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41.
魏芹芹 《山东理工大学学报:自然科学版》2006,20(5):68-71
用阳极电流腐蚀法制备多孔硅(PS),并将其分散到无水乙醇中形成溶胶.用荧光光谱仪测定了多孔硅溶胶的荧光强度与浓度的关系,研究了不同表面活性剂的掺入对溶胶体系的稳定性及其荧光强度的影响.进行了多孔硅溶胶的电迁移实验,并发现不同的表面活性剂的加入可使多孔硅溶胶带不同电荷,从而使多孔硅溶胶的电迁移变的可控.用扫描电镜(SEM)和X光电子能谱(XPS)对多孔硅溶胶电迁移沉积层进行了对比分析.研究表明,溶胶体系中表面活性剂的加入对沉积层的成分没有影响,可以用这种方法实现多孔硅纳米粒子的可控组装. 相似文献
42.
《Analytical letters》2012,45(15):1127-1132
Abstract Disc electrophoresic can be used to determine if uncookee beef and beef products have Seen adulterated with meat from horses, hogs, deer, and buffalo. 相似文献
43.
《Journal of Coordination Chemistry》2012,65(11):1945-1958
To explore anti-tumor activities of manganese complexes, two complexes have been synthesized and characterized. Complex 1 is bridged by 1,10-phenanthroline and 2,4-biphenyl dicarboxylate. The two complexes have strong fluorescent emission and interact with DNA in an intercalative mode. The complexes also exhibit significant cytotoxic specificity and cancer cell inhibition. 相似文献
44.
Patrik Vrábel 《Journal of luminescence》2006,118(2):283-292
Capillary electrophoresis with laser-induced fluorescence detection (CELIF) is a powerful tool for separation and sensitive determination of fluorescent species. Biologically active compounds, such as amino acids, peptides and proteins may exhibit native fluorescence, which is however often low and/or an expensive laser is required for excitation in UV. Therefore, labelling of the analytes with a fluorescent dye is usually necessary.In this work, a home-built CELIF instrument with diode pumped frequency-doubled continuous wave Nd:YAG excitation laser with feedback power regulation (532 nm) was constructed. The suitability of this type of laser for LIF detection in a separation method was found excellent. A limit of detection (LOD) (S/N=3) of 2×10−13 mol/l was achieved with rhodamine B, which is comparable to those obtained using similar instruments with Ar+ laser [Y.F. Cheng, N.J. Dovichi, Science 242 (1988) 562, E.S. Yeung et al., J. Chromatogr. 608 (1992) 73]. LOD of a protein derivatized according to modified procedures [M.J. Little et al., Anal. Chim. Acta 339 (1997) 279, A. Chersi et al., Biochim. Biophys. Acta 1336 (1997) 83] was determined. Detection of the derivatives was found to be limited by insufficient reaction recovery at low analyte concentration, chemical noise, separation efficiency and quality of the derivatizing reagent rather than by the detector performance. As a consequence, a huge gap between the detection ability of CELIF instruments and LOD determined in real samples is revealed. 相似文献
45.
The volume phase transition in gels induced by visible light and its related properties are presented, the mechanism of which is based on local heating of a polymer network by illumination of light. The gels consist of a covalently cross-linked copolymer network of thermosensitive N-isopropylacrylamide and a chromophore. Without light illumination, the gel volume changes sharply, but continuously at approximately 34°C when the temperature is varied. At a fixed temperature of an appropriate value, a discontinuous volume transition is observed when the light intensity is gradually changed. The phase transitions can be understood in terms of the temperature increment at the immediate vicinity of polymer chains due to the local heating via light absorption and subsequent thermal dissipation of light by the chromophore. The results can be qualitatively described by the Flory-Huggins mean-field equation of state of gels. In order to make clear the mechanism of the light-induced phase transition in the present system, we measured the light transmitting properties and the swelling as well as shrinking kinetics. These preliminary results are described semi-qualitatively by making use of a simple phenomenological model. 相似文献
46.
东方欧鳊(Abramis brama orientalis Berg)源于苏联咸海,我区伊犁河和额尔齐斯河均有分布,由于地理隔离的结果,两水系的东方真鳊已在形态学上出现了某些差异,为进一步探明二者间的亲缘关系,我们进行了鱼肉蛋白质含量、鱼肉氨基酸组成,LDH同工酶、血清蛋白等生化指标的比较研究,结果表明除了氨基酸组成及含量基本未发生变化外,其余三项指标均有显著不同,即说明两水系的东方欧鳊已出现种群间差异,至于是否已分化成两个不同的亚种,尚待进一步研究. 相似文献
47.
48.
应用毛细管区带电泳(CZE)分析测定阿片受体、抗独特型抗羟甲芬太尼抗体等生物大分子样品。熔融石英毛细管柱为60cm×100μmi.d.(从进样到检测器长度为50cm),以硼砂-氢氧化钾为缓冲液。结果表明缓冲液的pH影响CZE对阿片受体的分析,当pH为9.0时分析效果最理想,重现性良好,测得的两个主峰与同批样品进行SDS-PAGE分析得到的两个条带相符。用CZE分析抗独特型抗羟甲芬太尼抗体(IgG),表明用PrOteinA-Sepharose亲和色谱分离得到部分纯化的IgG,迁移时间不同于对照豚鼠的IgG。 相似文献
49.
The carbon-13 chemical shifts of seven N-(4-substituted phenyl) piperidine; the corresponding N-oxides, and their thermal rearrangement products were analyzed and assigned. The N-oxidation effect on the carbon-13 chemical shift is discussed, a correlation of N-oxidation effect with substituent constant (σp, σm, σI and σR) has been studied; dual substituent-parameter equation produce better correlation. 相似文献
50.
Shuai Zhang Guangsu Huang Jinrong Wu 《Journal of Macromolecular Science: Physics》2013,52(11):2203-2213
In this work, the aqueous solution rheology properties of both partially hydrolyzed polyacrylamide (HPAM) and the template copolymer (TPAM) synthesized from acrylic acid (AA) and acrylamide (AM) were investigated using an advanced rheometer and viscometer. The results were correlated with the corresponding molecular structures of HPAM and TPAM, which were characterized by high-resolution nuclear magnetic resonance. It was found that the thickening ability of TPAM is much stronger than that of HPAM due to its unique microblocky structure, while the viscosity of TPAM was more sensitive to shear rate. Furthermore, the effect of polymer concentration was also tested in an oscillation shear mode. It showed that the characteristic relaxation time of TPAM was much higher than that of HPAM at the high concentrations. The research on salt-resistance properties showed that the viscosity retention of TPAM was similar to HPAM at the same NaCl concentration. But, unexpectedly, at the same CaCl2 concentration the viscosity retention of TPAM was much lower than that of HPAM, indicating a poor divalent salt-resistance property. 相似文献