全文获取类型
收费全文 | 1128篇 |
免费 | 32篇 |
国内免费 | 68篇 |
专业分类
化学 | 207篇 |
晶体学 | 4篇 |
力学 | 140篇 |
综合类 | 1篇 |
数学 | 103篇 |
物理学 | 579篇 |
综合类 | 194篇 |
出版年
2024年 | 1篇 |
2023年 | 13篇 |
2022年 | 19篇 |
2021年 | 11篇 |
2020年 | 19篇 |
2019年 | 17篇 |
2018年 | 21篇 |
2017年 | 24篇 |
2016年 | 35篇 |
2015年 | 34篇 |
2014年 | 71篇 |
2013年 | 89篇 |
2012年 | 59篇 |
2011年 | 91篇 |
2010年 | 47篇 |
2009年 | 96篇 |
2008年 | 79篇 |
2007年 | 57篇 |
2006年 | 35篇 |
2005年 | 43篇 |
2004年 | 37篇 |
2003年 | 30篇 |
2002年 | 30篇 |
2001年 | 34篇 |
2000年 | 27篇 |
1999年 | 21篇 |
1998年 | 19篇 |
1997年 | 26篇 |
1996年 | 22篇 |
1995年 | 17篇 |
1994年 | 18篇 |
1993年 | 24篇 |
1992年 | 10篇 |
1991年 | 4篇 |
1990年 | 15篇 |
1989年 | 4篇 |
1988年 | 10篇 |
1987年 | 7篇 |
1986年 | 2篇 |
1985年 | 1篇 |
1983年 | 2篇 |
1982年 | 2篇 |
1981年 | 1篇 |
1979年 | 2篇 |
1978年 | 1篇 |
1977年 | 1篇 |
排序方式: 共有1228条查询结果,搜索用时 0 毫秒
41.
Mohammad A. Mottaleb T. W. Moy J. H. Zimmerman 《International journal of environmental analytical chemistry》2013,93(10):743-756
Musk xylene (MX) is frequently used as a fragrance in commercial toiletries. Biotransformation of MX into 4-amino-MX (4-AMX) and 2-amino-MX (2-AMX) metabolites in rainbow trout haemoglobin (Hb) has been described. The dose–response relationship and toxicokinetics of the metabolites as adducts in the Hb were determined by gas chromatography (GC)–electron capture negative chemical ionization (NCI)–mass spectrometry (MS), and GC–electron ionization (EI)–MS/MS, using selected ion monitoring (SIM). The trout were subjected to a single exposure of 0.010, 0.030, 0.10, and/or 0.30?mg?MX/g of fish. Hb samples were collected from exposed and control fish, and analysed subsequent to exposure at intervals of 24, 72, and 168?h. Alkaline hydrolysis released 4-AMX and 2-AMX metabolites from the Hb, and the solutes were extracted into n-hexane. The extracts were preconcentrated and analysed. The presence of the metabolites in the Hb extracts was confirmed based on agreement of similar mass spectral features from NCI/MS and EI-MS/MS spectra, and retention times of the metabolites with standards. The NCI/MS results were used for dose–response and toxicokinetics measurements. For dose–response, the concentrations of adducts of the metabolites increased with dosage, and a maximum adduct formation was observed at 0.10?mg?g?1, beyond which it decreased. The average concentrations of 4-AMX and 2-AMX at a dosage of 0.10?mg?g?1 were 700 and 7.4?ng?g?1, respectively. For toxicokinetics, the concentration of the metabolites in the Hb reached a maximum in the 3 day sample after administration of MX. Further elimination of the metabolites exhibited kinetics with a half-life estimated to be 1–2 days, assuming first-order kinetics. Quantitations were made based on an internal standard and a calibration plot. In control samples, non-hydrolysed Hb, and reagent blank extracts, the metabolites were not detected. The limits of detection for 4-AMX and 2-AMX in the Hb were approximately 1.7 and 1.4?µg?L?1, respectively, based on a signal-to-noise ratio of 3 with NCI/MS. 相似文献
42.
