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81.
在沉积序列、沉积特征和物性分析基础上,研究滇东-黔西地区二叠系龙潭组层序格架和致密储层类型及其空间展布规律。龙潭组是扬子板块在二叠纪碳酸盐台地基础上形成的以煤系为特点的海陆过渡相沉积,主要物源区是西部川滇地区,相带走向为北东-南西向。滇东-黔西一带靠物源一侧的西部地区以河流相细砂岩为主,往东为以含煤层系为特点的中间过渡相带和靠海一侧的河口湾海岸相带。龙潭组岩石类型主要有煤岩、泥页岩和致密砂岩,这3种岩石构成了3种致密天然气储层,都具有一定的含气性,但含气量从煤岩→泥页岩→致密砂岩具有逐渐变弱的变化规律。煤岩物性相对较好,泥页岩物性较差,致密砂岩物性最差。煤岩储层在黔西的大方-金沙-六盘水地区和滇东的富源-曲靖-罗平-丘北地区较为发育,三角洲平原、潮坪-潟湖相是煤层气发育的有利相带;往东南靠海方向主要发育泥页岩致密储层的潮坪-潟湖相带;致密砂岩储层主要发育在北西方向靠物源一侧的三角洲前缘亚相。煤岩和泥页岩在相邻的黔北地区、四川泸州、重庆永川和云南的弥勒、普者黑等地延展分布,这些区域的龙潭组可能存在相应的致密储层和天然气藏。 相似文献
82.
在川西拗陷中三叠统雷口坡组沉积背景研究基础上,通过岩心、薄片观察和测井、地震资料分析,运用层序地层学原理,研究雷四3亚段高频层序发育特征,对雷四3亚段进行精细层序地层对比,落实层序地层在研究区展布情况,探讨其发育控制因素及与储层发育的关系.雷口坡组可划分出2个Ⅲ级层序,雷四3亚段发育于第2个Ⅲ级旋回sQ2高水位体系域,进一步可识别出2个Ⅳ级层序和7个Ⅴ级层序.在高频层序划分的基础上,建立了雷四3亚段高频层序地层格架,以Ⅴ级层序为单元,对研究区雷四3亚段地层进行精细对比发现,层序地层横向具有较好的对比性,XS1井、DS1井、TS1井缺失顶部地层,分析认为与印支期地层剥蚀有关.川西拗陷雷四3亚段层序发育主要受海平面升降、构造运动及气候影响,Ⅴ级层序以向上变浅的旋回为主,溶蚀作用主要发育在Ⅴ级层序中上部,易形成优质溶蚀型储层. 相似文献
83.
储层流动单元研究可以更好地预测剩余油的分布,指导油田开发.以准噶尔盆地百口泉油田百21井区百口泉组冲积扇相储层为例,利用岩心、测井资料开展流动单元研究,在储层细分对比的基础上,采用定性与定量相结合的方法将研究区流动单元分为E,G,F,P等4种类型.描述了各类流动单元孔隙结构特征、空间分布规律及其与沉积微相间的相互关系.总结出冲积扇流动单元模式,并分析了各类流动单元与剩余油分布的关系.研究表明:冲积扇储层中E类流动单元多分布于主槽流沟的中心部位;G类流动单元多呈宽带状分布于主槽微相的沟间滩及侧缘槽微相砂体的侧翼;F类流动单元一般都在辫流砂岛、辫流滩地;P类流动单元一般分布在扇间滩地或漫洪、漫流带.剩余油多分布于横向渗流屏障附近流动单元的边缘部位和流动单元接合处. 相似文献
84.
东营凹陷沙河街组岩性油藏的形成与分布在宏观上受多种元素的控制,这些宏观地质控制因素包括构造带类型、沉积体系域类型、储集相类型、烃源岩条件和盆地温压条件等.根据岩性油藏的自身特点分析认为,东营凹陷沙河街组岩性圈闭能否成藏主要受到4大主控元素的控制,分别为岩性油藏输导通道因素、流体动力因素、储层临界物性因素、砂体封闭性因素.经研究在牛庄洼陷发现沙河街组岩性油藏具有“三元主控”的特征. 相似文献
85.
BiFeO3 perovskite with 2D laminated cylinder-like structure was prepared via a facile one-pot hydrothermal method, whose morphologies and optical properties was characterized using X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersion spectrum (EDS), and UV-Visible diffuse reflectance spectroscopy (UV-Vis DRS). The photocatalytic properties of the as-prepared BiFeO3 composites were evaluated according to degrading Rhodamine B (RhB) and desulfurization under visible light irradiation, with excellent photocatalytic degradation and desulfurization activity found. Moreover, the mechanism study of active free radicals in photocatalytic activity indicates that the h+ radical in holes was mainly responsible for synergistic catalytic efficacy in photocatalytic degradation. 相似文献
86.
