Solvatochromic Solvent Polarity Measurements In Analytical Chemistry: Synthesiss And Applications Of Et-30

Abstract

The E_T(30) scale of solvent polarity has been shown to be useful in examining many diverse analytical processes. It is based on the charge transfer absorption of 2,6-diphenyl-4-(2,4,6-triphenyl-N-pyridinio)phenolate (referred to as ET-30 in this paper). Unfortunately, use of the E_T(30) scale has been hindered by (a) the lack of a commercial source of the ET-30 dye and (b) the lack of an English language synthetic procedure. Here we discuss recent applications of the E_T(30) scale to analytical techniques, as well as a simplified procedure for the synthesis of ET-30.     

Separation and Analysis of o.p'-DDD and its Lipophilic Metabolite,O.P'-DDE,in Tissue,Faeces and Plasma

Abstract

An analytical procedure based on electron capture gas chromatography for the determination of o,p′-DDD, a drug used for the treatment of Cushing′s syndrome, is presented. Detection of a metabolite, identified as o,p′-DDE, is also described.     

微光成像系统的阈值探测理论和视距探测方程的研究

研究目前文献中常见的１８种微光成像系统探测方程之间的内在联系和异同之处，分析论证各种阈值探测理论和探测方程存在的问题和不足。在此基础上，从人眼的视觉理论和阈值特性出发，建立微光成像系统新的阈值探测理论模型，并分别导出微光直视系统和微光电视系统的视距探测方程。应用所导出的理论公式计算的数据与各种实际系统的实测数据进行了比较，证明新的阈值探测理论和视距探测方程是正确可靠的，且具有很高的精度。     

Photoconductivity of erbium-doped germanium

We have applied the technique of Photo Thermal Ionization Spectroscopy (PTIS) to the study of an erbium-doped p-Ge epitaxial layer, grown by MBE on an undoped n-type germanium substrate. The Er-doped Ge layer shows continuum photoconductivity response in the far-infrared region extending from 70 cm^–1 to 900 cm^–1. This type of epitaxial Er-doped Ge layers is a potentially attractive system for photoconductivity detectors of far-infrared radiation. Below 900 cm^–1 three acceptor-like charged states can be distinguished with ionization energies of 9, 26.6 and 50 meV. Additionally, a study of the photoconductive response of the same sample for radiation from 1000 cm^–1 to 10000 cm^–1, i.e., for radiation energies well inside the forbidden gap to energies above it, shows a wealth of levels, some of which have previously been associated with erbium.On leave from: Instituto de Física, Universidad Autónoma de Puebla, Puebla, México     

电磁场边值关系中的独立方程

文献[1]曾指出、在麦克斯韦微分方程组中,只有二个旋度方程是独立的。文献[2]曾就定态波的特殊情况,指出电磁场边值关系中,也只有二个方程是独立的。本文进一步在随时间任意变化场情况下,从电磁场的二切向分量边值关系推导出另外二个法向分量的边值关系,从而普遍的证明了时变电     

The size distribution for theA g RB f−g Model of polymerization

This paper gives the equilibrium distribution of polymer sizes for Flory'sA _g RB _f–g model of polymerization. In this model, the polymers are composed of structural units withg functional groups of the typeA and (f-g) functional groups of the typeB. Reaction is subject to three conditions: (1) Functional groups of the typeA react only with those of typeB, and vice versa. (2) Intramolecular reactions do not occur [and therefore only branched-chain (noncyclic) polymers and formed]. (3) Subject to conditions (1) and (2), all functional groups are equally reactive. The derivation employs Stockmayer's statistical mechanical method (first used on Flory'sRA _f model), coupled with a recursion giving the number of distinct polymers which may be assembled fromk units of theA _g RB _f–g type. We also give distributions for a limiting case of theA _g RB _f–g model, the so-calledA _g RB model. This paper completes the solution of the Smoluchowski coagulation equation (monodisperse case) for the kernelsa _ij =A + B(i +j)+ Cij. The proof will be given in another publication.     

A simple game with a singular focal line

We propose a simple game whose solution contains a singular focal line, i.e., a focal line reached by optimal trajectories in a nontangential fashion. We also provide a discussion of how the optimal discriminating strategy can be approximated by a pure feedback.This work was prepared while the first author was visiting at INRIA-Sophia Antipolis, Valbonne, France.     

石墨烯纳米带电极区N掺杂电子输运性质研究

运用密度泛函理论和非平衡格林函数结合的方法,研究电极区N掺杂对扶手椅型石墨烯纳米带电子输运特性的影响.结果表明,与本征扶手椅型石墨烯纳米带电流-电压曲线相比,宽度为7的石墨烯纳米带电流-电压曲线表现出明显的不对称性,其中心N掺杂表现强烈的整流特性,整流系数达到102数量级,且将N原子从电极区中心位置移动到边缘,整流特性减弱.研究结果表明宽度为7的扶手椅型石墨烯纳米带出现强整流现象的原因主要是负向偏压下能量窗内没有透射峰引起的,该研究结果对将来石墨烯整流器件的设计具有重要的意义.     

Constructing Solutions of an Ill-Posed Nonlinear Singularly Perturbed Problem for an Equation of Elliptic Type

Mathematical Notes -