Phase behavior and Li+ Ion conductivity of styrene‐ethylene oxide multiblock copolymer electrolytes

Solid polymer electrolytes are attractive materials for use as battery separators. Here, a molecular weight series of polystyrene–polyethylene oxide (PEO) multiblock copolymers was synthesized by the thiol–norbornene click reaction. The subsequent materials were characterized both neat and with a lithium bis‐(trifluoromethane)sulfonimide salt loading [(Li)/(EO)] of 0.1. In general, neat samples demonstrated crystallinity scaling with PEO content. Lithium ion‐containing samples had broad scattering peaks, half of which displayed disordered scattering, even at the lowest block molecular weights (polystyrene = 1 kg/mol, PEO = 1 kg/mol). Fitting of disordered scattering data, using the random phase approximation, yielded χ_RPA and R_g values that were compared with recent predictive work by Balsara and coworkers. The predictions were accurate near the volume fraction f_PEO = 0.5 but deviated symmetrically with volume fraction asymmetry. Samples were also analyzed by electrochemical impedance spectroscopy for their potential to conduct lithium ions. Samples with f_PEO ≥ 0.5 demonstrated robust conductivity, whereas samples below this volume fraction conducted very poorly, with one exception (f_PEO = 0.24). This work expanded upon our recently reported approach to multiblock copolymer synthesis, demonstrating the improved access of materials to further our fundamental understanding of multiblock copolymers. Copyright © 2016 John Wiley & Sons, Ltd.     

Ultra-fast chromatographic micro-assay for quantification of diphenidol in plasma: application in an oral multi-dose switchability trial

Pharmacokinetics of diphenidol (DPN) is limited due to the lack of analytical methodology. Here, a micro-assay for DPN quantification was developed, by coupling ultra-performance liquid chromatography with tandem mass spectrometry. The procedure involved plasma precipitation and injection of supernatant into UPLC with an Acquitytrade mark C18 column. Detection was in positive electrospray, following transitions of m/z 310.3 --> 292.3 and m/z 275.3 --> 230.2 for DPN and chlorphenamine (internal standard), respectively. The method was linear with a range of 4-400 ng/mL, and a 2 min run time. This method was applied in a switchability trial, where both formulations of DPN were bioequivalent.     

基于项目网络拆分决策的多项目协同调度问题建模

以大型工业品资源共享型节拍式流水装配过程为背景,提出基于项目网络拆分决策的多项目协同调度问题.根据装配过程作业的周期性调度需求,将单个项目的作业集合划分成共享资源的多个并行执行的协同子项目,以最小化节拍时间为目标,建立了项目网络拆分与项目调度同时决策的数学优化模型,设计了一种双层循环迭代算法以对模型进行求解.算法的上层是基于有效时序约束数量的作业划分构造型启发式算法,可在多项目网络之间调整作业的从属关系;算法的下层采用基于优先规则的启发式算法对上层拆分后的多项目网络进行求解,并将调度结果反馈至上层,通过循环迭代不断优化项目来调度计划.数据实验结果表明,所提算法能够有效提高资源利用率,且其求解质量和效率较高.     

多目标决策中定性指标的评价方法

多决策中的定性指标通常可以数学方法和数学模型来用评价和测定,但由于评价指标的模糊性,所获得的评价结果有时可能是不准确的。于是如何提高评价结果的精确度,便是多目标决策理论中研究的一个重要课题。本文对此进行了探讨,应用集值统计原理,获得了4个在不同情形下可以使用的评价方法。     

基于AutoCAD ASI的弹簧绘图与管理

介绍利用绘图软件ＡｕｔｏＣＡＤ的Ｃ语言开发系统ＡＤＳ（ＡｕｔｏＣＡＤＤｅｖｅｌｏｐｍｅｎｔＳｙｓ－ｔｅｍ）和数据库接口ＡＳＩ（ＡｕｔｏＣＡＤＳＱＬＩｎｔｅｒｆａｃｅ）开发出的弹簧绘图和管理模块,该模块利用数据库技术,开发方法体现了现代ＣＡＤ的技术思想,具有直观、方便和实用的特点．     

基于DCT域的自适应数字水印算法

针对离散余弦变换(DCT)的特点,提出一种自适应水印算法.选取JPEG量化矩阵若干DCT中频系数,并求均值,比较嵌入位与均值的关系,调整嵌入位的大小实现水印自适应嵌入.利用Arnold变换对水印信息进行预处理和后续处理,降低水印信息的相关性;同时用随机控制方法选取水印嵌入图像块,用于控制随机选取块的密钥作为该算法的一个密钥,实现水印的加密处理,提高水印的安全性.实验表明,该算法在保证隐蔽性的前提下,水印提取效果较好,对旋转、剪切、JPEG、修改等攻击具有较好的鲁棒性和稳健性.     

供应链网状结构中多级库存控制模型

基于供应链网状结构模型，提出了该模型的多级库存控制问题，引入前置时间和订单执行率等参量，分析了供应链上各节点企业发生的订货费、存贮费和运输费。在假定需求函数和前置时间函数是随机分布的前提下，研究了在保证供应链上中企业一定订单执行率的条件下，确定最佳订货批量和订货临界点的方法，使其应链上总的库存费用最低；并以三级库存模型为例，给出了一种验证模型的方法，该模型能完整地表示多级库存系统中各实体之间的活动和相互关系，有效降低供应链上的库存成本，增强供应链的协调性。     

Electrochemical Sensor for Sensitive Determination of Ga(III) Ion Based on β‐Cyclodextrin Incorporated Multi‐walled Carbon Nanotubes and Imprinted Sol‐gel Composite Film

A novel sensor for detection of trace gallium ion [Ga(III)] was created by stepwise modification of a gold electrode with β‐cyclodextrin (β‐CD)/multi‐walled carbon nanotubes (MWCNTs) and an ion imprinted polymer (IIP). The sensor surface morphology was characterized by scanning electron microscopy. The electrochemical performance of the imprinted sensor was investigated by cyclic voltammetry, differential pulse voltammetry and chronoamperometry. The sensor displayed excellent selectivity towards the target Ga(III) ion. Meanwhile, the introduced MWCNTs displayed noticeable catalytic activity, and β‐CD demonstrated significant enrichment capacity. A linear calibration curve was obtained covering the concentration range from 5.0×10^?8 to 1.0×10^?4 mol·L^?1, with a detection limit of 7.6×10^?9 mol·L^?1. The proposed sensor was successfully applied to detect Ga(III) in real urine samples.