STRUCTURE OF CRYSTALLINE DOMAINS IN SEMICRYSTALLINE BLOCK COPOLYMER THIN FILMS

Thin film morphology of a symmetric semicrystalline oxyethylene/oxybutylene diblock copolymer （E76B38） on silicon was investigated by tapping mode atomic force microscopy （AFM）. It is found that the nascent thin film is composed of multiple polymer layers having mixed thicknesses of L ≈ L0 and L ≈ L0/2 （L0 is the long period of the block copolymer in bulk） besides the first layer near the substrate. This shows that the crystalline domain in the block copolymer consists of double poly（oxyethylene） layers. Annealing leads to disappearance of the polymer layers with thickness L ≈L0/2, indicating that such polymer layers are metastable.     

嵌段共聚物/均聚物共混体系的结晶行为 I. 非球状共聚物胶束的作用

将Leibler, Whitmore和Mayes等近期关于非晶嵌段共聚物“稀固体溶液”的理论应用于嵌段聚共聚物结晶型“稀固体溶液”结晶行为的研究。发现球状共聚物胶束既可起成核剂作用, 也可起抑制成核作用。报导了当共聚物胶束由球形变为非球形时, 共聚物胶束的上述作用都会发生较大的变化, 并根据Leibler和Mayes分别提出的球形和非球形胶束理论解释了这一实验现象。     

利用地表化探详查方法确定断块油藏边界

对我国东部某断块油田进行了地表化探详查研究．采用０．２５ｋｍ×０．２５ｋｍ测网，通过地表土壤介质的地化分析，确定了该油田长期以来悬而未决的油藏边界，建立了断块油气藏可能的异常模式，并从油气化探角度提出了对该油藏进行进一步钻探的合理化建议．该项试验成果表明，利用地表化探详查的方法确定我国东部断块油藏的边界和含油层分布是可行的．     

一类循环分块矩阵的一些结果

引进了Ｒ－循环分块矩阵的概念，讨论了它的一般性质，特别，当Ｒ＝Ｉ时，得到了其块谱分解宣，矩阵范数意义下的圆盘定理以及非奇异的几个充分条件。     

页岩气水平井地质信息解析与三维构造建模

页岩气开发具有开发评价期短,评价井少（直井）的特点,直井密度低增加了储层精细描述和地质建模的技术难度。因此,建立研究区地层的岩性、物性和电性特征的定量识别标准,利用该标准对水平井水平段开展精细小层划分,并对实际钻遇地层厚度进行校正,将水平井水平段等效为多口平面分布的直井。在此基础上,以水平井段解析的各小层数据资料作为控制点,建立研究区精细构造模型。水平井多点地质信息解析,将水平段等效为多口评价井获取相关地质参数资料,可有效地弥补评价井资料少的不足。     

溶剂去除速度对于溶剂退火薄膜相形貌的影响

以聚苯乙烯-聚4-乙烯基吡啶(PS-b-P4VP)嵌段共聚物作为研究对象,采用DMF作为退火溶剂,以原子力显微镜(AFM)和透射电子显微镜(TEM)为表征手段,研究了溶剂退火后期溶胀薄膜中溶剂的去除速度对于薄膜相形貌的影响,发现通过改变溶剂去除速度可以有效的调控薄膜中的形貌.当薄膜厚度为35 nm时,DMF的快速挥发会导致薄膜中形成以PS为分散相的反转柱状相结构,当降低溶剂的挥发速度时,薄膜中形成了以PS为分散相的环状形貌,当进一步减缓挥发速度时,薄膜中将形成台阶状的片层结构;然而当薄膜厚度为55 nm时,溶剂退火后期薄膜中形成的是以P4VP为分散相的正常柱状相结构,在相同溶剂去除速度条件下薄膜相形貌变化较小.     

Direct synthesis of Poly(Ԑ-Caprolactone)-block-poly (glycidyl methacrylate) copolymer and its usage as a potential nano micelles carrier for hydrophobic drugs

Ring-opening (ROP) and enzymatic copolymerization (ECP) are among the most widely used approaches for synthesizing copolymers of polycaprolactone (PCL). It involves multiple-step reactions and the utilization of enzymes that make the process a lot more complicated, time consuming, and expensive. Atom transfer radical polymerization (ATRP) has been adopted to synthesize a novel amphiphilic copolymer in our study. The study presents a method to eliminate the ROP/ECP multiple steps in monomer polymerization thus making the process simpler and smoother. The synthesis of cationic polymer micelles copolymer of PCL-PGMA (polycaprolactone grafted poly glycidyl methacrylate) was carried out using direct functionalization of hydroxy group in crude PCL to achieve a higher degree of functionalization, i.e., 12.8% for macroinitiator. FTIR and ¹H-NMR confirmed the successful synthesis of the copolymer with better control over the molecular weight with a PDI (1.84). DSC and XRD results showed the reduction of crystallinity by 86.81%, making copolymer more compatible for drug delivery application. The synthesized copolymer was further converted to nano-micelles drug carrier having an average size of 96.08 ± 21.22 nm. The drug encapsulation efficiency achieved was 60.0 ± 1.7%, and nano-micelles rendered a slow and controlled release of naproxen with long-term storage stability.     

Getting to the bottom morphology of block copolymer thin films

We demonstrate a general approach for attaining the bottom morphology of block copolymer(BCP) thin films. In our former measurements on PS-b-PMMA films, surface morphology maps of the BCP films revealed distinct ordering regimes where the cylinders orient predominantly perpendicular or parallel to the interface and an ‘intermediate' regime where these morphologies coexist. However, this earlier work did not explore the bottom morphology of BCP thin films. In this study, we investigated the block copolymer morphology near the solid substrate in the cast block copolymer film having a perpendicular cylinder morphology on the surface.