全文获取类型
收费全文 | 9595篇 |
免费 | 688篇 |
国内免费 | 359篇 |
专业分类
化学 | 475篇 |
晶体学 | 3篇 |
力学 | 48篇 |
综合类 | 61篇 |
数学 | 931篇 |
物理学 | 2295篇 |
综合类 | 6829篇 |
出版年
2024年 | 31篇 |
2023年 | 80篇 |
2022年 | 144篇 |
2021年 | 121篇 |
2020年 | 107篇 |
2019年 | 110篇 |
2018年 | 137篇 |
2017年 | 205篇 |
2016年 | 231篇 |
2015年 | 268篇 |
2014年 | 530篇 |
2013年 | 496篇 |
2012年 | 512篇 |
2011年 | 585篇 |
2010年 | 548篇 |
2009年 | 586篇 |
2008年 | 601篇 |
2007年 | 733篇 |
2006年 | 648篇 |
2005年 | 589篇 |
2004年 | 560篇 |
2003年 | 514篇 |
2002年 | 378篇 |
2001年 | 302篇 |
2000年 | 239篇 |
1999年 | 188篇 |
1998年 | 201篇 |
1997年 | 188篇 |
1996年 | 143篇 |
1995年 | 106篇 |
1994年 | 85篇 |
1993年 | 72篇 |
1992年 | 86篇 |
1991年 | 68篇 |
1990年 | 47篇 |
1989年 | 49篇 |
1988年 | 44篇 |
1987年 | 24篇 |
1986年 | 28篇 |
1985年 | 13篇 |
1984年 | 4篇 |
1983年 | 5篇 |
1982年 | 9篇 |
1980年 | 5篇 |
1979年 | 3篇 |
1978年 | 2篇 |
1977年 | 4篇 |
1974年 | 2篇 |
1973年 | 6篇 |
1969年 | 2篇 |
排序方式: 共有10000条查询结果,搜索用时 8 毫秒
91.
《Electroanalysis》2003,15(13):1109-1114
The electrochemical characterization of a hydrogen peroxide sensor based on a ferrocene‐containing polymer electrochemically deposited onto a platinum electrode is described. The redox polymer consists of a siloxane‐based homopolymer, with pendant electronically communicated ferrocenyl moieties. The electrodes were used as the transducer for glucose and lactate‐sensing enzyme sensors. Amperometric biosensors were prepared by immobilization of glucose oxidase (Gox) or lactate oxidase (Lox) onto these modified electrodes. The steady‐state amperometric response of the sensors is investigated as a function of the applied potential and substrate concentration. Interferences, sensitivity and stability of the sensors were also studied. 相似文献
92.
H. Kienitz 《Angewandte Chemie (International ed. in English)》1969,8(10):733-750
The important advances being made in modern analytical methods are indicative of the fundamental changes that are occuring in the theory and practice of “analytical chemistry”. “Information optimization” demands a new approach in teaching and research, and calls for the intergration of chemistry with other scientific and technical disciplines. 相似文献
93.
Pierre Parisot 《商业与工业应用随机模型》1985,1(1):35-54
We studied a population of paraplegic patients in order to give prominence to a possible relationship between the topography of their spinal lesion and the occurrence of special articular diseases (P.O.A.). According to the motor and sensory state of their spinal cord, we first tried to obtain a classification of these lesions (the usual one schematically separates ‘flaccid’ and ‘rigid’ paraplegics). We mainly put the emphasis on this clustering step of the study:
- 相似文献
94.
95.
介绍了锗在光纤通信中的作用,分析了世界光纤市场的变化及其对锗的市场结构的影响,预测近期国内锗的市场结构不会有大的变化。 相似文献
96.
