Calibration of a simple cone-penetration model for snow

Numerical studies using the Material Point Method (MPM) have been conducted recently to model snow penetration tests for fine-grained and coarse-grained snows using small cones with diameters ranging from 2.5 mm to 4 mm, and cone half-angles between 15° and 45°. Although numerical studies have gained physical insight of these tests, due to the lengthy computation time needed for the MPM simulations, it is not feasible to use these simulations to develop a stochastic model to assess the large variations of the mechanical properties of snow typically shown in tests. In this paper, we present a simple and efficient physics-based analytical model based on equilibrium and a cavity expansion solution upon which a stochastic model is built to obtain calibrated material parameters for a Drucker–Prager (DP) model such that prediction of the model can be made. Sensitivity analysis of the analytical model indicates that cohesion and interfacial shear (friction) factor contribute significantly to the penetration hardness whereas the friction angle has little contribution. The calibrated material parameters are similar to those estimated via the MPM simulations. The quality of the stochastic model, when compared with test data, was assessed using four interval-based validation metrics with good results.     

New insight on acoustoplasticity - Ultrasonic irradiation enhances subgrain formation during deformation

Many industrial applications make use of ultrasonic vibration to soften metals. The existing understanding of such an acoustoplastic effect is one in which the ultrasonic irradiation either imposes additional stress waves to augment the quasi-static applied load, or causes heating of the metal, whereas the metal’s intrinsic deformation resistance or mechanism is assumed to be unaltered by the ultrasound. In this study, indentation experiments performed on aluminum samples simultaneously excited by ultrasound reveal that the latter intrinsically alters the deformation characteristics of the metal. The deformation microstructures underneath the indents were investigated by a combination of cross-sectional microscopic techniques involving focused-ion-beam milling, transmission electron microscopy and crystal orientation mapping by electron backscattered diffraction. The softening effect of the ultrasound is found to constitute recovery associated with extensive enhancement of subgrain formation during deformation. By comparing the microstructures of samples deformed with and without simultaneous application of ultrasound, and those subsequently excited by ultrasound after deformation, the enhanced subgrain formation is proved to be one due to the combined application of the quasi-static loading and the ultrasound, but not a simple addition of the two. Similarly, by comparing with samples deformed while being simultaneously or subsequently heated up, the enhanced subgrain formation by the ultrasound is proved to be a lot greater than that due to the heat that it generates within the metal. Such effects of the ultrasound are interpreted by its ability to enhance dipole annihilation. The superimposed ultrasound causes dislocations to travel longer distances in a jerky manner, so that they can continuously explore until dipole annihilation.     

Texture change through film thickness and off-axis accommodation of (0 0 2) planes

We present our recent experimental results on the formation of off-axis texture and crystallographic tilting of crystallites that take place in thin film of transition metal nitrides. For this purpose, the microstructural development of TiAlN film was studied, specially the change in texture with film thickness. Fiber texture was measured using θ-2θ and pole figure X-ray diffraction (XRD), while scanning electron microscopy (SEM) and transmission electron microscopy (TEM) were used to observe the microstructure and changes in texture with thickness. The sin²ψ method was applied to determine the stresses on (1 1 1) and (0 0 2) plane. With deposition parameters chosen, the growth texture mechanism is discussed in three different stages of film growth. Surface energy minimization at low thickness leads to the development of (0 0 2) orientation. On the other hand, the competitive growth promotes the growth of (1 1 1) planes parallel to film surface at higher thickness. However, contrary to the prediction of growth models, the (0 0 2) grains are not completely overlapped by (1 1 1) grains at higher thickness. Rather the (0 0 2) grains still constitute the surface, but are tilted away from the substrate normal showing substantial in-plane alignment to allow the (1 1 1) planes remain parallel to film surface. Intrinsic stress along (1 1 1) and (0 0 2) shows a strong dependence with preferred orientation. The stress level in (0 0 2) grains which was compressive at low thickness changes to tensile at higher thickness. This change in the nature of stress allows the (0 0 2) planes to tilt away in order to promote the growth of 〈1 1 1〉 parallel to film normal and to minimize the overall energy of system due to high compressive stress stored in the (1 1 1) grains. The change in surface morphology with thickness was observed using SEM. An increase in surface roughness with film thickness was observed which indicates the development of (1 1 1) texture parallel to film surface. TEM observations support the XRD results regarding texture change. Film hardness was measured by nanoindentation and a correlation between (1 1 1) texture, stress and hardness is obtained. The results indicate that texture development is a complex interplay between thermodynamic and kinetic forces. An attempt is made to understand this phenomenon of off-axis accommodation of (0 0 2) at higher thicknesses, which is a new result not reported previously.     