光子晶体光纤非线性系数与其结构参量及光波长的关系 总被引:24,自引:18,他引:6
推导计算了全内反射型光子晶体光纤的非线性系数与其两个几何结构参量:包层空气孔半径和空气孔间距之间的关系,给出了输入光波长为1550 nm处,非线性系数与这两个结构参量之间的关系曲线并对其进行了分析.给出了全内反射型光子晶体光纤的非线性系数随输入光波长变化的曲线,分析了短波处高非线性系数产生的原因并指出这一特性的应用潜力. 相似文献
43.
连续级联喇曼光纤激光器耦合波方程的修正 总被引:2,自引:1,他引:1
从最基本的耦合波方程出发,考虑光波正反向传输的情况下,推导出了一个全面的、准确的关于连续级联喇曼光纤激光器的理论模型,描述了各级Stokes光波功率沿光纤长度的变化.指出了相关一些文献中存在的不足,并且给出了多级斯托克斯光波相互作用的有效作用面积的表达式.此模型有助于喇曼光纤激光器的设计. 相似文献
44.
45.
46.
《Physics letters. A》2020,384(31):126794
An analytical approach for the electronic stopping force for non-relativistic energies that has no adjustable parameters has been developed. The approach combines the Bohr model for the close collisions and the Firsov model for the distant collisions. In order to combine the two models, a probabilistic model was introduced. We have applied our model to 16O in 12C, 16O in 27Al, 84 Kr in 27Al, 5Li in 12C, 12C in 12C, and 132Xe in 12C systems and compared with SRIM/MSTAR software, the original Bohr model, the Firsov model and available experimental data. We have found that the calculated electronic stopping force values are in agreement with the general qualitative behaviour of the electronic stopping force as a function of particle velocity reported in the literature. The proposed analytical formula is expected to be valid for other projectile-target combinations but more experimental data are needed to verify this assumption. 相似文献
47.
《Wave Motion》2017
Two methods for computing the complex-valued effective wavenumber of a rough beam in the context of linear time-harmonic theory are presented. The roughness of the beam is modelled as a continuous random process of known characteristic length and root-mean-square amplitude for either the beam mass or the beam rigidity. The first method is based on a random sampling method, with the effective wave field calculated as the mean of a large ensemble of wave fields for individual realisations of the roughness. The individual wave fields are calculated using a step approximation, which is validated for a deterministic problem via comparison to results produced by an integral equation approach. The second method assumes a splitting of the length scale of the fluctuations and an observation scale, employing a multiple-scale approximation to derive analytical expressions for the effective attenuation rate and phase change. Numerical comparisons show agreement of the results of the random sampling method and the multiple-scale approximation for a wide range of parameters. It is shown that the effective wavenumbers only differ by a real constant between the cases of varying beam mass and rigidity. 相似文献
48.
Vijay S. Raykar 《Physics letters. A》2010,374(45):4618-4621
A differential effective medium theory together with Brownian motion is used to predict Effective Thermal Conductivity (ETC) of CNT nanofluids. ETC was influenced significantly by Brownian motion and enhancement was higher in dilute nanofluids. A theoretical model employing an effective volume fraction with dispersibility factor agrees well with experimental data. 相似文献
49.
There are over two million modern English words, thus English becomes a language with the largest vocabulary in the world. Moreover, English vocabulary is constantly being renewed and enlarged with the development of the society and advancement of science and technology. So vocabulary development becomes language learners’ top priority. Unfortunately, learning English words by rote can’t guarantee that students will have a large vocabulary, let alone enable students to make practical use of the words they h... 相似文献
50.
The binding energy of an off-center hydrogenic donor impurity in weakly oblate Ellipsoidal Quantum Dot (EQD), using the expansion method within the framework of effective mass approximation in strong confinement, is investigated. In this regard, the binding energies of different states of GaAs structures, as functions of the donor position and ellipticity parameter, are calculated. The results show that variations of binding energies are proportional to the ellipticity constant, the dot dimension and the location of impurity. 相似文献