全文获取类型
收费全文 | 6458篇 |
免费 | 421篇 |
国内免费 | 451篇 |
专业分类
化学 | 1760篇 |
晶体学 | 59篇 |
力学 | 532篇 |
综合类 | 25篇 |
数学 | 1151篇 |
物理学 | 1538篇 |
综合类 | 2265篇 |
出版年
2024年 | 10篇 |
2023年 | 65篇 |
2022年 | 132篇 |
2021年 | 131篇 |
2020年 | 135篇 |
2019年 | 157篇 |
2018年 | 147篇 |
2017年 | 159篇 |
2016年 | 169篇 |
2015年 | 199篇 |
2014年 | 297篇 |
2013年 | 440篇 |
2012年 | 350篇 |
2011年 | 397篇 |
2010年 | 344篇 |
2009年 | 406篇 |
2008年 | 405篇 |
2007年 | 380篇 |
2006年 | 347篇 |
2005年 | 317篇 |
2004年 | 277篇 |
2003年 | 241篇 |
2002年 | 186篇 |
2001年 | 166篇 |
2000年 | 161篇 |
1999年 | 160篇 |
1998年 | 138篇 |
1997年 | 128篇 |
1996年 | 117篇 |
1995年 | 120篇 |
1994年 | 104篇 |
1993年 | 90篇 |
1992年 | 79篇 |
1991年 | 64篇 |
1990年 | 61篇 |
1989年 | 46篇 |
1988年 | 52篇 |
1987年 | 33篇 |
1986年 | 23篇 |
1985年 | 18篇 |
1984年 | 16篇 |
1983年 | 7篇 |
1982年 | 7篇 |
1981年 | 11篇 |
1980年 | 5篇 |
1979年 | 7篇 |
1978年 | 7篇 |
1977年 | 3篇 |
1976年 | 3篇 |
1973年 | 5篇 |
排序方式: 共有7330条查询结果,搜索用时 15 毫秒
91.
Chatterjee J 《Advances in colloid and interface science》2002,99(2):163-179
Removal of oil drops from solid surfaces immersed in an aqueous medium is of interest in many applications. It has been shown that drop shape analysis can be used to predict conditions at which the stability limit of a lighter than water oil drop on a solid surface immersed in an aqueous bath is reached (Adv. Colloid Interface Sci. 98 (2002) 265). However the above analysis is restricted to cases where the contact angle made by the drop is below 90degrees and when the surface conditions result in a 'pinned' contact line. In this paper, it is shown that drop shape analysis can be used to predict the critical conditions at which drop stability limit is reached for drop contact angles of 90degrees and above, which is encountered with 'hydrophilic' surfaces. This critical condition can predict the occurrence of partial oil drop detachment, before complete removal due to 'roll-up', which occurs when the hydrophilic surface is adequately smooth which prevents 'pinning' of the contact line. The critical conditions at which partial drop detachment occurs can also be approximately predicted from simple force balances. It has been shown (Adv. Colloid Interface Sci. 98 (2002) 265) that for contact angles less than 90degrees, the critical limit based on shape analysis appears to resolve the differences that arise due to alternate expressions for capillary retention force. This paper shows that even for contact angles above 90degrees, the critical conditions predicted from the shape analysis resolves the differences in the predictions from the alternate force balances. Drop shape analysis used in this paper is based on the 'Arc-length' form of Young-Laplace or 'drop shape' equation, which is different from the 'Y vs X' form of the above equation that is used in Adv. Colloid Interface Sci. 98 (2002) 265. The above drop shape equation is solved by a fourth order Runge-Kutta technique and it is shown that for angles less than 90degrees, the two forms of the drop shape equation, predict almost identical values of the critical Eotvos number. This paper highlights the competing effects of interfacial tension lowering induced drop instability and 'roll-up', a term that is used to describe the retraction of the contact line of an oil drop on a surface, in being the primary c ause for drop detachment. 相似文献
92.
This paper deals with the asymptotic behavior of solutions to a class of non-autonomous Lamé systems modeling the physical phenomenon of isotropic elasticity. The main feature of this model is that the nonlinearity can be decomposed into a subcritical part and a critical one. We first show that the system generates a non-autonomous dynamical system, and then prove that the system has a minimal universe pullback attractor. The upper-semicontinuity of these pullback attractors is also established as the perturbation parameter of the external force tends to zero. The quasi-stability ideas developed by Chueshov and Lasiecka (2010, 2008, 2015) are used to prove the pullback asymptotic compactness of the solutions in order to overcome the difficulty caused by the critical growthness of the nonlinearity. 相似文献
93.