Formation, crystal structure, polymorphism, and transition between polymorphs are reported for M(thd)3, (M = Al, Cr, Mn, Fe, Co, Ga, and In) [(thd)– = anion of H(thd) = C11H20O2 = 2, 2, 6, 6‐tetramethylheptane‐3, 5‐dione]. Fresh crystal‐structure data are provided for monoclinic polymorphs of Al(thd)3, Ga(thd)3, and In(thd)3. Apart from adjustment of the M–Ok bond length, the structural characteristics of M(thd)3 complexes remain essentially unaffected by change of M. Analysis of the M–Ok, Ok–Ck, and Ck–Ck distances support the notion that the M–Ok–Ck–Ck–Ck–Ok– ring forms a heterocyclic unit with σ and π contributions to the bonds. Tentative assessments according to the bond‐valence or bond‐order scheme suggest that the strengths of the σ bonds are approximately equal for the M–Ok, Ok–Ck, and Ck–Ck bonds, whereas the π component of the M–Ok bonds is small compared with those for the Ok–Ck, and Ck–Ck bonds. The contours of a pattern for the occurrence of M(thd)3 polymorphs suggest that polymorphs with structures of orthorhombic or higher symmetry are favored on crystallization from the vapor phase (viz. sublimation). Monoclinic polymorphs prefer crystallization from solution at temperatures closer to ambient. Each of the M(thd)3 complexes subject to this study exhibits three or more polymorphs (further variants are likely to emerge consequent on systematic exploration of the crystallization conditions). High‐temperature powder X‐ray diffraction shows that the monoclinic polymorphs convert irreversibly to the corresponding rotational disordered orthorhombic variant above some 100–150 °C (depending on M). The orthorhombic variant is in turn transformed into polymorphs of tetragonal and cubic symmetry before entering the molten state. These findings are discussed in light of the current conceptions of rotational disorder in molecular crystals. 相似文献
87.
Florian Breitsameter Hans-Peter Schrdel Alfred Schmidpeter Heinrich Nth Susana Rojas-Lima 《无机化学与普通化学杂志》1999,625(8):1293-1300
Ylide Adducts of Pentele Trichlorides Ylides Ph3PCR2 form 1 : 1 adducts with PCl3, AsCl3 und SbCl3. The addition of HCl to dichlorophosphanyl- und dichloroarsanyl ylides also leads to such adducts. In solution the PCl3 adducts 2 are dissociated into ions. For the AsCl3 adducts 3 b and 3 e of triphenylphosphonium ethylide and isopropylide X-ray analyses show distinctly different degrees of transition from a zwitterionic ψ-tbp to a cationic ψ-tetrahedral structure. The SbCl3 adduct 4 b of the triphenylphosphonium ethylide on the other hand forms a rather asymmetric dimer and approaches a square-pyramidal geometry at the antimony atom. The 2 : 1 ylide adducts 11 with PCl3 form in solution the dications (Ph3PCR2)2PCl2+. The 2 : 3 adduct 15 of triphenylphosphonium methylide to AsCl3 also has an ionic structure in the crystal. There are cations (Ph3PCH2)2AsCl2+, which pairwise join with two AsCl3 molecules to form doubly charged supracations in the presence of As2Cl82– as counterions. 相似文献
88.
Equilibrium Pressure Measurements in the System Se/O/Br The saturation pressure or saturation decomposition pressure of SeOBr2,l, Se2Br2,l and SeBr4,s were determined in a membran zero manometer. The decomposition behaviour follows from pressure measurements outside of saturation. From the equilibrium data are derived the Enthalpies of formation: Data see Inhaltsübersicht. Informations about the melting diagrams obtained via the barograms of the condensed compositions SeO2/SeBr4 and Se/Br. 相似文献
89.
GAO Sheng li ** CHEN San ping HU Rong zu SHI Qi zhen Shaanxi Key Laboratory of Physico Inorganic Chemistry Department of Chemistry Northwest University Xi′an P.R. China 《高等学校化学研究》2003,19(2)
IntroductionNickel is an essential trace biological element.L-α- Amino acids are the structural units of pro-teins.L- α- Histidine is one of the eight species ofamino acids which have to be absorbed from foodbecause they are not synthesized by organism.Thus,the investigation on the complexation ofnickel and L -α- histidine is of considerable practicaland fundamental importance.For the nickel com-plexes of amino acids,more extensive work hasbeen carried out[1— 3 ] . However,the thermochem… 相似文献
90.
Ghosh K Semwal A Nayak SK Banerjee SB Banerjee M 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2007,66(4-5):1122-1125
[60]- and [70]Fullerenes have been shown to form 1:1 supramolecular complexes with bis[2-(5,11,17,23,29,35-hexa-tert-butyl-37,38,39,40,41-pentahydroxycalix[6]arenyl-oxy ethyl ether) (1) and 5,11,17,23,29,35-hexa-tert-butyl-37,38,40,41-tetra hydroxyl-39,42-(crown-4)calix[6]arene (2) in CHCl3 medium by electronic absorption spectroscopy. Formation constants (K) of the complexes of [60]- and [70]fullerenes with 1 and 2 have been determined at room temperature from which free energy of formation values of the complexes have been estimated. The very high formation constant value of [60]fullerene/1 complex (5900 dm3 mol-1) in indicative of formation of inclusion complex. Moreover, PM3 calculations reveal that intermolecular interaction between [60]fullerene and 1 proceeds through quite deep energy molecular orbital. 相似文献