Dielectric properties of plasma polymerized PVCa and composite PVCa:Au films

Dielectric properties of plasma polymerized PVCa and composite PVCa:Au films had been analyzed in the frequency range from 10 to 10⁵ Hz. In order to explain experimental data obtained the modification of Maxwell-Garnett and Bruggeman self-consistent models for the case of three-component composite has been done. The theoretical analysis performed allows to determine peculiarities of dielectric behavior of a three-component system, as well as to disclose the procedure of evaluation of third-component parameters. Results of this analysis are in agreement with experimental ones.     

A novel type of Si-containing poly(urethane-imide)s: synthesis, characterization and electrical properties

A novel type of a Si-containing poly(urethane-imide) (PUI) was prepared by two different methods. In the first method, Si-containing polyurethane (PU) prepolymer having isocyanate end groups was prepared by the reaction of diphenylsilanediol (DSiD) and toluene diisocyanate (TDI). Subsequently the PU prepolymer was reacted with pyromellitic dianhydride (PMDA) or benzophenonetetracarboxylic dianhydride (BTDA) in N-methyl pyrolidone (NMP) to form Si-containing modified polyimide directly. In the second method, PU prepolymer was reacted with diaminodiphenylether (DDE) or diaminodiphenylsulfone (DDS) in order to prepare an amine telechelic PU prepolymer. Finally, the PU prepolymer having diamine end groups was reacted with PMDA or BTDA to form a Si-containing modified polyimide. Cast films prepared by second method were thermally treated at 160 °C to give a series of clear, transparent PUI films. Thermogravimetric analysis indicated that the thermal degradation of PUI starts at 265 °C which is higher than degradation temperature of conventional PU, confirming that the introduction of imide groups improved the thermal stability of PU.To characterize the modified polyimides and their films, TGA, FTIR, SEM and inherent viscosity analyses were carried out. The dielectrical properties were investigated by the frequency-capacitance method. Dielectric constant, dielectric breakdown strength, moisture uptake and solubility properties of the films were also investigated.     

Dielectric relaxation of ball-like labels in polyisoprene

Ball-like molecules with strong dipoles (labels) were mixed with synthetic polyisoprene (IR305) in low concentrations (<1%) and measured dielectrically in the frequency range 10^–2–10⁷ Hz and the temperature range –70–0°C (glass relaxation region). Calorimetric measurements showed that this type of label has a plasticizing effect on the polymeric matrix. The dielectric measurements showed that these ball-like molecules relax through cooperative rotations with the polymeric segments and at the same relaxation frequency. In addition, the label molecules showed a high-frequency local relaxation process. The relaxation strength ratio of the local process (X _local) to the total relaxation strength of the label was found to be dependent on the volume as well as on the shape of the label. A comparison between the relaxation behaviors of the ball-and rod-like molecules, having the same volume, showed that the length of the label is also an important parameter for the determination of the local contribution as well as of the cooperative relaxation mechanism of the label. The label relaxation process is discussed in relation to the molecular packing of the host polymer.     

Novel Catalytic Dielectric Barrier Discharge Reactor for Gas-Phase Abatement of Isopropanol

Catalytic gas-phase abatement of air containing 250 ppm of isopropanol (IPA) was carried out with a novel dielectric barrier discharge (DBD) reactor with the inner catalytic electrode made of sintered metal fibers (SMF). The optimization of the reactor performance was carried out by varying the voltage from 12.5 to 22.5 kV and the frequency in the range 200–275 Hz. The performance was significantly improved by modifying SMF with Mn and Co oxide. Under the experimental conditions used, the MnO _x /SMF showed a higher activity towards total oxidation of IPA as compared to CoO _x /SMF and SMF electrodes. The complete destruction of 250 ppm of IPA was attained with a specific input energy of ∼235 J/L using the MnO _x /SMF catalytic electrode, whereas, the total oxidation was achieved at 760 J/L. The better performance of the MnO _x /SMF compared to other catalytic electrodes suggests the formation of short-lived active species on its surface by the in-situ decomposition of ozone.     

