并行工程计划问题的模糊网络分析方法

基于网络流模型,本文提出了确定模糊网络关键路线的参数线性规划方法,并给出了反映决策者偏好信息的模糊网络关键路线和工程模糊完工期的隶属函数形式,从而得到了模糊网络关键路线性质的更全面结果。最后,针对模糊环境下的并行工程计划问题,给出了模糊网络的分析方法。     

基于Access公路工程机械数据库开发

介绍了Ｗｉｎｄｏｗｓ９５／ＮＴ下的数据库管理与开发平台Ａｃｃｅｓｓ的特点,论述了如何利用ＯＬＥ等手段来提高工程数据库的开发效率与质量,并结合公路工程机械数据库的开发实例,完成了各类别公路机械数据库建立、事务关系处理、实时检测数据分析处理、网络管理等工作．     

大型河工模型智能化采集与控制系统

介绍了大型河工物理模型智能化采集与控制系统的开发要点,包括系统的功能、硬件设计、系统的采集与控制、软件设计以及开发工具等。运行情况证明,该系统在大型河工物理模型中应用具有可靠、高效、操作方便等特点。     

荷载效应组合系数的统计方法

根据实测数据,以多车道公路桥梁车辆荷载效应组合为背景,基于ＩＳＯ２３９４提出的原则,探讨了荷载效应组合系数的统计方法,以合理确定参与组合的各种荷载的设计值．     

新工科视阈下石油化工类高校应用化学专业课程体系重构

Taking a typical local and industry-orientated applied chemistry major as an example with focusing on the major changes in the form and content of the petrochemical industry, the way to reform the core curriculum system and teaching contents is presented. Based on the changing tendency of refinement of the petrochemical industry, a complete curriculum system with distinctive industry characteristics is set up according to the principles of the emerging engineering education (3E) with several reasonable suggestions. A new model for the construction of a 3E major in chemistry-related majors is suggested. It is a good reference for the construction of curriculum systems for other local and industry-orientated colleges who want to make 3E reform.     

Thermoanalytical study of nucleating effects in polypropylene composites

Nucleating and transcrystallization behaviour of additives in engineering PP composites and the effect of modified interfacial structure is the subject of this series of papers. The first part concentrates on polypropylene/liquid crystalline polyester blends. Increased crystallisation temperature and degree of crystallinity of polypropylene is characteristic to the blends containing different amount of LCP additive. Transcrystallization process governs the formation of crystalline structure in these systems in course of isothermal crystallisation at 132C. The nucleating effect of LCP gives rise to more uniform crystalline structure in the polypropylene phase.The financial support of the OTKA 014194 is acknowledged with gratitude.     

Oxythallation of norbornene derivatives with thallium(III) acetate in methanol

Treatment of norbornene, norbornadiene, benzonorbornadiene, and chloro- and methoxy-benzonorbornadiene with thallium(III) acetate in methanol affords only the corresponding cis-exo-acetoxythallation adducts in a sharp contrast to oxymercuration of such strained olefins where methoxymercuration prevails. In the cases of substituted benzonorbornadienes the products are obtained as the regioisomeric mixtures, the isomer ratio being determined by ¹³C NMR. In the cases of 5-norbornene-2,3-dicarboxylic anhydride, 5-norbornene-2-methyl-2,3-dicarboxylic anhydride, and 5-norbornen-2-endo-carboxylic acid, lactonization occurs to give a trans-oxythallation adduct having a lactone ring, no introduction of either methoxy or acetoxy groups being observed. ¹H and/or ¹³C NMR data for several new oxythallation adducts are provided. The alkaline sodium borohydride reduction of adducts in methanol affords mainly the parent olefin together with 10–16% yields of the corresponding exo-alcohol.     

Selective formation of AAB- and ABC-type heterotrimeric alpha-helical coiled coils

The alpha-helical coiled coils have a representative amino acid sequence of (abcdefg)(n) heptad repeats. We previously reported that two peptides named IZ-2A and IZ-2W formed an (IZ-2A)(2)/IZ-2W heterotrimer with an Ala-Ala-Trp interaction in the hydrophobic core. In this paper, we describe the selective formation of AAB- and ABC-type heterotrimers. To increase the selectivity of the AAB-type heterotrimeric formation, Lys residues at the f position were mutated to either an Ala or a Gln residue to form IZ-2A(fA) or IZ-2W(fQ). Separately, both IZ-2A(fA) and IZ-2W(fQ) have a random structure at pH 7 and 20 degrees C. However, together IZ-2A(fA) and IZ-2W(fQ) form a 2:1 complex with a thermal transition midpoint (Tm) of 48 degrees C. This procedure was applied to prepare the ABC-type heterotrimer, in which two sets of Ala-Ala-Trp interactions were designed in the hydrophobic core. Interhelical interaction between the e and g positions and the alpha-helical propensity of the amino acid at the f position were also considered in the design. The resultant three peptides selectively formed the ABC-type heterotrimer with a Tm of 51 degrees C. Other peptide combinations had random coil properties.     

Anion control of isomerism, crystal packing and binding properties in a mononuclear zinc complex

The coordination chemistry of the tetradentate pyridyl N-donor ligand cis-3,5-bis-[2-pyridinyleneamin]-trans-hydroxycyclohexane (DDOP) has been investigated with zinc(II) nitrate and triflate. The resulting complexes, [Zn(DDOP)(H₂O)(NO₃)](NO₃) (1), and [Zn(DDOP)(H₂O)(OTf)](OTf) (2) differ not only in their counterions, but also the arrangement of the axial ligands and their solid state hydrogen bonded networks. Isothermal titration calorimetry was used to assess the difference in binding properties exhibited by the two zinc complexes at physiological pH in an aqueous environment. A series of coordinating amino acids were found to preferentially bind to the mononuclear zinc triflate (1) complex over the corresponding nitrate (2) assembly, with histidine exhibiting a two centre binding mode.     

Steric control over hydrogen bonding in crystalline organic solids: a structural study of N,N'-dialkylthioureas

Hydrogen bonding in crystalline N,N'-dialkylthioureas was examined with the help of single-crystal X-ray diffraction, DFT calculations, and Cambridge Structural Database (CSD) analysis. A CSD survey indicated that unlike the related urea derivatives, which persistently self-assemble into one-dimensional hydrogen-bonded chains, the analogous thioureas can form two different hydrogen-bonding motifs in the solid state: chains, structurally similar with those found in ureas, and dimers, that further associate into hydrogen-bonded layers. The formation of one motif or another can be manipulated by the bulkiness of the organic substituents on the thiourea group, which provides a clear example of steric control over the hydrogen bonding arrangement in crystalline organic solids.