Cork-based activated carbons as supported adsorbent materials for trace level analysis of ibuprofen and clofibric acid in environmental and biological matrices

In this contribution, powdered activated carbons (ACs) from cork waste were supported for bar adsorptive micro-extraction (BAμE), as novel adsorbent phases for the analysis of polar compounds. By combining this approach with liquid desorption followed by high performance liquid chromatography with diode array detection (BAμE(AC)-LD/HPLC-DAD), good analytical performance was achieved using clofibric acid (CLOF) and ibuprofen (IBU) model compounds in environmental and biological matrices. Assays performed on 30 mL water samples spiked at the 25.0 μg L(-1) level yielded recoveries around 80% for CLOF and 95% for IBU, under optimized experimental conditions. The ACs textural and surface chemistry properties were correlated with the results obtained. The analytical performance showed good precision (<15%), suitable detection limits (0.24 and 0.78 μg L(-1) for CLOF and IBU, respectively) and good linear dynamic ranges (r(2)>0.9922) from 1.0 to 600.0 μg L(-1). By using the standard addition methodology, the application of the present approach to environmental water and urine matrices allowed remarkable performance at the trace level. The proposed methodology proved to be a viable alternative for acidic pharmaceuticals analysis, showing to be easy to implement, reliable, sensitive and requiring low sample volume to monitor these priority compounds in environmental and biological matrices.     

基于二项分布随机增长的无标度网络

提出—个具有随机增长的无标度网络模型．该模型的演化规则仍然是BA模型的增长和择优连接,但是每一时间间隔添加到网络中的边数是—个具有二项分布的随机变量．通过率方程方法,本文证明了该网络的度分布具有幂律尾部,该模型生成了—个无标度网络．     

Novel monofunctional and bifunctional boronic acid‐functionalized squarylium dyes as precolumn and on‐column labels for protein analysis by capillary electrophoresis with laser‐induced fluorescence

This article presents a continuous capillary electrophoresis with laser‐induced fluorescence (CE‐LIF) following spectral studies of the noncovalent interactions between novel Squarylium Boronic Acid 4 (SQ‐BA4) & Squarylium Diboronic Acid 2 (SQ‐DBA2) squarylium dyes and human serum albumin (HSA). Two protocols were used wherein the on‐column‐labeling protocol was found to be more sensitive than the precolumn one by showing a better enhancement in the peak area of the HSA–dye complex besides lower limits of detection (LODs) for HSA. Also, stability studies were conducted with or without HSA using precolumn‐labeling mode over one week exhibiting the superiority of SQ‐BA4 to SQ‐DBA2. Then, a mixture containing three model proteins, HSA, β‐lactoglobulin B, and transferrin, was labeled on‐column with both dyes and completely resolved by CE‐LIF after optimization of several parameters. Both dyes provided lower LODs for HSA than those of β‐lactoglobulin B and transferrin with higher sensitivities. In addition, the SQ‐BA4 dye showed again greater sensitivities with all the three proteins than SQ‐DBA2.     

BA对大豆子叶培养物器官分化的影响及其与子叶离体时苗龄的关系

苗龄显著影响大豆子叶培养物器官分化的能力,其中3d苗龄子叶的器官分化率最高.BA促进不定芽和抑制不定根形成的作用没有改变苗龄对子叶器官发生的影响趋势.BA对器官发生的影响幅度随苗龄而异,表明不同苗龄子叶对BA的反应不同.子叶器官发生的适宜苗龄和BA生理影响幅度最大的苗龄是有区别的.     

复杂网络模型的分析

从平均路径长度、聚集系数、度分布的角度对复杂网络中的三种网络模型,即随机网络模型、小世界网络模型和无标度网络模型进行了分析,并对复杂网络模型的研究意义进行了说明.随着对复杂系统研究的深入,复杂网络在现实中的应用范围日益广泛,提供了一种新的方法去研究世界,同时也给带来新的机遇和挑战.     

基于构式语法理论的对外汉语“把”字句偏误分析

构式语法理论认为语言中的基本句子就是一种构式,即形式——意义的匹配体,其本身具有意义,且独立于具体的动词而存在的.“把”字句也是一个构式,运用构式语法理论划分“把”字句构式义项,并进行义素分析,得出其语义配置,并在此基础上对学习者中介语语料库进行偏误分析,从语言认知的角度做出解释,希冀能为对外汉语“把”字句教学提供有益的思路.     

一类点边同时变化的无标度复杂网络模型研究

在BA模型的基础上,提出了一个能较好描述现实复杂网络特征的无标度网络模型.该模型的节点和连边能同时发生变化,即新节点的加入和旧节点的删除,旧节点的再生连接和删除.运用连续介质理论和平均场理论建立起与之对应的演化方程,并计算出了它的严格解,导出了该模型的度分布和幂律指数的表达式.研究分析表明:该模型能自组织演化成无标度网络,其幂律指数在1~3范围内,这与现实中的许多复杂网络相吻合,因此,该模型更具有一般性.     

静电纺丝制备Eu(BA)3phen/PANI/PVP光电双功能复合纳米纤维及其性能

采用静电纺丝技术将聚苯胺(PANI)和稀土配合物Eu(BA)3phen掺杂到高分子材料聚乙烯吡咯烷酮(PVP)中, 制备出新型的具有光电双功能的Eu(BA)3phen/PANI/PVP复合纳米纤维. 采用扫描电子显微镜、 X射线能量色散谱仪、 荧光光谱仪及宽频介电松弛谱仪对样品进行了表征. 实验结果表明, 复合纳米纤维直径为(270±31) nm. 在275 nm紫外光激发下, Eu(BA)3phen/PANI/PVP复合纳米纤维发射出主峰位于580, 594和617 nm的红光, 对应于Eu3+的 5D0→7F0, 5D0→7F1和5D0→7F2跃迁. 当m[Eu(BA)3phen]:m(PANI):m(PVP)=15:10:100 时, 复合纳米纤维的荧光发射最强. 复合纤维的电导率随PANI含量的增大而升高. 在m(PANI):m(PVP)=50:100时, 其电导率在高频(106 Hz)下达到1.5×10-6 S/cm.     

鲜食葡萄品种无核化处理的研究

用GA,BA处理新疆地区主载的几种大粒鲜食葡萄品种,结果表明：GA能促进葡萄无籽果粒的形成,混用BA可使处理效果稳定,同时对果实品质及成熟期也有一定的影响。     

EA/BA/AN/VAC四元共聚物接枝改性天然橡胶的研究

研究了 EA/ BA/ AN/ VAC四元共聚物接枝改性天然橡胶的制备过程中 ,反应温度、引发剂用量、反应时间及单体浓度对接枝聚合反应的影响。结果表明 :采用乳液聚合方法 ,以 KPS/ SHS氧化 -还原体系为引发剂 ,反应温度 6 0～ 70℃ ,引发剂用量1 .3% ,反应时间 2 .5 h为适宜的合成条件。红外光谱证实了接枝共聚物的生成