基团电负性与三甲基硅烷衍生物的标准生成热

利用前文建立的基因电负性,通过分析ΔΔfH~0(MeSiX/CH_3X)与基团电负性XG的关系,本文建立了两个计算ΔfH(Me_3SiX)的公式: ΔfH~0(Me_3SiX)=ΔfH~0(CH_3X)-15.18X_G-19.70 ΔfH~0(Me_3SiX)=ΔfH~0(HX)+(6.05p-15.18)X_G-16.08p-19.70 式中,X_G为基团X的电负性;X=F.0H、NH_2、Cl Br、SH.I.ΔfH~0(Me_3SiX)和ΔfH~0(HX)分别为Me_3SiX、CH_3X和HX的标准生成热,P为分子HX中氢原子的个数。两式计算的平均偏差分别为0.99 Kcal/mol和0.84Kcal/mol。同时,导出了一个计算Me_3Si—X键的键裂能的方法: DH(Me_3Si—X)=DH(CH_2—X)+15.18X_G-16.2, X=F、OH、NH_2、Cl、Br、SH、上式计算的平均偏差为0.99Kcal/mol。     

苏北高邮凹陷下第三系戴一段有机质类型及其地球化学特征

作者通过干酪根显微组分、元素,饱和烃色谱和色质谱,以及芳烃红外光谱等方法,对苏北高邮凹陷下第三系戴一段有机质类型特征和生油潜力进行了探讨。研究表明:戴一段存在着四种不同类型的干酪根,其中以Ⅲ类为主。Ⅰ类和Ⅱ类出现在顶部,是戴南组主要油源。本文为苏北油气勘探提供了重要依据。     

陕西韩城矿区三趾马红土层及三门组的发现

在韩城矿区象山山地,于二叠系之上,第四系黄土之下,发现了两套属于新生界的地层单位。根据岩性特点、地层层位和它们所处的地貌部位,可以认为,一套是上中新统三趾马红土层,一套是下更新统三门组。这一发现,增补了韩城矿区新生界地层资料,同时对全面认识矿区地质历史,正确评估新构造运动幅度,都具有重要意义。     

平顶山煤田山西组沉积体系与聚煤模式

讨论了河南平顶山煤田山西组的沉积体系和聚煤模式。文中提出山西组下段形成于碎屑障壁海岸环境,山西组上段为三角洲沉积体系的进积部分。已组煤形成于障壁海岸沉积体系的上部,其发育过程明显受到基底沉积环境的控制。已组煤的聚煤作用特征是沉积基底地形高差、压实沉降率与泥炭堆积速率之间的平衡关系随海平面变化而变化。己组煤发育的气候条件可能属热带背景。     

平庄西露天矿区元宝山组沉积体系分析

本文运用现代沉积学原理和方法．以丰富的地质资料为基础，把西露天矿区元宝山组自下而上划分为湖泊三角洲体系和扇三角洲体系、冲积扇体系、曲流河体系、辫状河体系．比较详细地剖析了各沉积体系的构成、特征，再现了聚煤期及其前后的沉积环境演化。     

High-quality hydrocarbon source rock in the Paleogene sequence of the Ping Chau Formation, Hong Kong

Although petroleum exploration is being conducted in the Hong Kong region, high-quality hydrocarbon source rocks have never been found in this area. The Ping Chau Formation is only Mesozoic-Cenozoic sedimentary rock exposed in Hong Kong and its surrounding areas. The hydrocarbon source rock of the Ping Chau Formation is very rich in organic matters, which has an average total organic carbon (TOC) of 1.9% and chloroform bitumen ““A““ range from 0.14% to 0.24%. The total hydrocarbon content varies from 880 to 1800 ppm and the transformation ratio is specific from 5 to 9. The index of pyrolytic hydrogen is up to about 600 mgHC/gTOC. These data demonstrate the characteristics of the high-quality hydrocarbon source rock. The lamalginite is the major maceral of the source rock of the Ping Chau Formation, and geochemical characteristics also suggest that the organic materials of the source rock are of type I and type Ⅱ1, with abundant gammacerane, γ, β-caro-tane and C24 tetracyclic terpane, which indicate that it was formed in the salt water and brackish water sedimentary environment, and the source rock has evolved into a mature phase. The organic inclusions are found within calcite veins in cracks of the source rock, indicating that hydrocarbon has been generated and a secondary migration has happened. The source rock in the Ping Chau Formation is about 200-300 m thick, thus having considerable hydrocarbon potential. The discovery of the high quality hydrocarbon source rock in the Ping Chau Formation will certainly provide insight on hydrocarbon resource exploration in the South China Sea area.