岩石复电阻率测量技术及标定方法研究

研究储层岩石的复电阻率特性,首先必须排除岩石物理测量系统极化效应的影响。基于不同金属电极材料测量装置和硫酸铜面团装置,完成清水条件下的复电阻率实验,并应用纯电阻和RC并联电路对测量仪器和测量装置系统进行标定,证实硫酸铜面团测量装置的性能最稳定,确保了实验结果的准确性和可靠性。在此基础上,建立了一套完整的岩石复电阻率测量技术和标定方法,优选出性能最稳定的测量装置系统,排除非岩石极化效应的影响,为常规与非常规油气储层岩石物理分析和评价提供技术保障。     

强干扰区可控源音频大地电磁勘探处理研究

强干扰区进行地球物理探测,尤其是电磁法勘探时,难以获得可靠的、高质量的原始数据;为取得良好的勘探效果,预处理的重要性更加凸显。通过对原始数据的呈现、分析,提出数据预处理的两套方案,并从理论和实际上证实了方案的可行性。最终结合勘探实例,对比两套数据预处理方案,优选全区视电阻率的方法对原始数据进行预处理,并对其预处理数据反演成图,取得了良好的应用效果。     

Generation and characterization of air micro-bubbles in highly hydrophobic capillaries

The generation of air microbubbles in microfluidic systems or in capillaries could be of great interest for transportation (single cell analysis, organite transportation) or for liquid compartmentation. The physicochemical characterization of air bubbles and a better understanding of the process leading to bubble generation during electrophoresis is also interesting in a theoretical point of view. In this work, the generation of microbubbles on hydrophobic Glaco™ coated capillaries has been studied in water-based electrolyte. Air bubbles were generated at the detection window and the required experimental parameters for microbubbles generation have been identified. Generated bubbles migrated against the electroosmotic flow, as would do strongly negatively charged solutes, under constant electric field. They have been characterized in terms of dimensions, electrophoretic mobility, and apparent charge.     

Electrical transport in liquid Sn1-xPbx metallic alloys: a self-consistent approach

The calculations of electrical resistivity of Sn–Pb liquid metallic alloys/solutions are investigated by self-consistent approach. We employ modified empty-core pseudopotential to represent electron–ion interaction, while partial structure factors are calculated using Aschroft–Langreth scheme with hard sphere reference system. The potential parameters for elemental metals were optimised to structural data in our previous paper. Computed results for resistivity as a function of temperature and concentration are discussed with other such results. Overall good agreement confirms the applicability of the present model potential for computing the electrical properties, including thermal conductivity and thermoelectric power for liquid metallic alloys.     

Micellar Exchange Kinetics of Quaternary Ammonium Type Gemini Surfactants Monitored by Nuclear Magnetic Resonance

The dynamic NMR (DNMR) method was used to detect kinetic parameters of the molecular exchange process between monomers in bulk solution and those in the micelle for Gemini surfactants, 12-s-12 and 14-s-14(s=2, 3 and 4).The escape rate constant, k^-, was derived based on the simplified equations of DNMR theory, and the apparent activation energy of escape, E_a^-, was obtained based on the Arrhenius equation through temperature variation experiments.Results show that the orders of magnitude of k^- for 14-s-14 and 12-s-12 are respectively 10 and 10³ s^-1, E_a^- of 14-s-14 and 12-s-12 are respectively 54.04-73.64 and 33.42-47.09 kJ/mol.Furthermore, increases and E_a^- decreases with the spacer length growing.In combination with the micro-polarity measurements, it was revealed that molecules of 14-s-14 and 12-s-12 have to experience conformation changes when escaping from the micelles.The two-step molecular exchange mechanism for Gemini surfactants was therefore supported.     

Cu/Ni多层膜的电阻与位错

采用电桥及X射线衍射线形分析法研究磁控溅射Cu／Ni多层膜（CLI及Ni单层厚度均为5nm）的室温电阻率及平均位错密度随对层（bilayer）层数的变化规律．结果表明,随层数增加,电阻率及平均位错密度减少;多层膜电阻率大于单层膜电阻率;单层膜电阻率大于同质块状体的电阻率．并对其微观机制进行分析．     

模拟覆岩破坏稳恒电场特征的相似材料配比研究

通过大量的相似材料配比试验研究证明,在材料中加入一定浓度适量的Ｎａｃｌ溶液是实现覆岩破坏稳恒电场特征相似材料模拟的最佳方法。试验得出了相似材料电阻率与Ｎａｃｌ溶液浓度的关系。按照这一关系配制的相似材料模型的试验结果准确地反映了覆岩破坏稳恒电场的变化特征。     

Cd1−xZnxTe: Growth and characterization of crystals for X-ray and gamma-ray detectors

The choice a suitable crystal growth method and a reasonable x value is of profound importance in the preparation of high quality Cd_1−xZn_xTe crystals for x-ray and gamma-ray detectors. The present paper reviews the evolution and development of Cd_1−xZn_xTe crystal growth for x-ray and gamma-ray detectors. At the same time, emphasis is put upon finding the relationship between the x value and the quality of the Cd_1−xZn_xTe. Three sets of Cd_1−xZn_xTe ingots with different x values, specifically 0.10, 0.15, and 0.20 were grown by the vertical Bridgman method (VBM) and characterized. Their x specification was then correlated with their dislocation densities, Te precipitates, inclusions, IR transmission, resistivities, and impurity concentrations, respectively. It was found that VBM Cd_0.85Zn_0.15Te as grown in this paper possessed the best choice of qualities with respect to defects and impurities.     

基于连通导电理论和HB方程的骨架导电纯岩石电阻率模型

针对现有导电模型很难描述骨架含导电矿物黄铁矿的岩石导电规律的难题,利用骨架完全由导电颗粒组成的人造岩样以及骨架部分由导电颗粒组成的天然和人造岩样的岩电实验数据,研究水电阻率和导电颗粒体积分数变化对岩石导电规律的影响,得出骨架导电纯岩石的地层因素与孔隙度及电阻增大系数与含水饱和度在双对数坐标上为非线性关系,随水电导率减小或导电颗粒体积分数增大,地层因素和电阻增大系数值降低。根据骨架导电纯岩石的组成,结合连通导电理论特点,将骨架导电纯岩石分为不导电骨架相、导电骨架相和自由流体相。基于连通导电方程只能描述单一导电相的两相混合介质导电规律而HB方程能描述两相均导电的混合介质导电规律的特点,基于连通导电理和HB方程建立骨架导电纯岩石电阻率模型。结果表明,骨架导电纯岩石电阻率模型预测的地层因素与孔隙度以及电阻增大系数与含水饱和度的理论关系与实验规律相符且模型满足物理约束,该模型能够描述骨架完全和部分由导电矿物组成的纯岩石的导电规律,可用于定量评价骨架导电低阻油层的饱和度。