94.
从能斯特方程出发,考虑到国产CNa电极的离散性,给出实用的数学模型,并用MCS-51单片机构成高性能价格比的微量钠离子检测仪。 相似文献
95.
研究钢筋混凝土薄钢板剪力墙在侧向力作用下的弹性掘曲临界载荷计算问题,提出了相应的计算模型,导出了计算公式,并与相应实验结果比较,符合良好。 相似文献
96.
胰腺腺泡细胞胞浆游离钙浓度的测定及药物作用的研究 总被引:3,自引:1,他引:2
本文建立了用荧光指示利Fura-2测定胰腺腺泡细胞胞浆游离Ca2+浓度([Ca2+]i)的实验技术,包括:胰腺腺泡的分离制备;Fura—2/AM的负载;腺泡悬液的荧光光谱测量等.测定了胰腺腺泡细胞[Ca2+]i。的静息值和卡巴可促腺泡细胞[Ca2+]i升高的剂量—效应关系及动力学过程,并研究了柴胡总皂甙对胰腺腺泡细胞[Ca2+i]的影响.发现0.01mg/ml浓度的柴胡总皂甙使胰腺腺泡细胞[Ca2+]。明显升高,0.1mg/ml浓度时可使[Ca2+]。升高到静息值的3倍,提示柴胡总皂甙的促酶分泌作用是通过胞内[Ca2+]i升高介导的. 相似文献
97.
2,6—二硝基甲苯对鲤鱼的毒性 总被引:10,自引:2,他引:8
研究测定了2,6-二硝基甲苯(2,6-DNT)对鲤鱼的急性和亚致死毒性.亚致死试验经180mg/L、360mg/L、540mg/L、720mg/L、990mg/L2,6-DNT暴露21d.在15℃~19℃下,24h、48h、72h、96h的半致死浓度值分别为2548mg/L、2296mg/L、2012mg/L、1900mg/L.亚致死试验中,根据2,6-DNT对鲤鱼生长和肝、肾、鳃ATPase活力的影响,求得2,6-DNT的最大允许毒物浓度为180~360mg/L. 相似文献
98.
超滤法浓缩提取萝卜POD过程中的数量关系探讨 总被引:4,自引:3,他引:1
对超滤法浓缩提取萝卜POD(peroxidase)过程中酶活、比活力、蛋白质浓度及浓缩液体积等的动态变化的初步研究表明:(1)时间与浓缩液的蛋白质浓度、酶活、酶损失率间,浓缩液体积与蛋白质浓度、酶活、比活力及酶活的增加倍数间,以及体积浓缩倍数与酶和蛋白质的得率间的关系,均可用方程y=aebx来表示;(2)时间与透过液的蛋白质浓度及酶活间的关系可用方程y=a+b1x+b2x2+b3x3+bx44来表示;(3)浓缩液蛋白质浓度与酶活及酶的浓缩倍数间,时间与浓缩液体积及透过液的比活力间的关系,均可用方程y=a+bx来表示. 相似文献
99.
The thermoreversible gelation of semi-diluted atactic polyacrylnitrile (PAN)/dimethylformamide (DMF)-solutions has been studied. The structural features of PAN/DMF-gels, formed by supercooling have been investigated by DSC-, x-ray- and swelling measurements. A new structural model has been introduced to describe the morphology of the junction zones of PAN/DMF-gels and to also explain the gelation behavior of PAN/DMF-solutions as the structural features of PAN/DMF-gels. The junction zones of a PAN/DMF-gel have been defined as ordered junction zones.A gelation enthalpy of about H=–6 kJ/mol supports the idea that an ordered junction zone is formed by intermolecularly neighboring stereoregular parts of atactic PAN chains due to a nucleation process in the solution. It can be defined as a strongly distributed fringed micelle. 相似文献
100.
As the application of a dielectric theory proposed previously (J Membrane Sci 64:153–161 (1991)), theoretical formulation and the practical procedure of dielectric analysis are developed to calculate the structural parameters such as the conductivity gradient and the thickness of the concentration polarization layer, the capacitances and the conductances of the two adjoining aqueous phases from the observed dielectric parameters. The procedure of calculation consequent upon the theoretical formulation was applied to double relaxation data observed for cation-exchange membrane systems under application of d.c. bias voltage. As a consequence, the structural parameters of concentration polarization were readily obtained with accuracy. 相似文献