Time Evolution of Vibration-Induced Excited State Decay

A simple model consisting of two electronic levels and one vibrational mode (phonon) was theoretically studied. The electronic-vibrational interaction was linear in the vibrational displacement. The vibrational mode was taken in the harmonic approximation and was attached to the thermal bath formed by the ambient environment. The kinetic constants of the vibrational dissipation were of the second order in the vibrational-bath coupling and were taken in the Markovian limit. Although, depending on the parameters of the model, different curves of the non-radiative vibration-induced excited state decay were obtained, in general, three time intervals, corresponding to different physical behaviour, were found. In the short-time interval, small oscillations superimposed on the excited state decay were observed. They were determined by the vibrational frequency and influenced by electronic-vibrational coupling. In the middle-time interval, almost quasi-exponential decay was detected; its rate constant increased with stronger electronic-vibrational interaction and speed of vibrational relaxation. In the long-time interval, the decay was very slow and, under special conditions, even an asymptotic non-zero excited state population was observed. Its value increased with the strength of the off-diagonal electron-vibrational coupling. Links of the parameters of the model with quantum chemical terms were estimated.     

空隙中的生长——庄子与芒德勃罗的互读

庄子认为“无”是“道”之本源,“虚”是“道”之禀性,“无”与“虚”蕴藏着勃勃生机。芒德勃罗发现了空集的价值,揭示了自然界虚实相间的生长状态。庄子和芒德勃罗都“以无观有”,认为“无”是“有”潜藏的存在,“无”和“空”是生成万物的根源,在“空隙中生长”是宇宙的常态。芒德勃罗的空集是一种形而下的研究,其指向是现实存在物的实体和空隙合一,是对象性的整体观。庄子之“无”所看重的是人内心世界的空灵,是主客心物合一的非对象性的整体现。     

Generalized Complex Spectral Decomposition for a Quantum Decay Process

By extending the notion of mixed states to functionals acting on the space of observables with diagonal singularity we obtain a well-defined complex spectral decomposition of the time evolution for a quantum decaying system. In this formalism, generalized Gamow states are obtained with well-defined physical properties.     

Positions of convex bodies associated to extremal problems and isotropic measures

We show that there are close relations between extremal problems in dual Brunn-Minkowski theory and isotropic-type properties for some Borel measures on the sphere. The methods we use allow us to obtain similar results in the context of Firey-Brunn-Minkowski theory. We also study reverse inequalities for dual mixed volumes which are related with classical positions, such as ?-position or isotropic position.     

On modular inequalities in variable L p spaces

We show that the Hardy-Littlewood maximal operator and a class of Calderón-Zygmund singular integrals satisfy the strong type modular inequality in variable L^p spaces if and only if the variable exponent p(x) ∼ const. Received: 15 September 2004     

Nonlocal vertex algebras generated by formal vertex operators

This is the first paper in a series to study vertex algebra-like objects arising from infinite-dimensional quantum groups (quantum affine algebras and Yangians). In this paper we lay the foundations for this study. For any vector space W, we study what we call quasi compatible subsets of Hom (W,W((x))) and we prove that any maximal quasi compatible subspace has a natural nonlocal (namely noncommutative) vertex algebra structure with W as a natural faithful quasi module in a certain sense, and that any quasi compatible subset generates a nonlocal vertex algebra with W as a quasi module. In particular, taking W to be a highest weight module for a quantum affine algebra we obtain a nonlocal vertex algebra with W as a quasi module. We also formulate and study a notion of quantum vertex algebra and we give general constructions of nonlocal vertex algebras, quantum vertex algebras and their modules.     

Upper bounds on correlation decay for one-dimensional long-range spin-glass models

Some recent results on one-dimensional spin-glass models with polynomially decreasing interactions are described.     

Heteroclinic orbits between rotating waves of semilinear parabolic equations on the circle

We investigate heteroclinic orbits between equilibria and rotating waves for scalar semilinear parabolic reaction-advection-diffusion equations with periodic boundary conditions. Using zero number properties of the solutions and the phase shift equivariance of the equation, we establish a necessary and sufficient condition for the existence of a heteroclinic connection between any pair of hyperbolic equilibria or rotating waves.