全文获取类型
收费全文 | 100307篇 |
免费 | 7721篇 |
国内免费 | 15268篇 |
专业分类
化学 | 66466篇 |
晶体学 | 2279篇 |
力学 | 1032篇 |
综合类 | 550篇 |
数学 | 12940篇 |
物理学 | 17371篇 |
综合类 | 22658篇 |
出版年
2024年 | 235篇 |
2023年 | 1380篇 |
2022年 | 2416篇 |
2021年 | 2451篇 |
2020年 | 2729篇 |
2019年 | 2968篇 |
2018年 | 2428篇 |
2017年 | 2951篇 |
2016年 | 3071篇 |
2015年 | 3099篇 |
2014年 | 4272篇 |
2013年 | 7312篇 |
2012年 | 5830篇 |
2011年 | 6616篇 |
2010年 | 5628篇 |
2009年 | 6636篇 |
2008年 | 6659篇 |
2007年 | 7012篇 |
2006年 | 6346篇 |
2005年 | 5407篇 |
2004年 | 5200篇 |
2003年 | 4482篇 |
2002年 | 3933篇 |
2001年 | 3105篇 |
2000年 | 2785篇 |
1999年 | 2472篇 |
1998年 | 1999篇 |
1997年 | 1770篇 |
1996年 | 1592篇 |
1995年 | 1495篇 |
1994年 | 1321篇 |
1993年 | 1124篇 |
1992年 | 1106篇 |
1991年 | 837篇 |
1990年 | 653篇 |
1989年 | 615篇 |
1988年 | 527篇 |
1987年 | 411篇 |
1986年 | 334篇 |
1985年 | 338篇 |
1984年 | 317篇 |
1983年 | 178篇 |
1982年 | 180篇 |
1981年 | 193篇 |
1980年 | 151篇 |
1979年 | 159篇 |
1978年 | 120篇 |
1977年 | 109篇 |
1976年 | 96篇 |
1973年 | 69篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
41.
Dinesh Topwal U. Manju Sugata Ray S. Raj D. D. Sarma S. R. Krishnakumar M. Bertolo S. La Rosa G. Cautero 《Journal of Chemical Sciences》2006,118(1):87-92
Disordered Sr2FeMoO6 shows a drastic reduction in saturation magnetization compared to highly ordered samples, moreover magnetization as a function
of the temperature for different disordered samples shows qualitatively different behaviours. We investigate the origin of
such diversity by performing spatially resolved photoemission spectroscopy on various disordered samples. Our results establish
that extensive electronic inhomogeneity, arising most probably from an underlying chemical inhomogeneity in disordered samples, is
responsible for the observed magnetic inhomogeneity. It is further pointed out that these inhomogeneities are connected with
composition fluctuations of the type Sr2Fe1+x
Mo1-x
O6 with Fe-rich (x > 0) and Mo-rich (x < 0) regions.
Dedicated to Prof J Gopalakrishnan on his 62nd birthday. 相似文献
42.
根据我国高硫煤的赋存特点,提出采用微细介质重介旋流器及细泥选择性絮凝组合工艺实现细粒煤的深度脱硫,无机硫脱除率可大幅度提高,分选下限明显降低,是实现煤炭深度脱硫降灰产业化的有效技术途径. 相似文献
43.
根据W变换和Delta函数的定义,讨论了函数f(x)的线性函数af(x) b的W变换和函数Ⅱi-1^n,(x)的W变换问题,并推广了W变换的线性性质,得到了几个进一步的结果. 相似文献
44.
Pedro lvarez‐Boo Jos Sergio Casas Alfonso Castieiras María Delfina Couce Eduardo Freijanes Eva Novoa Jos Sordo 《应用有机金属化学》2003,17(9):725-729
Reaction of dichloro‐ and dibromodimethyltin(IV) with 2‐(pyrazol‐1‐ylmethyl)pyridine (PMP) afforded [SnMe2Cl2(PMP)] and [SnMe2Br2(PMP)] respectively. The new complexes were characterized by elemental analysis and mass spectrometry and by IR, Raman and NMR (1H, 13C) spectroscopies. Structural studies by X‐ray diffraction techniques show that the compounds consist of discrete units with the tin atom octahedrally coordinated to the carbon atoms of the two methyl groups in a trans disposition (Sn? C = 2.097(5), 2.120(5) Å and 2.110(6), 2.121(6) Å in the chloro and in the bromo compounds respectively), two cis halogen atoms (Sn? Cl = 2.4908(16), 2.5447(17) Å; Sn? Br = 2.6875(11), 2.7464(9) Å) and the two donor atoms of the ligand (Sn? N = 2.407(4), 2.471(4) Å and 2.360(5), 2.455(5) Å). In both cases, the Sn? N(pyridine) bond length is markedly longer than the Sn? N(pyrazole) distance. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
45.
