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991.
S. I. Kuzina A. I. Mikhailov G. N. Nesterenko A. A. Shteinman 《Russian Chemical Bulletin》1996,45(4):824-826
-Irradiation of -oxo-bridged binuclear iron complexes FeIII
2OL
n
in a glycerol or dimethylformamide matrix at 77 K affords unstable mixed-valence FeIIFIII forms resulting from the transfer of a mobile electron generated by the ionizing radiation. These nonequilibrium forms retain the ligand environment of the original complexes, and their ESR spectra at 77–200 K are characterized by an asymmetric signal with an axially anisotropicg-factor, which is in agreement with the spectra of the FeIIFe syu forms obtained by chemical reduction.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 869–871, April, 1996. 相似文献
992.
Ser Peow Tan 《Geometriae Dedicata》1996,62(2):209-225
Let M be a compact orientable surface with nonempty boundary (x(M)<0) and fundamental group . Let be a geodesic on M (with a fixed hyperbolic structure), and let W be a (cyclically reduced) word in a fixed set
of generators of which represents . In this paper, we give an algorithm to count the number of self-intersections of in terms of W, generalizing a result of Birman and Series, where an algorithm was given to decide if was simple. Some applications of the algorithm to surfaces with one boundary and the Markoff spectrum are also given. 相似文献
993.
Approximation by translates of refinable functions 总被引:23,自引:0,他引:23
Summary.
The functions
are
refinable if they are
combinations of the rescaled and translated functions
.
This is very common in scientific computing on a regular mesh.
The space of approximating functions with meshwidth
is a
subspace of with meshwidth
.
These refinable spaces have refinable basis functions.
The accuracy of the computations
depends on , the
order of approximation, which is determined by the degree of
polynomials
that lie in .
Most refinable functions (such as scaling functions in the theory
of wavelets) have no simple formulas.
The functions
are known only through the coefficients
in the refinement equation – scalars in the traditional case,
matrices for multiwavelets.
The scalar "sum rules" that determine
are well known.
We find the conditions on the matrices
that
yield approximation of order
from .
These are equivalent to the Strang–Fix conditions on the Fourier
transforms
, but for refinable
functions they can be explicitly verified from
the .
Received
August 31, 1994 / Revised version received May 2, 1995 相似文献
994.
本文以Na、ca、Al、Zn作为主要基体元素,在不同ICP发射光谱仪上考察了20多条分析谱线受到的干扰情况,初步总结了基体干扰效应的一般规律。结果表明,在常用分析条件下,一般金属元素具有与易电离元素类似的基体效应,即在较低观察区域对测定谱线信号产生增感,而在正常观察区域产生抑制;从增感转向抑制的零干扰点主要出现在感应圈上方8~14mm的观察区域,这一结果为实际分析条件的优化提供了有益的依据。 相似文献
995.
Bogumil Zelent Józef Kuśba Ignacy Gryczynski Michael L. Johnson Joseph R. Lakowicz 《Journal of fluorescence》1993,3(3):199-207
We examined the time-dependent intensity decays ofN-acetyl-l-tryptophanamide (NATA) when collisionally quenched by acrylamide in propylene glycol over a range of temperatures. The intensity decays of NATA became increasingly heterogeneous in the presence of acrylamide. The NATA intensity decays were not consistent with the Collins-Kimball radiation boundary condition (RBC) model for quenching. The steady-state Stern-Volmer plots show significant upward curvature, and quenching of NATA by acrylamide was observed even in vitrified propylene glycol, where translational diffusion cannot occur during the lifetime of the excited state. These frequencydomain and steady-state data indicate a through-space quenching interaction between NATA and acrylamide, and the results are consistent with a rate constant for quenching that depends exponentially on the fluorophore-quencher separation distance. The exponential distance-dependent rate of quenching also explains the upward curvature of the Stern-Volmer plot, and the steady-state data aid in determining the interaction distance between NATA and acrylamide. These results suggest that the distance-dependent quenching rates need to be considered in the interpretation of acrylamide quenching of proteins. 相似文献
996.
董槐林 《厦门大学学报(自然科学版)》1993,32(4):419-423
探讨智能型决策支持系统(IDSS)的实现技术,以DSS模型语言IFPS/plus为工具建立的“贷款审批决策系统”说明了使用模型语法表达定性数据和符号推理的方法,这种方法把专家系统(ES)的功能直接嵌入DSS,对许多IDSS的构建是有效的。 相似文献
997.
师顺凡 《河北理工学院学报》1993,(1)
采用“减小刀具刚度”的方法进行切削,从而改善了机械加工精度。对系统进行动态分析,建立二个自由度模型。在切削加工期间,将切削过程的等效刚度模拟为弹簧,在模拟系统中,附加了阻尼元件,而且还串联上刀具,恰当地选择元件的刚度,这样,即使减小了刀具的实际刚度,也会增加系统的稳定性,如果选择适宜的阻尼材料,装置设计合理.那么,就会在动态特性和机械加工精度(圆柱度)这两个方面获得好的效果。 相似文献
998.
A note on smoothed estimating functions 总被引:1,自引:0,他引:1
A. Thavaneswaran Jagbir Singh 《Annals of the Institute of Statistical Mathematics》1993,45(4):721-729
The kernel estimate of regression function in likelihood based models has been studied in Staniswalis (1989,J. Amer. Statist. Assoc.,84, 276–283). The notion of optimal estimation for the nonparametric kernel estimation of semimartingale intensity (t) is proposed. The goal is to arrive at a nonparametric estimate
of 0=(t
0) for a fixed pointt
0 [0, 1]. We consider the estimator that is a solution of the smoothed optimal estimating equation
is the optimal estimating function as in Thavaneswaran and Thompson (1986,J. Appl. Probab.,23, 409–417). 相似文献
999.
A. B. Levy 《Set-Valued Analysis》1993,1(4):379-392
Epi-derivatives have many applications in optimization as approached through nonsmooth analysis. In particular, second-order epi-derivatives can be used to obtain optimality conditions and carry out sensitivity analysis. Therefore the existence of second-order epi-derivatives for various classes of functions is a topic of considerable interest. A broad class of composite functions on
n
called fully amenable functions (which include general penalty functions composed withC
2 mappings, possibly under a constraint qualification) are now known to be twice epi-differentiable. Integral functionals appear widely in problems in infinite-dimensional optimization, yet to date, only integral functionals defined by convex integrands have been shown to be twice epi-differentiable, provided that the integrands are twice epi-differentiable. Here it is shown that integral functionals are twice epi-differentiable even without convexity, provided only that their defining integrands are twice epi-differentiable and satisfy a uniform lower boundedness condition. In particular, integral functionals defined by fully amenable integrands are twice epi-differentiable under mild conditions on the behavior of the integrands.This work was supported in part by the National Science Foundation under grant DMS-9200303. 相似文献
1000.
The stability and convergence of the solutions of perturbed and regularized variational inequality to the solutions of the primary (unstable a priori) variational inequality with proper monotone operator are investigated. All the objects of inequality: the operatorA, the right-hand partf and the set of constrains are to be perturbed. At the same time no assumptions of boundedness and smoothness of the operatorA are used. The connection between the parameters of perturbations, which guarantees strong convergence of approximate solutions, is established. It is proved that the existence of the solution to the unperturbed variational inequality is necessary and sufficient condition for convergence of the regularized perturbed inequality solutions.This research was supported in part by the Ministry of Science Grant 3481-1-91 and by the Ministry of Absorption Center for Absorption in Science. 相似文献