种新的几何——仿射几何．本文将证明这种几何同构于某一体(域)上的n维仿射几何,若添加牍序公理,则这种几何同构于某一有序体(域)上的n维仿射几何,最后我们指出：三维仿射几何的结合公理、平行公理和顺序公理就是Hilben公理体系中的结合公理、平行公理和顺序公理。     

IDSS的实现技术探讨

探讨智能型决策支持系统(IDSS)的实现技术,以DSS模型语言IFPS/plus为工具建立的“贷款审批决策系统”说明了使用模型语法表达定性数据和符号推理的方法,这种方法把专家系统(ES)的功能直接嵌入DSS,对许多IDSS的构建是有效的。     

新工科视阈下石油化工类高校应用化学专业课程体系重构

Taking a typical local and industry-orientated applied chemistry major as an example with focusing on the major changes in the form and content of the petrochemical industry, the way to reform the core curriculum system and teaching contents is presented. Based on the changing tendency of refinement of the petrochemical industry, a complete curriculum system with distinctive industry characteristics is set up according to the principles of the emerging engineering education (3E) with several reasonable suggestions. A new model for the construction of a 3E major in chemistry-related majors is suggested. It is a good reference for the construction of curriculum systems for other local and industry-orientated colleges who want to make 3E reform.     

Crystal Structure and Characterization of 2-N-(2-Hydroxy-benzylidene) Furanmethanoamine Nickel(II) Complex

1 INTRODUCTION Recently, the low-spin square-planar nickel(II) complexes and high-spin octahedral nickel(II) complexes with Schiff base ligands have received much attention in optical materials[1～3]. Some nic- kel(II) complexes are widely used as lubricating oil, rubber industry additives, a fire-resistant additive and fungicide for leather[4～7]. Also, their adducts with nitrogen have attracted broad attention due to their potential applications as organic conductors and magnetic mate…     

Synthesis of nanostructures based on 1,4- and 1,3,5-phenylethynyl units with π-extended conjugation. Carbon networks dendrimer base units

A convenient and efficient synthesis of 3,5-di(silylethynyl)phenylacetylene and p-[3,5-di(silylethynyl)phenylethynyl]phenylacetylene has been carried out. These compounds serve to prepare nanometer-sized conjugated 1,4- and 1,3,5-phenylethynyl oligomers, by means of cross-coupling with a convenient haloaryl derivative, catalysed by palladium(II), in excellent yields. The phenylethynyl homologues show fluorescence emission, the wavelength of which is displaced by approximately 20 nm by each phenylethynyl unit increasing the conjugate chain.     

Shape of the proton potential in an intramolecular hydrogen-bonded system. Part II

The crystals of 5,5′-dibromo-3-diethylaminomethyl-2,2′-biphenol N-oxide were studied by X-ray and FT-IR spectroscopy. Within this molecule two short OHO intramolecular hydrogen bonds are formed. The NO?H⁺?O⁻ bond between the OH and the N-oxide groups is very strong, of 2.419(7) Å between the oxygen atoms. The proton potential of this hydrogen bond is flat, broad and has probably no barrier—consequently it could not be located from X-ray diffraction data. The other hydrogen bond formed between two hydroxyl groups appears asymmetrical from FT-IR spectra, and shows also relatively limited proton polarizability. The molecular conformation is non-planar, due to strong overcrowding effect between the oxygen atoms involved in the hydrogen bonds.     

Tröger's base scaffold in racemic and chiral fashion as a spacer for bisdistamycin formation. Synthesis and DNA binding study

‘Head-to-head’ oligo-N-methylpyrrole peptide dimers linked by a methano[1,5]diazocin scaffold are presented in racemic as well as chiral fashion. Their DNA binding activities were assayed on calf thymus DNA, poly(dA-dT)₂, and poly(dC-dG)₂ by NMR and ECD spectroscopies, and fluorescence probe displacement assay. The presented dimers prefer AT sequences, but show higher affinity to poly(dC-dG)₂ than distamycin A. The (4R,9R) configuration of methanodiazocin bridge was found to be better suited for interaction with ct-DNA and poly(dA-dT)₂ than (4S,9S) configuration.     

H3PW12O40 and its cesium salts as pentane isomerization catalysts at ambient temperature

The activity of Mg−Al basic heterogeneous catalysts in the reactions of alcohols with ethylene oxide was studied. The kinetics of alcohol oxyethylation was examined. The kinetic equation of the reaction was determined and the structure of products was studied. The distribution coefficients of the oxyethylation reaction products were calculated. A comparison of the catalytic activity of Mg−Al hydroxides and products of their thermal treatment was made.