Synthesis and characterization of indium and thallium immobilized on isonicotinamide‐functionalized mesoporous MCM‐41: Two novel and highly active heterogeneous catalysts for selective oxidation of sulfides and thiols to their corresponding sulfoxides and disulfides

Two highly ordered isonicotinamide (INA)‐functionalized mesoporous MCM‐41 materials supporting indium and thallium (MCM‐41‐INA‐In and MCM‐41‐INA‐Tl) have been developed using a covalent grafting method. A surface functionalization method has been applied to prepare Cl‐modified mesoporous MCM‐41 material. Condensation of this Cl‐functionalized MCM‐41 with INA leads to the formation of MCM‐41‐INA. The reaction of MCM‐41‐INA with In(NO₃)₃ or Tl(NO₃)₃ leads to the formation of MCM‐41‐INA‐In and MCM‐41‐INA‐Tl catalysts. The resulting materials were characterized using various techniques. These MCM‐41‐INA‐In and MCM‐41‐INA‐Tl catalysts show excellent catalytic performance in the selective oxidation of sulfides and thiols to their corresponding sulfoxides and disulfides. Finally, it is found that the anchored indium and thallium do not leach out from the surface of the mesoporous catalysts during reaction and the catalysts can be reused for seven repeat reaction runs without considerable loss of catalytic performance.     

高温作用后砂岩物理力学性质阈值温度的确定——基于机器学习算法

通过采用机器学习算法，提出了高温作用后砂岩物理力学性质变化的阈值温度的确定方法。基于Python语言，利用K-Means、SVM算法，实现了对样本数据的分类和聚类，确定了阈值温度区间，验证了二分类法的合理性和准确性.结果表明，砂岩样本的阈值温度区间为400~600 ℃，阈值温度上下砂岩的物理力学性质存在显著差异，体现为阈值温度区间以下的岩样物理力学性质较为分散，而阈值温度区间以上的岩样物理力学性质较为集中.     

回眸百年再启程:中国科技社团发展的历史进程与主要贡献

 19世纪末20世纪初在中华大地上兴起学会热潮，尤其是“五四”新文化运动以来，现代意义上的科技社团在中国已经走过了百年历程，构成世界科技社团发展史上波澜壮阔的画卷之一。在纪念“五四”运动100周年之际，回顾科技社团百年来发展历程，研究分析科技社团在中国科学文化启蒙、科学技术发展和经济社会建设中的重要作用，对于探寻新时代中国科技社团发展道路，具有重要的理论和现实意义。     

Path integral quantization corresponding to the deformed Heisenberg algebra

In this paper, the deformation of the Heisenberg algebra, consistent with both the generalized uncertainty principle and doubly special relativity, has been analyzed. It has been observed that, though this algebra can give rise to fractional derivative terms in the corresponding quantum mechanical Hamiltonian, a formal meaning can be given to them by using the theory of harmonic extensions of function. Depending on this argument, the expression of the propagator of the path integral corresponding to the deformed Heisenberg algebra, has been obtained. In particular, the consistent expression of the one dimensional free particle propagator has been evaluated explicitly. With this propagator in hand, it has been shown that, even in free particle case, normal generalized uncertainty principle and doubly special relativity show very much different result.     

市级党校图书馆功能转变研究

为了更好应对信息技术发展带来的挑战，市级党校图书馆应明确功能定位，确定图书馆功能转变的路径方式，客观分析影响图书馆功能转变的不利因素，制定具体措施，实现市级党校图书馆的功能转变。     

Recent Progress in the $L_p$ Theory for Elliptic and Parabolic Equations with Discontinuous Coefficients

In this paper, we review some results over the last 10-15 years on elliptic and parabolic equations with discontinuous coefficients. We begin with an approach given by N. V. Krylov to parabolic equations in the whole space with $\rm{VMO}_x$ coefficients. We then discuss some subsequent development including elliptic and parabolic equations with coefficients which are allowed to be merely measurable in one or two space directions, weighted $L_p$estimates with Muckenhoupt ($A_p$) weights, non-local elliptic and parabolic equations, as well as fully nonlinear elliptic and parabolic equations.     

测绘工程专业CAD课程教学改革与实践

结合测绘工程专业本身的特点，该文首先介绍了CAD课程的作用，分析了该课程的教学现状，总结了在现实教学中存在的问题，进一步引出教学改革的必要性。接下来结合实际教学经验，分别从课程的教学内容、教材的选择、教学方法与教学手段、考核方式、师资队伍建设等方面探讨了AutoCAD教学的改革措施，对提高CAD课程教学质量，培养学生实际动手能力，更好地将CAD应用到专业中，适应实际行业工作需求，具有十分重要的意义。     

高校校园文化景观设计创意和表达

高校校园的文化景观不仅对其师生有潜移默化的教育作用,更会传达给师生归属感和认同感.以上海应用技术学院奉贤校区的"思贤庭"为例,在设计中结合地理位置、学科特色、功能定位、校园文化特色等,从场地原有的精神特性、历史文脉出发,演绎推导出校园文化景观的语境、符号等要素,形成了较有典型意义的校园文化景观表达模式.指出,文化景观创意的表达无需说教,可用"只言片语"的形式含蓄表达,重要的是营造出既符合功能需求又具有灵性的校园户外空间.     

基于化学学科认知障碍突破的中考复习教学实践* ——以“二氧化碳的性质”为例

分析学生对二氧化碳的3个典型学科认知障碍,以“二氧化碳的捕捉”为情境,通过“尝试捕捉二氧化碳”“谁在捕捉二氧化碳”“捕捉背后的原理”等3个主要环节,实现对学科认知障碍的突破,展示了一种新的中考复习教学思路。     

Cycloparaphenylene (CPP) series are molecular models for graphene armchair edges: trends in their aromaticity and cyclic conjugation are evaluated

Cycloparaphenylene ([r]CPP) and cyclacene ([r]CA) series are models for short carbon nanotubes. It is shown that armchair edges in model cycloparaphenylenes possess greater aromaticity and cyclic conjugation than do zigzag edges in model cyclacenes. According to Aihara’s bond resonance energy (BRE) and Bosanac and Gutman energy effect (ef) measurements, cycloparaphenylenes are twice as aromatic as cyclacenes. The general solution of all eigenvalues of all members of the cycloparaphenylene series is given. The origin of the recurrence of some eigenvalues are determined.