《Magnetic resonance in chemistry : MRC》2003,41(9):660-670
Reduced forms of iso‐α‐acids (isohumulones), used in modern beer brewing were separated and characterized by 1H and 13C NMR spectroscopy. Components from mixtures of rho‐iso‐α‐acids, tetrahydro‐iso‐α‐acids, and hexahydro‐iso‐α‐acids were isolated using high‐performance liquid chromatography (HPLC) and analyzed by use of one‐ and two‐dimensional NMR experiments. The data presented assign the identities of the main peaks in the HPLC traces for the reduced iso‐α‐acids. Previous tentative assignments regarding the cis and trans configurations and the structures of the acyl residues of the reduced iso‐α‐acids were confirmed and extensive NMR assignments were made. Furthermore, the previously unknown stereochemistry in the C‐4 side‐chain of the rho‐ and hexahydro‐iso‐α‐acids was assigned. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
46.
Martin A. Bos Bertus Dunnewind Ton van Vliet 《Colloids and surfaces. B, Biointerfaces》2003,31(1-4):95-105
Interfacial rheological properties and their suitability for foam production and stability of two vegetable proteins were studied and compared to β-casein. Proteins used ranged from flexible to rigid/globular in the order of β-casein, gliadin and soy glycinin. Experiments were performed at pH 6.7. Network forming properties were characterised by the surface dilational modulus (determined with the ring trough) and the critical falling film length (Lstill) at which a stagnant protein film will break. Gliadin had the highest dilational modulus, followed by glycinin and β-casein, whereas glycinin formed the strongest film against fracture in the overflowing cylinder. The rate of decrease in the surface tension was studied at the air–water (Wilhelmy plate method) and the oil–water interface (bursting membrane) and the dynamic surface tension during compression and expansion in the caterpillar. Gliadin had the lowest equilibrium interfacial tensions and β-casein the lowest dynamic surface tension during expansion. Hardly any foam could be formed at a concentration of 0.1 g/l by shaking. At a concentration of 1.4 g/l most foam was formed by β-casein, followed by gliadin and glycinin. It seems that in the first place the rate of adsorption is important for foam formation. For the vegetable proteins, adsorption was slow. This resulted in lower foamability, especially for glycinin. 相似文献
47.
This Review discusses the synthesis and characterization by our Group of new antibiotics belonging to the class of penicillins, cephalosporins and rifamycins with ferrocenyl and 1, 1′-ferrocenilene residues in the molecule. As reactants for 6-aminopenicillanic acid (6-APA) and 7-aminocephalosporanic acid (7-ACA) the following were used: 1, 1-bis(chlorocarbonyl)ferrocene, ferrocenyl sulfochloride, 1, 1′-ferrocenylenedisulfochloride and thioglycolic acids S-modified with ferrocene. In the synthesis of rifamycins, the hydrazides of the thioglycolic acids, S-modified with ferrocene, were employed as nucleophilic agents. The synthesized intermediates were characterized by elemental analysis, TLC, IR, UV and 1H NMR spectra. The characterization of new antibiotics was made by TLC, IR and UV spectral analysis. Biological activity was tested on Gram-negative and Gram-positive bacteria. Good activity is reported towards Gram-positive bacteria in the case of derivatives containing residues of thioglycolic acid S-modified with ferrocene, the antibacterial activity being similar to that of amoxicillin, carbenicillin and cephalothin. All compounds are inactive towards Gram-negative bacteria. 相似文献
48.
49.
Electric fields of the anions, cations and neutral forms of 2-aminopurine and 6-thioguanine have been mapped. Certain important
features of the maps are similar to those found earlier in the neutral and ionic forms of adenine and guanine. The computed
electric field patterns satisfactorily explain reactive sites and biological activity of the molecules. 相似文献
50.
本文叙述了用于定量分析电镀添加剂中丙烯磺酸钠和糖精钠的快速、准确、精密的NMR分析方法.该方法是依据每个组分的NMR特征信号和用作内标的四甲基澳化按NMR信号的积分比值建立的,各组分不需要预先分离. 相似文献