Structural chemistry of bimetallic hydride complexes of titanium and aluminium: I. Crystal and molecular structure of [(η5-C5H5)2,Ti(μ-H)2AlH2]2(CH3)2NCH2CH2N(CH3)2C6H6

The structure of a titanium aluminium hydride complex of composition [(C₅H₅)₂TiAlH₄]₂(CH₃)₂NC₂H₄N(CH₃)₂C₆H₆ has been determined by X-ray diffraction. The complex forms triclinic crystals with unit cell dimensions a = 8.406(2), b = 10.117(2), c = 11.269(3) Å; α = 112.01(2)°, β = 109.25(2)°, γ = 87.04(2)°, space group P$\text{1}$, Z = 2 and density d = 1.21 g/cm³. The structure was refined to give a discrepancy index R = 0.056. The crystals are composed of centrosymmetric molecules of (Cp₂TiAlH₄)₂TMEDA (Cp = η⁵-cyclopentadienyl) and molecules of crystal benzene. Two moieties of Cp₂TiH₂AlH₂ are linked by a tetramethylethylenediamine molecule (r_AlN 2.11 Å). The aluminium atom is bonded to a titanium atom by a double hydride bridge (r_AlH b = 1.8, 1.6 Å, r_TiH b = 1.6 Å), and has trigonal bipyramidal stereochemistry, [H₄N] (r_AlH t = 1.6 Å).     

Ditertiary phosphine complexes of (ν-allyl)dicarbonylmolybdenum(II) and -tungsten(II)

Compounds of the type [XM(CO)₂(ν-allyl)L₂] (where X = Cl and Br; M = Mo and W; L₂ = Ph₂PCH₂PPh₂ and Ph₂ PCH₂CH₂PPh₂) have been prepard from the corersponding MeCN complexes. The spectral properties of these compounds and the effects of chelate rign size on ³¹P coordination shifts and J(¹⁸³W—³¹P) have been investigated.     

“双一流”背景下高等农业院校有机化学基础课程教学新模式的构建及实践

The crop science of Sichuan Agricultural University is an authorized first-class discipline. As the strategic supporting department for innovative talent cultivation in agriculture and forestry major, we are facing a long-term challenge in reforming the teaching mode for basic course-organic chemistry and cultivating talented students with solid basic knowledge and strong sense of innovation. Herein a thorough survey was performing to establish the executable teaching programs for this course during the "Double-First Class Universities Plan" period. A multidimensional teaching resource library for organic chemistry course was also constructed. The new classroom teaching mode "Interest cultivation-Creative thought development-Autonomous and Cooperative learning", along with a stepwise practice teaching mode "Foundation skills-Integrated application-Innovative trial" was proposed and practiced among thirty-five majors including agriculture, forestry and veterinary, to improve the quality for innovative talent cultivation and support our first-class discipline construction. This research could probably serve as a reference for congeneric agricultural university.     

农民外出务工对义务教育的影响

农民工收入的增加及观念的转变有利于义务教育的完全普及,同时,农民外出务工又带来了留守生和流动子女的教育问题;要解决农民外出务工对义务教育的负面影响,国家、政府及学校都要采取补救措施。     

高速公路线形设计的质量量化评价模型

针对道路安全审计中如何量化评价线形的设计质量这一重大技术问题,在分析国内外相关研究及实际调查研究的基础上,构造了高速公路线形设计质量量化评价模型,找出了模型量化评价值与亿车公里事故率之间的内在联系,充分验证了评价模型的适应性和有效性,最后给出了高速公路线形设计质量评价标准.     

计算机网络技术在图书馆采访工作中的应用

计算机网络技术的应用，产生了新的采购方式：电子商务和不完全电子商务。同时这些技术的应用使采访者与外界的信息交流变得便捷；采访数据可由采访人员输入或从网络引入并且可在图书馆多种工作环节中重复使用；采访查重、订购、统计可利用机读数据和网络设备轻松准确完成。     

采油中的润湿热、粘附功和吸附焓变

为了深入了解润湿热、粘附功和吸附焓变在；果油中的地位、应用和相互关系，从概念、相互关系和测量方法等方面探讨了3个量的意义，分析了它们在采油中的作用和应用。分析表明，粘附与润湿均与吸附有关，二者关系密切，在采油中起着举足轻重的作用。油在岩石表面的粘附功、润湿热越大，越不容易被驱走；驱油剂在岩石表面的润湿热越大，越有利于自发渗吸，提高洗油效率；驱油剂在岩石表面的吸附焓变越大，吸附能力越强，越有利于改变岩石表面的性质。     

一稿多投的复杂成因与杜绝对策

一稿多投的屡禁不止，有来自各方面的复杂的成因，要杜绝此现象，须着重处理好两层关系：在改善编辑工作的同时提高作服务工作的质量；在做好防范工作的同时加强对一稿多投的惩治力度。     

给水管网故障时阀门关闭的计算机调度

针对城市给水管网发生事故时,在事故点位置已经确定的情况下,根据管网的拓扑关系,通过BFS算法实现了对阀门的优化调度,并用Visual Basic语言编制了抢修时阀门优化调度实用程序.通过实例用计算机进行了验证,在各种情况下,均获得了满意的结果,关闭阀门形成的集合为最优.     

DEP260变电站事故预警系统的研制

各类变电站在运行过程，必须建立一个安全的运行环境，对变电站各种设备的运行状态及影响变电站安全运行的因素实现在线监测。介绍了变电站事故预警系统的原理，并给出了为满足各种用户要求的系统结构。