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41.
Previous work carried out in our laboratories has focused on the formation and investigation of a dextran and concanavalin A (con A) based gel, which has the ability to alter its conformational structure in the presence and absence of free and terminal glucoses such that a gel–sol phase transition occurs. Here we report the diffusion and rheological investigations in to the effects of the addition of insulin and varyingconcentrations of magnesium chloride hexahydrate (Mg2Cl26H2O) at 20 and 37 °C. Rheological examination of glucose-sensitive (dextran-con A) gels were conducted using a cone and plate viscometer used in continual rotation and oscillatory modes. The results are interpreted in terms of the structure of the gel network and suggest rheological assessment provides an effective method of assessing the properties of gel systems. The subsequent testing of such formulations in in-vitro diffusion experiments revealed a reduction in the rate of diffusivity in the insulin marker, poly R-478 dye. The performance of this self-regulating drug delivery system has been examined and the addition of insulin and magnesium chloride may alter the way in which the gel operates as a drug delivery device and in the delivery of insulin. This may have implications for other ligands. 相似文献
42.
复合桩基中承台内区土阻力群桩效应系数的有限元分析 总被引:1,自引:0,他引:1
采用有限元方法,对复合桩基中承台内区土阻力群桩效应系数进行了分析,并编制了相应的有限元程序。应用该程序讨论了桩距、桩数、桩长、土类等对承台内区土阻力群桩效应系数的影响。 相似文献
43.
Duygu Avci Aylin Ziylan Albayrak 《Journal of polymer science. Part A, Polymer chemistry》2003,41(14):2207-2217
Two phosphorus‐containing acrylate monomers were synthesized from the reaction of ethyl α‐chloromethyl acrylate and t‐butyl α‐bromomethyl acrylate with triethyl phosphite. The selective hydrolysis of the ethyl ester monomer with trimethylsilyl bromide (TMSBr) gave a phosphonic acid monomer. The attempted bulk polymerizations of the monomers at 57–60 °C with 2,2′‐azobisisobutyronitrile (AIBN) were unsuccessful; however, the monomers were copolymerized with methyl methacrylate (MMA) in bulk at 60 °C with AIBN. The resulting copolymers produced chars on burning, showing potential as flame‐retardant materials. Additionally, α‐(chloromethyl)acryloyl chloride (CMAC) was reacted with diethyl (hydroxymethyl)phosphonate to obtain a new monomer with identical ester and ether moieties. This monomer was hydrolyzed with TMSBr, homopolymerized, and copolymerized with MMA. The thermal stabilities of the copolymers increased with increasing amounts of the phosphonate monomer in the copolymers. A new route to highly reactive phosphorus‐containing acrylate monomers was developed. A new derivative of CMAC with mixed ester and ether groups was synthesized by substitution, first with diethyl (hydroxymethyl)phosphonate and then with sodium acetate. This monomer showed the highest reactivity and gave a crosslinked polymer. The incorporation of an ester group increased the rate of polymerization. The relative reactivities of the synthesized monomers in photopolymerizations were determined and compared with those of the other phosphorous‐containing acrylate monomers. Changing the monomer structure allowed control of the polymerization reactivity so that new phosphorus‐containing polymers with desirable properties could be obtained. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 2207–2217, 2003 相似文献
44.
贾海燕 《科技情报开发与经济》2007,17(33):262-263
介绍了直流大功率模拟电阻的原理,分析了直流大功率模拟电阻在计量中的运用,提出了使用9920匝比测量仪器时的接线方法。 相似文献
45.
综述了国外VA菌根影响宿主植物的抗旱性、耐盐性、抗低温性、抗重金属毒害及抗病虫害能力等方面的研究成果,同时提出了VA菌根真菌影响植物抗逆性问题。 相似文献
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Conductive composite films of poly(styrene‐co‐n‐butylacrylate) copolymers filled with low‐density, Ni‐plated core‐shell polymeric particles were prepared and their behaviors of positive temperature coefficient of resistance (PTCR) were investigated. When the conductive fillers in the composite film were loaded beyond the critical volume, 10 up to 25 vol %, composite films exhibited a unique electrical resistant transition behavior, which the electrical resistance rapidly increased by several orders of magnitude at the critical temperature. The PTCR transition temperature, in general, occurred before the glass transition temperature of polymer matrix. Further increased the conductive filler loading to 30 vol %, the overpacked conduction paths were formed in the entire composite and the PTCR effects became blurred. While the composite film treated with thermal cycle several times from room temperature up to 120 °C, the electrical resistivity increased accompanied with the shift of the PTCR transition to lower temperature. The reason might have been caused by the formed interfacial cracks within the composite film. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 322–329, 2007 相似文献
49.
本文把扩展电阻法应用于陶瓷微区电导性能研究.建立了微区的定位标识系统,可精确、方便地对选定的微区进行电导性能及组分的重复测定.该方法在研究Ba(Sn_(1-x)Sb_x)O_3、ZnO及BaTiO_3半导体瓷应用中得到有意义的结果. 相似文献
50.
硬盘驱动器巨磁电阻(GMR)磁头:从微米到纳米 总被引:7,自引:0,他引:7
近年来电脑硬盘存储密度的飞速增长(年增长100%)已超出摩尔定律的预言.这种惊人的高速增长中,最关键的因素是自旋阀纳米多层膜结构,即巨磁电阻(GMR)读传感器磁头的应用.事实上,巨磁电阻磁头读传感器(reader sensor)已经实现由微电子器件向纳米电子器件转化,并且形成大规模产业.这一过程包含了自旋电子学、材料科学、微电子工程学、化学、微机械力学和工程学等诸学科和相关微加工技术综合性挑战极限,进入纳米科技领域实质性进步. 相似文献