Effects of micro-additions on structures and properties of rapidly solidified Sn-10% Sb alloy

Structure, electrical resistivity, hardness, internal friction and elastic modulus of Sn-10% Sb and Sn₈₉Sb₁₀M₁ (M₁ = Ag, Cu, Zn and Pb) alloys have been investigated. No obvious change on the electrical resistivity value was found at 293 °K of a Sn-10% Sb alloy by adding Zn and Cu, but extreme changes occurred after adding Ag and Pb. The elastic modulus, internal friction, hardness and thermal diffusivity values are greatly affected by adding the micro-additions to a Sn-10% Sb rapidly solidified alloy. It is also interesting to note that Ledbetter's theoretical values of μ/E are in good agreement with the experimental results. The rapidly solidified alloys Sn₉₀Sb₁₀ and Sn₈₉Sb₁₀Ag₁ have good properties as toxic-free lead solder alloys for high-temperature applications and good mechanical properties such as under the hood in the automobile and avionics systems. Also, the rapidly solidified alloys Sn₈₉Sb₁₀Zn₁, Sn₈₉Sb₁₀Cu₁ and Sn₈₉Sb₁₀Pb₁ have good properties as bearing materials.     

Modification of structural,optical, thermal and mechanical properties of KDP crystals on the addition of Ni

Nonlinear optical materials are acquiring a new significance day by day with the advent of a large number of devices utilizing solid state laser sources. Owing to this technological application KDP having superior nonlinear optical property has been exploited for various applications. KDP crystals were grown from aqueous solutions added with Ni²⁺. SHG studies confirm that the title exhibits NLO property. The influence of doping Ni²⁺ on the structural, optical, thermal, NLO and mechanical properties has been studied in this present investigation. It is observed that addition of Ni²⁺ improves the optical, thermal and mechanical properties of the crystal.     

Synthesis,crystal growth and characterization of novel semiorganic nonlinear optical crystal: Dichloro(beta-alanine)cadmium(II)

Semiorganic nonlinear optical material of dichloro(beta-alanine)cadmium(II) (DCBAC) have been synthesized and single crystals were grown by solvent evaporation method at room temperature. The lattice parameters of the grown crystals are determined by single crystal XRD. The modes of vibration of different molecular groups present in the sample were identified by the FTIR spectral analysis. Thermal stability of the crystal was investigated using thermo gravimetric analysis (TGA) and differential thermal analysis (DTA). The dielectric constants of the crystal were studied as a function of frequency and the results are discussed. The grown crystals are subjected to microhardness studies and the variation of the microhardness with the applied load is studied. The optical transmission spectra and second harmonic generation (SHG) were investigated to study its linear and nonlinear optical properties. The nonlinear optical (NLO) property of the crystal was confirmed by powder second harmonic generation (SHG) test. SHG efficiency is comparable to that of KDP.     

Decision-theoretic troubleshooting: Hardness of approximation

Decision-theoretic troubleshooting is one of the areas to which Bayesian networks can be applied. Given a probabilistic model of a malfunctioning man-made device, the task is to construct a repair strategy with minimal expected cost. The problem has received considerable attention over the past two decades. Efficient solution algorithms have been found for simple cases, whereas other variants have been proven NP-complete. We study several variants of the problem found in literature, and prove that computing approximate troubleshooting strategies is NP-hard. In the proofs, we exploit a close connection to set-covering problems.     

Modelling and optimization of rebound resilience and hardness of defatted rice bran/calcium carbonate-filled NR vulcanisates

Hardness and rebound resilience of natural rubber (NR) vulcanisates filled with defatted rice bran (DRB)/calcium carbonate (CaCO₃) were modelled and optimized. Second-order polynomial functions were generated to model the properties and to generate contour plots. Predicted properties of NR vulcanisates showed good agreement with experimental results. Hardness of filled-NR vulcanisates increased with filler loading, whereas rebound resilience decreased. At a fixed hardness level, lower CaCO₃ loading can be used with partial DRB replacement. DRB incorporation into rubber compounds can improve their stiffness. Contour plots were used to identify DRB and CaCO₃ level ranges for achieving optimum hardness and rebound resilience.     

Effect of the Poly(Methyl Methacrylate) Molecular Weight on the Mechanical Properties BisGMA/TEGDMA Semi-interpenetrating Polymer Networks

Abstract

The effect of poly(methyl methacrylate) [PMMA], with different molecular weights on the mechanical properties of a polymerized BisGMA/TEGDMA base monomer resin was investigated. With the aid of acetone solvent, PMMA could be readily dissolved in BisGMA/TEGDMA mixtures. The addition of PMMA can significantly improve the compressive strengths and decrease the Knoop hardness values of the BisGMA/TEGDMA/PMMA semi-IPNs. The thermal expansion coefficients rapidly increased before T_g, and decreased after T _g. The observed properties could be attributed to the effect of the molecular weight of the PMMA on the phase structures of the semi-IPNs.     

Laser controlled melting of pre-prepared inconel 718 alloy surface

Laser treatment of Inconel 718 alloy surface is carried out. The alloy surface is coated with a carbon layer containing 7% TiC particles prior to the laser treatment. The carbon coating provides increased absorption of the incident laser beam and holds TiC particles. The microstrutural and morphological changes in the laser treated region are examined using optical and scanning electron microscopes, energy dispersive spectroscopy, and X-ray diffraction. The microhardness of the surface is measured and the residual stress formed at the surface vicinity is determined from the XRD technique. It is found that partial dissolution of carbide particles takes place at the surface. The composition of fine grains at the surface vicinity, nitride compounds formed, and dissolution of Laves phase at the surface region enhances the hardness at the treated surface. In addition, laser treated surface is free from the micro-crack network and cavities.