水平变化双层波导声传播问题的耦合简正波解

为了验证现有模型的精度,导出了全反射下边界双层波导中简正波耦合矩阵的解析表达式,并将其应用到全局矩阵耦合简正波模型(Direct Global Matrix Coupled-Mode)中,使得该模型可以提供水平变化双层波导问题的标准解。文中首先利用COUPLE的简正波及耦合矩阵数值解验证了该简正波及耦合矩阵解析表达式的正确性;其次,采用改进的DGMCM模型求解了双层波导海山声传播损失,结果表明,改进后的DGMCM模型可以非常精确地求解水平变化双层波导问题,可作为求解此类问题的标准模型使用。     

降低直接甲醇燃料电池浓差极化的含磺化碳管阻水夹层的构建

采用直接接枝法, 将来自对氨基苯磺酸的苯磺酸官能团引入氧化多壁碳纳米管, 制得磺化多壁碳纳米管(SO₃-MCNT). 再以SO₃-MCNT为填料, 以Nafion离聚物为黏结剂, 利用超声喷涂在商业N212质子交换膜一侧构建了新的膜层, 获得了一种复合膜(SO₃-MCNT?N212). 使用SO₃-MCNT?N212制备燃料电池膜电极(MEA), 并用于直接甲醇燃料电池(DMFC)测试. 与使用普通N212膜的膜电极相比, 该膜电极的性能得到明显提升. 进一步分析表明, SO₃-MCNT膜层的引入降低了阳极向阴极的跨膜水迁移作用, 缓解了阴极的水淹, 从而降低了浓差极化, 提升了膜电极的性能.     

扫描电化学显微镜在电催化表面反应分析中的现代应用

能源和环境问题成为制约未来可持续发展的关键问题之一,因此,针对不同电催化反应设计电催化剂变得越来越重要.电催化剂因其能量效率高、制备简单和易操作等优点,而应用于可再生能源的相关反应(如水分解和人工光合作用)中.明确不同反应电催化剂的设计原理,深入理解其在相关反应中的催化机理,可进一步优化催化剂性能.本文综述了扫描电化学显微镜(SECM)应用于电催化反应的历程、关键方法以及一些代表性的工作,阐明了电催化剂的工作机理以推进电催化剂的设计.本文还介绍了为提高SECM的空间分辨率而尝试的纳米尺寸电极方面的新进展,分享了纳米电极在以前研究无法涉及的单一催化实体方面的应用.     

Synthesis of 4-(thien-2-yl)-substituted coumarins through Lewis acid catalyzed Michael addition of thiophenes to 3-benzoylcoumarins followed by oxidation

3-Benzoyl-4-(thien-2-yl)coumarins have been obtained in good yields according to the S_N^H addition–oxidation protocol, involving the diastereoselective addition of thiophenes at C-4 of 3-benzoylcoumarins under BBr₃ catalysis, followed by oxidation of the intermediate 3,4-trans-3-benzoyl-4-(thien-2-yl)-3,4-dihydrocoumarins with DDQ. This two-step procedure can be regarded as nucleophilic substitution of hydrogen (S_N^H) on the heterocyclic ring of coumarins.     

On air-chemistry reduction for hypersonic external flow applications

In external hypersonic flows, viscous and compressibility effects generate very high temperatures leading to significant chemical reactions among air constituents. Therefore, hypersonic flow computations require coupled calculations of flow and chemistry. Accurate and efficient computations of air-chemistry kinetics are of much importance for many practical applications but calculations accounting for detailed chemical kinetics can be prohibitively expensive. In this paper, we investigate the possibility of applying chemical kinetics reduction schemes for hypersonic air-chemistry. We consider two chemical kinetics sets appropriate for three different temperature ranges: 2500 K to 4500 K; 4500 K to 9000 K; and above 9000 K. By demonstrating the existence of the so-called the slow manifold in each of the chemistry sets, we show that judicious chemical kinetics reduction leading to significant computational savings is possible without much loss in accuracy.     

Improving the efficiency of a direct ethanol fuel cell by a periodic load change

We present a simple method to increase the efficiency of a direct ethanol fuel cell by a periodic modulation of the load (pulsed mode). The fuel cell was periodically short circuited with a resistor (1...     

New type of heteroclinic tangency in two-dimensional maps

A new mechanism of heteroclinic tangency is investigated by using two-dimensional maps. First, it is numerically shown that the unstable manifold from a hyperbolic fixed point accumulates to the stable manifold of a nearby period-2 hyperbolic point in a piecewise linear map and that the unstable manifold from a hyperbolic fixed point accumulates to the accumulation of the stable manifold of a nearby period-2 hyperbolic point in a cubic map. Second, a theorem on the impossibility of heteroclinic tangency (in the usual sense) is given for a particular type of map. The notions ofdirect andasymptotic heteroclinic tangencies are introduced and heteroclinic tangency is classified into four types.     

Minimum cost spanning tree games

We consider the problem of cost allocation among users of a minimum cost spanning tree network. It is formulated as a cooperative game in characteristic function form, referred to as a minimum cost spanning tree (m.c.s.t.) game. We show that the core of a m.c.s.t. game is never empty. In fact, a point in the core can be read directly from any minimum cost spanning tree graph associated with the problem. For m.c.s.t. games with efficient coalition structures we define and construct m.c.s.t. games on the components of the structure. We show that the core and the nucleolus of the original game are the cartesian products of the cores and the nucleoli, respectively, of the induced games on the components of the efficient coalition structure.This paper is a revision of [4].     

最可几法在带电粒子径迹重建中的应用

本文介绍了用最可几法拟合具有非高斯型测量误差的空间径迹,与常用的最小二乘法拟合相比较,分辨率大大提高,因之也提高了识别真假径迹的可靠性.