机助数据采集与通用平差系统

PC-1500袖珍计算机是理想的野外数据采集工具,IBM系列微机又是比较普及的内业处理机,PC-1500与IBM又可以联机通讯.从而可达到从野外数据采集到内业数据处理的自动化.本文就控制测量的野外数据采集与内业数据处理作了一系列理论研究与实用试验,编制出一整套实用软件.可用于生产实际中.     

BP网络及其应用

基函数选取和系数求解是函数逼近中的两个关键问题,目前广泛应用的回归分析或其它映射方法均有局限性。采用人工神经网络中的BP网较好地解决了这两个问题,对理论和实际的数据进行了比较与验证,结果表明.BP网络有助于提高数据处理的可靠性与预测的精度.     

提高石油化工企业原料利用率的技术研究

坚持眼睛向内,挖潜增效,这是当前原油变重、供应量不足,生产资料涨价的客观形势下走出困境、提高企业效益的主要途径之一,本文从拓宽催化回炼油的利用途径,催化和加氢裂化互换循环油加工,优化重油原料的安排,提高轻油头的化肥效益,挤出烷基化原料,开发异丁烷的化工用途及油化结合等方面,分析通过厂际装置间的原料互供、生产优化来挖掘企业内涵,提高经济效益.     

置换环上的稳定矩阵

本文证明了置换环上的正则稳定矩阵是幂等矩阵和可逆矩阵的积,进一步证明了置换环上的正则稳定矩阵可以对角化。     

Investigation of sulfonated poly(ether ether ketone sulfone)/heteropolyacid composite membranes for high temperature fuel cell applications

The sulfonated poly(ether ether ketone sulfone) (SPEEKS)/heteropolyacid (HPA) composite membranes with different HPA content in SPEEKS copolymers matrix with different degree of sulfonation (DS) were investigated for high temperature proton exchange membrane fuel cells. Composite membranes were characterized by Fourier transfer infrared spectroscopy (FTIR) and scanning electron microscopy (SEM). FTIR band shifts suggested that the sulfonic acid groups on the copolymer backbone strongly interact with HPA particles. SEM pictures showed that the HPA particles were uniformly distributed throughout the SPEEKS membranes matrix and particle sizes decreased with the increment of copolymers' DS. The holes were not found in SPEEKS‐4/HPA30 (consisting of 70% SPEEKS copolymers with DS = 0.8 and 30% HPA) composite membrane after composite membranes were treated with boiling water for 24 h. Thermal stabilities of the composite membranes were better than those of pure sulfonated copolymers membranes. Although the composite membranes possessed lower water uptake, it exhibited higher proton conductivity for SPEEKS‐4/HPA30 especially at high temperature (above 100 °C). Its proton conductivity linearly increased from 0.068 S/cm at 25 °C to 0.095 S/cm at 120 °C, which was higher than 0.06 S/cm of Nafion 117. In contrast, proton conductivity of pure SPEEKS‐4 membrane only increased from 0.062 S/cm at 25 °C to 0.078 S/cm at 80 °C. At 120 °C, proton conductivity decreased to poor 0.073 S/cm. The result indicated that composite membranes exhibited high proton conductivity at high temperature. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 1967–1978, 2006     

Sulfonated poly(aryl ether ether ketone ketone)s containing fluorinated moieties as proton exchange membrane materials

A series of sulfonated poly(aryl ether ether ketone ketone)s statistical copolymers with high molecular weights were synthesized via an aromatic nucleophilic substitution polymerization. The sulfonation content (SC), defined as the number of sulfonic acid groups contained in an average repeat unit, could be controlled by the feed ratios of monomers. Flexible and strong membranes in sodium sulfonate form could be prepared by the solution casting method, and readily transformed to their proton forms by treating them in 2 N sulfuric acid. The polymers showed high T_gs, which increased with an increase in SC. Membranes prepared from the present sulfonated poly(ether ether ketone ketone) copolymers containing the hexafluoroisopropylidene moiety (SPEEKK‐6F) and copolymers containing the pendant 3,5‐ditrifluoromethylphenyl moiety (SPEEKK‐6FP) had lower water uptakes and lower swelling ratios in comparison with previously prepared copolymers containing 6F units. All of the polymers possessed proton conductivities higher than 1 × 10^?2 S/cm at room temperature, and proton conductivity values of several polymers were comparable to that of Nafion at high relative humidity. Their thermal stability, oxidative stability, and mechanical properties were also evaluated. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 2299–2310, 2006     

Monitoring managerial efficiency in the performing arts: A regional theatres network perspective

Managerial efficiency within the performing arts programming can be understood as the technical efficiency of transforming the resources cultural managers have available into a determined cultural output. Through this explanation different conceptions on the finished performance product it leads us to select two different output variables (number of performances, and number of attendances). In this way, three different models are considered regarding those conceptual points of view. Data on the Circuït Teatral Valencià, a Spanish regional theatres network, is used to develop empirically the concept of Managerial Efficiency and set up a framework to allow us to monitor it.     

侧析我国的学术环境——对诺贝尔奖困惑的反思

诺贝尔自然科学奖是比较公正的,但政治对科学发展的影响又是现实的。我国之所以未曾问津诺贝尔自然科学奖,在很大程度上是由于政治环境影响了基础研究的学术自由和学术交流。     

数据库管理系统自定义函数过程编写探索

当今信息化社会,人们利用计算机来处理大量的数据信息,数据库技术显得尤为重要。本文针对近年来数据库管理系统FoxBASE和Visual FoxPro程序设计课程教学中函数过程的编写提出一些经验和应用技巧,旨在启发广大数据库管理系统爱好者的编程思路。     

A new quantum statistical evaluation method for time correlation functions

Considering a system ofN identical interacting particles, which obey Fermi-Dirac or Bose-Einstein statistics, we derive new formulas for correlation functions of the type (whereB _j is diagonal in the free-particle states) in the thermodynamic limit. Thereby we apply and extend a superoperator formalism, recently developed for the derivation of long-time tails in semiclassical systems. As an illustrative application, the Boltzmann equation value of the time-integrated correlation functionC(t) is derived in a straightforward manner. Due to exchange effects, the obtained t-matrix and the resulting scattering cross section, which occurs in the Boltzmann collision operator, are now functionals of the Fermi-Dirac or Bose-Einstein distribution.