Salah Hassoon 《Analytica chimica acta》2004,512(1):125-132
Ultrasound-based water treatment is often applied for degradation of stable organic pollutants, such as polycyclic aromatic hydrocarbons and halogenated compounds. Monitoring the degradation process, during the application of ultrasound radiation, is of considerable economical interest. In this work, the possibility of performing on-line spectral analysis during sonication was examined and it was found that direct absorption or fluorescence readings are misleading. Optical monitoring is strongly affected by the absorption and scattering of light by cavitation micro-bubbles and ultrasound induced particulates. A model was developed to account for these effects and to allow for on-line fluorescence analysis. The model takes into account the absorption and scattering coefficients of the micro-bubbles and particulates, as well as their time dependent concentration. The model parameters are found from independent measurements where the pollutants are added to already sonicated pure water. Then, the model is tested for predicting the actual fluorescence behavior during the sonication process. It has been shown that the model allows for recovery of the true degradation data, as obtained by off-line HPLC measurements. 相似文献
97.
Dimethyl 1′,1′-ureylenedi(1-ferrocenecarboxylate) (1) formed during the synthesis of 1-amino, 1′-ferrocenecarboxylic acid shows virtual molecular centrosymmetry. Electronic coupling between the two Fc groups through the ureylene bridge results in both Fc groups being individually oxidizable (ΔE1/2?0.14 V). The possible existence of intermolecular electronic communication has discussed. The oxidation was followed by spectroelectrochemistry. The separation between the two halfwave potentials ΔE1/2=137±5 mV and the comproportionation constant Kc=207. 相似文献
98.
The new 10 μg l−1 arsenic standard in drinking water has been a spur to the search for reliable routine analytical methods with a limit of detection at the μg l−1 level. These methods also need to be easy to handle due to the routine analyses that are required in drinking water monitoring. Graphite furnace atomic absorption spectrometry (GFAAS) meets these requirements, but the limit of detection is generally too high except for methods using a pre-concentration or separation step. The use of a high-intensity boosted discharge hollow-cathode lamp decreases the baseline noise level and therefore allows a lower limit of detection. The temperature program, chemical matrix modifier and thermal stabilizer additives were optimized for total inorganic arsenic determination with GFAAS, without preliminary treatment. The optimal furnace program was validated with a proprietary software. The limit of detection was 0.26 μg As l−1 for a sample volume of 16 μl corresponding to 4.2 pg As. This attractive technique is rapid as 20 samples can be analysed per hour. This method was validated with arsenic reference solutions. Its applicability was verified with artificial and natural groundwaters. Recoveries from 91 to 105% with relative standard deviation <5% can be easily achieved. The effect of interfering anions and cations commonly found in groundwater was studied. Only phosphates and silicates (respectively at 4 and 20 mg l−1) lead to significant interferences in the determination of total inorganic arsenic at 4 μg l−1. 相似文献
99.
100.
With the accelerated accumulation of genomic sequence data, there is a pressing need to develop computational methods and advanced bioinformatics infrastructure for reliable and large-scale protein annotation and biological knowledge discovery. The Protein Information Resource (PIR) provides an integrated public resource of protein informatics to support genomic and proteomic research. PIR produces the Protein Sequence Database of functionally annotated protein sequences. The annotation problems are addressed by a classification-driven and rule-based method with evidence attribution, coupled with an integrated knowledge base system being developed. The approach allows sensitive identification, consistent and rich annotation, and systematic detection of annotation errors, as well as distinction of experimentally verified and computationally predicted features. The knowledge base consists of two new databases, sequence analysis tools, and graphical interfaces. PIR-NREF, a non-redundant reference database, provides a timely and comprehensive collection of all protein sequences, totaling more than 1,000,000 entries. iProClass, an integrated database of protein family, function, and structure information, provides extensive value-added features for about 830,000 proteins with rich links to over 50 molecular databases. This paper describes our approach to protein functional annotation with case studies and examines common identification errors. It also illustrates that data integration in PIR supports exploration of protein relationships and may reveal protein functional associations beyond sequence homology. 相似文献