新的适用于整个热力面的1,1,1,2-四氟乙烷(R134a)跨接状态方程

1前言作者建立了一个新型的符合临界重整化群理论的跨接状态方程，能够描述物质的整个区域热力性质山。鉴于R134a是R12的新的主要替代制冷剂，为了计算其整个区域的热力性质，本文将新跨接状态方程应用于R134a，以便提供一个能在整个区域计算R134a热力性质的状态方程。2新跨接状态方程作者建立了以下型式的新跨接状态方程l‘］：上式中，西方一r一IDZ户一p巾c；，一DI—TD；T—To／T；产为密度；pc为临界密度；T为温度；To为临界温度；矿对比过余Helmholtz自由能；A是Helmholtz自由能。新函数中，a。一30，a，一10；0—0．325和西一…     

以HFC134a为制冷剂的喷射制冷实验研究

设计并搭建了喷射制冷系统性能研究实验台,选取HFC134 a作为制冷剂进行了喷射制冷实验研究。研究表明,在测试工况范围内,喷射系统的COP随蒸发温度的升高而增加,随冷凝温度的升高呈现先是基本不变,后迅速降低的趋势,随发生温度的升高先升高后降低;另外,研究还发现系统的COP随着冷冻水流量的增加而增加。     

Fluorocarbons in the global environment: a review of the important interactions with atmospheric chemistry and physics

Fluorocarbon impact on ozone depletion is reviewed together with the efficacy of the Montreal Protocol in acting to correct the imbalance between stratospheric ozone production and destruction. The Protocol is also helping to reduce global warming: CFCs are shown to be currently the largest fluorocarbon contributors to climate change. Relative contributions to climate change from CFCs and their HFC substitutes are discussed, together with the consequences of control of minor greenhouse gases on an environmental impact which is dominated by carbon dioxide emissions. Both the potencies of the materials for environmental change and their concentrations in the atmosphere are important and are considered here.Trifluoroacetic acid, a minor product of atmospheric decomposition of some HCFCs and HFCs and of the pyrolysis of fluoropolymers, has been shown to be uniformly distributed in seawater to a depth of over 4000 m and so is natural, although the actual source has yet to be identified.The Montreal Protocol is only one example of action to reduce undesirable impact from fluorocarbons. Other, less universal, actions include abatement of fluoroform greenhouse gas emissions from HCFC manufacturing, process changes to eliminate trifluoromethylsulfur pentafluoride emissions from electrochemical fluorination and ceasing manufacture of perfluorooctanyl sulfonate compounds due to their persistence in human tissue.     

Reaction of HCFC‐133a (CF3CH2C1) or HFC‐134a (CF3CH2F) with alcohols or phenols in DMSO in the presence of KOH

In an open glassware, heating a gas HCFC‐133a (CF₃CH₂C1) or HFC‐134a (CF₃CH₂F), KOH and a phenol (or an alcohol) in DMSO at 80°C gave ethers ROCF₂CH₂X and (E/Z)‐ROCF = CHX (X = Cl, F) in moderate yields.     

基于PLL的HFC网管数据调制器设计

设计了基于PLL的HFC网络数据调制器．调制方式采用FSK，频偏为100kHz．这种数据调制器频率稳定度高，覆盖范围宽，并且可实现载波频率捷变．     

混合工质HFC152a/HCFC22压焓图及饱和性质表

根据现有的ＨＦＣ１５２ａ／ＨＣＦＣ２２的泡、露点实验数据,拟合出适用于计算其热力学性质的Ｐｅｎｇ－Ｒｏｂｉｎｓｏｎ方程的二元交相作用系数,并由此制作了混合工质ＨＦＣ１５２ａ／ＨＣＦＣ２２（质量分数为８５％／１５％）的压焓主饱和性质表,在以温度和压力的基准的饱和性质表中,列出了温度在－８０℃－１００℃,压力在１００ｋＰａ－３ＭＰａ之间,该混合工质的饱和热力性质,图和表所示的热力性质包括温度,压力,比     

Cable Modem宽带接入系统设计

本文介绍了HFC宽带接入系统Cable Modem的软、硬件设计方案,本系统具有速率高、工作稳定可 靠、不占用电话线即可永久在线等特点。     

双向HFC网上行传输的技术问题及对策

文章对有线电视双向HFC网上行传输的若干技术问题作了较详细的研究;阐述了双向HFC网传输通道中的特有问题——“汇集干扰”、“汇集均衡”等概念及形成原因,并通过实例分析;提出了解决双向HFC网中信号存在“汇集干扰”、“汇集均衡”等问题的可行性方案及加强有线电视上行通道安全性的措施。     

HFC和HCFC类物质的表面张力的关联

表面张力是有沸腾和凝结的换热计算必不可少的物性参数 ,HFC和 HCFC物质分别作为长期性和过渡性的制冷剂替代物 ,其表面张力数据对于制冷空调设备的设计计算是十分重要的。该文综合国际上现有的实验数据 ,给出了各种 HFC和 HCFC物质统一形式的表面张力关联式 ,可以在广阔的温度范围内高精度地再现实验数据 ,并与国际上现有的关联式进行了比较分析。该文所提供的表面张力关联式的计算精度可满足工程实际需要。     

HFC下行信道削波对QAM误码率的影响

分析了副载波路复用模拟光纤传输系统中,引入ＭＱＡＭ方式的数据业务后,原模型的消波对数字信号的影响,认真分析了ＱｕｎＳｈｉ的论文,采用一咱新的零阶Ｂｅｓｓｅｌ函数近似式和一种快速收敛级数算法对消波造成的ＭＱＡＭ误码率进行计算,得出了一些较精确的结论。