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11.
Hu Yang Weisi Yin Xuxin Kong Min Xu Yefeng Yao Qun Chen Rongshi Cheng 《Colloid and polymer science》2006,284(8):935-940
The compact single-chain (SC) particulates of Poly(N-isopropylacrylamide) (PNIPAM), which have been formed above its lower critical solution temperature in an aqueous solution containing the surfactant of sodium n-dodecyl sulfate (SDS), were recovered from the solution by freeze-drying. Under scanning electron microscopy, the compact particulate appears as a spherical or elliptical particulate individually dispersed in SDS, which acts as a solid solvent to prevent agglomeration. The conformation of the compact SC particulates of PNIPAM dispersed in SDS had been studied by the solid-state high-resolution 13C NMR spectroscopy. The 13C spin-lattice relaxation time T
1 of the SC sample was determined in comparison with that of the original one. It was found that the T
1 of the methyl carbon in the isopropyl group of the SC sample was about 45% higher than that in the original multichain sample, which revealed the differences in the motion of the methyl group in the different condensed states and illuminated the characteristic conformation of the compact SC globular particulates of PNIPAM. 相似文献
12.
On the applicability of the HSAB principle through the use of improved computational schemes for chemical hardness evaluation 总被引:1,自引:0,他引:1
Finite difference schemes, named Compact Finite Difference Schemes with Spectral-like Resolution, have been used for a less crude approximation of the analytical hardness definition as the second-order derivative of the energy with respect to the electron number. The improved computational schemes, at different levels of theory, have been used to calculate global hardness values of some probe bases, traditionally classified as hard and soft on the basis of their chemical behavior, and to investigate the quantitative applicability of the HSAB principle. Exchange acid-base reactions have been used to test the HSAB principle assuming the reaction energies as a measure of the stabilization of product adducts. 相似文献
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从紧算子的谱理论出发,给出了超双曲型方程(△x-△y)u+λu=f(x,y),x=(x1,x2,…,xm),y=(y1,y2,…,ym)的Dirichlet问题解的存在性和唯一性定理. 相似文献
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The Kakutani–Bebutov Theorem (1968) states that any compact metric real flow whose fixed point set is homeomorphic to a subset of embeds into the Bebutov flow, the -shift on . An interesting fact is that this universal space is a function space. However, it is not compact, nor locally compact. We construct an explicit countable product of compact subspaces of the Bebutov flow which is a universal space for all compact metric real flows, with no restriction; namely, into which any compact metric real flow embeds. The result is compared to previously known universal spaces. 相似文献
17.
《复变函数与椭圆型方程》2012,57(15):1163-1164
Let X be a smooth and connected Riemann surface of genus g 0 and f: X P1, h: X P1 non-constant meromorphic functions on X. Fix an integer n 4 and assume the existence of n distinct points a1, , an P1 such that [image omitted] (set-theoretically) for every i. Here we prove that either f = h or [image omitted]. 相似文献
18.
本文研究一类二维非线性的广义sine-Gordon(简称SG)方程的有限差分格式.首先构造三层时间的紧致交替方向隐式差分格式,并用能量分析法证明格式具有二阶时间精度和四阶空间精度.然后应用改进的Richardson外推算法将时间精度提高到四阶.最后,数值算例证实改进后的算法在空间和时间上均达到四阶精度. 相似文献
19.
In this note we consider the Schrödinger equation on compact manifolds equipped with possibly degenerate metrics. We prove Strichartz estimates with a loss of derivatives. The rate of loss of derivatives depends on the degeneracy of metrics. For the non-degenerate case we obtain, as an application of the main result, the same Strichartz estimates as that in the elliptic case. This extends Strichartz estimates for Riemannian metrics proved by Burq-Gérard-Tzvetkov to the non-elliptic case and improves the result by Salort for the degenerate case. We also investigate the optimality of the result for the case on 𝕊3 × 𝕊3. 相似文献
20.
周艳红 《贵州大学学报(自然科学版)》2007,24(1):22-24
首先给出了可数meso紧空间的一个等价刻画,然后主要证明了以下结论:(Ⅰ)分别准完备映射保持,逆保持可数meso紧性;(Ⅱ)可数meso紧空间在闭的紧覆盖映射下的象是可数meso紧空间;(Ⅲ)meso紧映射的逆保持可数meso紧性。 相似文献