Intermixing during epitaxial growth and Mössbauer spectroscopy with probe layers

Mössbauer spectroscopy with ⁵⁷Fe (¹¹⁹Sn) probe layers is a useful method to study the local magnetic structures at buried interfaces. However interface alloying, which always exists in the real samples, have to be taken into account for accurate interpretation of experimental data. We developed an algorithm, which describes the interface intermixing in the multilayers. Substituting deposited atoms by atoms of substrate and floating of deposited atoms in the upper layers during epitaxial growth leads to the formation of asymmetric chemical and magnetic interfaces. This asymmetry in the M₁/M₂ superlattices can explain the difference between magnetic responses from M₁ on M₂ and M₂ on M₁ interfaces which were observed in experiments. Applying this intermixing model to the systems with probe layers located at different distances from the interfaces gives the natural explanation of hyperfine fields distributions on probe atoms and helps us clarify some discrepancies reported in the literature.     

Spherical dye-doped silica particles

Organic dyes such as water soluble porphyrins were incorporated into monodispersed SiO₂ particles using the sol-gel technique (the Stober synthesis) and their monomeric and dimeric properties were investigated by aiming at the microcavity effect. Doping efficiencies of dyes into SiO₂ particles depended on dye's hydrophilic properties. The doping efficiency of a porphyrin, TTMAPP, decreased with increasing the nominal content in the starting solution and the doping content showed the maximum value of 1.6×10^–5 mol/g SiO₂. With increasing the TTMAPP content, spectra of doped particles were changed from dimeric to monomeric nature; the absorption peak due to dimers disappeared and halfwidth of absorption at Soret band decreased. This unusual change was caused by the decrease of particle sizes by dye doping. The TTMAPP-doped sample having monomeric spectrum showed the fluorescence life time of 8.5 nsec and photochemical hole burning at about 5 K.     

Synthesis and crystal structure of 1,3,5-tris [4-(phenylethynyl)phenyl]benzene

The crystal structure of 1,3,5-tris[4-(phenylethynyl)phenyl]benzene (1) has been investigated. Compound1 represents a model of the repeating unit of the most typical polyphenylene, which contains 1,3,5-trisubstituted benzene rings (chain centers) and acetylenic groups (complex-forming and cross-linking centers) in the main chain. The acetylene groups of neighboring molecules have a tendency to close mutual arrangement, which is favorable for their topochemical interaction. However, the relative conformational rigidity of molecules1 restricts not only the possibility of the optimal adjustment of the reactive sites of neighboring molecules to one another, but also hampers the close packing of molecules in the crystal, which contains channels filled by the solvent molecules (chloroform).Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 1986–1992, November, 1994.The work was carried out with the financial support of the International Science Foundation and the American Crystallographic Association.     

Anharmonic effects in large-amplitude vibrations of metal clusters

Two types of extreme collective motion, large-amplitude many-phonon vibration of the ionic core and rotation of the cluster with high angular momenta, are considered. The interplay between vibration and collective motion towards fission is discussed. A new mechanism of formation and rupture of the neck is proposed which is based on the Franck-Condon principle, and accounts for the interplay between vibration and fission. Under rotation, the change of the shape of the cluster and a phase transition from axially symmetric to triaxial ellipsoid are predicted. For studying the effects, vibrational motion can be induced by laser radiation. Rotational motion may arise in collisions of clusters. Received 26 April 2001 and Received in final form 15 October 2001     

中国数学史断代研究的一项新成果：—《明清数学史论文集》简介

本文简介梅荣照主编的《明清数学史论文集》一书，对中国数学史开展断代专题研究，是我国数学史界继承并发展李俨、钱宝琮、严郭杰先生研究成果的宏大计划，持续近三十年，历来为国际科学史界所重视，文集收入论文15篇、附录2篇，其中严敦杰先生遗作7篇，本文对15篇论文逐一作了简介。     

整体优化 提高高校学报质量

本文从学报形成的全过程入手,分析了影响学报质量的诸因素,提出了人与科学技术相结合;编者与作者相结合;编者与读者需要相结合;办刊与高校教育相结合来提高学报质量的观点,使学报在信息传播的全过程中实现整体优化。     

高等学校实验室及实验教学改革模式探讨

本文分析了目前高校实验室建设中存在的主要问题,对高校实验教学和实验室管理模式的改革方式进行了探讨.     

三峡工程水电站压力管道和蜗壳技术结构型式的选择及论证

The developing process of simulation technology is discussed in view of its development, maturation and further development.The applications of simulation technology in the fields of national economy are introduced. Finally, the level and status quo of simulation technology home and overseas are analyzed, and its future trend in the new century is presented.     

利用MAX813L防止应用程序出现死循环故障

介绍了利用CPU监控芯片MAX813L防止应用程序出现死循环的方法，使用表明该方法是可行的。     

浅谈适龄母猪的饲养管理

针对适龄母猪在妊娠期、分娩期、哺乳期等3个不同的生理阶段的特点。介绍了适龄母猪的饲养管理技术，并对母猪不同症状提出了相应的解决措施。