土与结构间一种新接触单元的数值解

推导了基于非线性弹性-理想塑性本构模型的接触带单元的单元刚度矩阵，并对接触带厚度的确定、非线性迭代方法等数值计算中一些重要的细节问题进行了论述．最后对某一典型算例进行了分析，分析结果表明，所提出的接触带单元能够合理地模拟接触面上的变形机理和受力状态，是一种比较适用的模型，在土与结构相互作用分析中具有一定的应用前景。     

边坡抗滑稳定可靠性分析

为了利用一次二阶矩法计算边坡抗滑稳定的可靠指标，针对抗滑稳定分析中的条分法，提出了从极限条件出发，通过在边坡最上面一分条上施加一假想力，使得边坡整体处于极限平衡状态来构造用于Ｂｉｓｈｏｐ法进行可靠性分析的功能函数，并具体给出了基于Ｂｉｓｈｏｐ法进行可靠性的功能函数的推导过程，通过算例与用瑞典条分法、传递系数法进行可靠性分析的结果进行了比较。     

工作面滞后支承压力分布规律

为获得综采工作面滞后支承压力的分布规律,采用理论分析、数值模拟及现场实测的方法,对兖州矿区工作面滞后支承压力分布规律进行了分析.分层开采与综放开采工作面滞后支承压力变化规律是,随着采高的增大,工作面滞后支承力的距离加大,垂直应力集中系数差别不大.实例结果表明:分层滞后支承压力在工作面后方160～180m以外稳定,综放工作面在其后方200 m以外稳定.     

Java多线程同步机制平台相关性浅析

Java多线程具有很大的平台相关性，导致了其同步机制的平台相关性。通过试验讨论了Java同步机制在不同平台下的成功实现和实现效率，并分析了这种平台相关性的原因和影响因素，对处理多线程同步机制的Java程序的跨平台性编写和执行具有借鉴意义。     

5G切片化网络中基于吞吐量最大化的用户切换机制

第五代无线通信系统(the fifth generation,5G)利用网络功能虚拟化(network function virtualization, NFV)和软件定义网络(software defined network, SDN)2项技术将网络进行了切片划分,让用户接入不同服务质量(quality of service,QoS)保障的虚拟网络切片以获得服务。为了解决切片化网络中由于用户移动性而导致的切片重新接入问题,提出了最大化网络吞吐量的用户切换机制来降低越区切换对已有网络切片的影响。该机制根据用户业务类型的QoS服务等级筛选备选接入站点的归属切片,运用贪心算法选择能为用户提供最大数据传输速率的切片接入服务,在网络切片代理的体系架构下完成切换过程的控制和管理。在与功率接入、负载接入和随机接入3种切换方案的性能对比中,相关仿真结果表明,随着越区用户数目和网络切片类型的增加,所提方案在保证较高网络吞吐量的同时,切换成功率始终维持在80%以上,远优于其他3种方案。     

自然崩落法放矿方案初步优化

放矿方案优化是放矿优化控制和放矿管理的基础。以数字矿山软件平台和VC++为工具,进行自然崩落法放矿方案优化研究。首先确定放矿方案构成要素与放矿方案优化准则;在数字矿山软件平台上构建放矿优化三维模型,确定放矿水平及放矿边界;自动确定放矿结构参数及布置放矿点,建立放矿点和放矿分层的品位计算数据搜索模型,通过品位估值确定放矿点及放矿分层的品位分布;建立基于矿山利润的放矿资源价值模型,以金属市场价格、生产成本及贫损指标为基础输入参数,计算各放矿分层的价值和利润,得到放矿点的最佳放矿高度、担负矿量和出矿截止品位,从而确定放矿优化方案,并为放矿计划编制和管理提供数据。