Microstructure and properties of in-situ synthesized Cu-1 wt%TiC alloy followed by ECAP and post-annealing

A dispersion-strengthened copper alloy with 1 wt% TiC for commercial electrical-contact wires was prepared by in-situ reaction casting, grain-ultrafining by equal-channel angular pressing (ECAP) and subsequent annealing with aim to obtain excellent comprehensive performance. The results showed that fine TiC particles were in-situ synthesized in the as-cast Cu matrix and aggregated in clusters, and thus mechanical properties of the as-cast alloy deemed insufficient. Continued ECAP at 473 K significantly refined the grains of the as-cast alloy and improved the distribution of TiC particles. Due to multiple strengthening mechanisms, the ECAP-processed alloys maintained good conductivity with obviously enhanced tensile strength and hardness values. After post-ECAP annealing, the elongation and conductivity of the fine-grained copper alloy increased with the adequate tensile strength. The novel combined process endows the alloy appropriate performance to serve current high-frequency electrification railway systems.     

Catalytic and kinetic spectrophotometric method for determination of vanadium(V) by 2,3,4-trihydroxyacetophenonephenylhydrazone

A new catalytic and kinetic spectrophotometric method for the determination of vanadium(V) was studied using 2,3,4-trihydroxyacetophenonephenylhydrazone (THAPPH) as an analytical reagent. The present method was developed on the catalytic effect of vanadium on oxidation of THAPPH by hydrogen peroxide in hydrochloric acid–potassium chloride buffer (pH = 2.8) at the 20th minute. The metal ion has formed 1:2 (M:L) complex with THAPPH. Beer’s law was obeyed in the range 20–120 ng/mL of V(V) at λ_max 390 nm. The sensitivity of the method was calculated in terms of molar absorptivity (1.999 × 10⁵ L mol⁻¹cm⁻¹) and Sandell’s sensitivity (0.000254 μg cm⁻²), shows that this method is more sensitive. The standard deviation (0.0022), relative standard deviation (0.56%), confidence limit (±0.0015) and standard error (0.0007) revealed that the developed method has more precision and accuracy. The stability constant was calculated with the help of Asmu’s (9.411 × 10⁻¹¹) and Edmond’s & Birnbaum’s (9.504 × 10⁻¹¹) methods at room temperature. The interfering effect of various cations and anions was also studied. The present method was successfully applied for the determination of vanadium(V) in environmental and alloy samples. The method’s validity was checked by comparing the results obtained with atomic-absorption spectrophotometry and also by evaluation of results using F-test.     

Cooling crystallization of aluminum sulfate in pure water modulated by sodium dodecylbenzenesulfonate

This study investigated the cooling crystallization of aluminum sulfate to explore the basic data for the recovery of aluminum resources from coal spoil. Cooling crystallization process of aluminum sulfate with sodium dodecylbenzenesulfonate (SDBS) was investigated experimentally. The effects of operating conditions, namely rotate speed and cooling rate on the crystal size (Median diameter, D_0.5) were studied. Based on single factor experimental results, the response surface method (RSM) with a Box–Behnken design (BBD) was used to determine the key operating conditions, from which a predictive equation was established to quantitatively describe the relationships of D_0.5 and there relative parameters. The optimum operating conditions for cooling crystallization of aluminum sulfate were as follows: rotate speed of 200–300 rpm, cooling rate of 4–5 °C /min and n (SDBS)/n (Al₂(SO₄)₃) of around 5E‐4. Molecular dynamics (MD) results reveal that SDBS decreases the diffusion coefficient (D) of Al³⁺ molecules, which inhibits nucleation and promotes crystal growth.     

油气雾化技术在钛合金加工中应用研究

为了提高金刚石刀具切削钛合金零件的表面加工质量,减轻金刚石刀具的磨损,提出一种以二氧化碳、水及植物油雾化后的雾状混合物作为冷却介质的加工技术.冷却介质经研制的油气雾化装置喷淋到切削区,达到冷却、润滑及保护金刚石刀具的目的.对比实验表明,利用油气雾化技术,二氧化碳气体能够更充分地接触加工表面,使工件加工表面中微量铁原子直...     

玻璃与金属封接过程中气孔率和玻璃飞溅

通过测量不同工艺条件下玻璃绝缘子中的气孔率和最大气泡直径,以及观察底盘表面的玻璃飞溅情况,研究了熔封气氛、熔封温度、熔封时间、氧化膜类型和厚度对玻璃绝缘子中气孔率和玻璃飞溅的影响.结果表明,玻璃绝缘子中气孔率与可伐合金底盘表面的飞溅程度有一定的关系.可伐合金表面Fe3O4氧化物与玻璃中SiO2发生化学反应是玻璃绝缘子中气泡的一个重要来源,也是引起玻璃飞溅的因素.熔封气氛和氧化膜厚度对气孔率和玻璃飞溅影响最大.推荐的工艺条件是在可伐合金表面生成厚度约1μm的FeO氧化膜,然后与玻坯在950～980℃工厂条件的气氛中熔封30～40 min.     

Influence of B,Al and Nb addition on the glass forming ability and stability of mechanically alloyed Zr-Ni amorphous alloys

We investigated the influence of minor additions of B,Al and Nb that have representative atomic sizes on the glass forming ability (GFA) and stability of Zr-Ni amorphous alloys during mechanical alloying. The results show that the minor addition of B,Al or Nb does not shorten the initial time of the full amorphization reaction or improve the glass forming ability of the Zr-Ni alloys at a low rotation speed. However,B addition can effectively improve the mechanical stability of the amorphous phase against me...     

电感耦合等离子发射光谱法测定铅黄铜中常微量元素

研究了用电感耦合等离子发射光谱法(ICP-AES)对铅黄铜合金中多元素分析的基本条件,确定了合适的谱线,采用相邻峰背景扣除法对光谱干扰进行了校正,探讨了酸度对光谱强度的影响,同时测定了各元素的检出限.测定元素的回收率为92%~107%,精密度为0.25%~2.75%.     

热镀5%铝-锌钢板在青岛不同海水区带的腐蚀行为

开展了热镀5%铝-锌钢板在青岛不同海水区带的实海腐蚀测试,并利用电化学测试、失重腐蚀测试和扫描电镜首次研究了镀层的海水腐蚀行为.结果表明,由于腐蚀电流密度小,腐蚀产物具有保护性,镀层在全浸区表现出较好的耐蚀性能;镀层在潮差区出现不同程度的生物污损,而比较充分的充气条件又促进了镀层的氧化,其腐蚀速度比全浸区明显降低;镀层在飞溅区未出现生物污损,耐蚀性能最好,可能与良好的充气条件和腐蚀产物层的阻挡作用有关.镀层在飞溅区和潮差区的耐蚀性比全浸区分别提高197%和183%;但在全浸区和潮差区,镀层有局部腐蚀倾向.     

宏观孔对泡沫工业纯铝阻尼行为的影响

文章运用多功能内耗仪研究了宏观孔对空气加压渗流法制备的泡沫工业纯铝阻尼行为的影响。在室温低频率条件下测量了泡沫工业纯铝的内耗,实验结果表明泡沫工业纯铝的阻尼能力比致密工业纯铝的阻尼能力提高较大,前者内耗随着测量频率的增加而增加,同时也随应变振幅的增加而增大。运用TEM观察材料的微观结构,发现在晶界附近存在大量的位错亚结构。根据内耗测量和微观观察,讨论了泡沫工业纯铝中可能的阻尼机制,基于多孔弹性材料的平面波方程,理论计算得到了泡沫工业纯铝中内耗的表达式。