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991.
非晶态聚消旋乳酸(PDLLA)对PLLA的结晶行为有较大的影响。本文利用差示扫描量热仪(DSC)和偏光显微镜(POM)对不同分子量PLLA、PDLLA按不同比例制得的共混物结晶进行了系统研究。结果表明随PDLLA含量的增大PLLA冷结晶温度升高,且越接近熔融温度。PDLLA分子量较小时PLLA球晶特征被明显破坏,PDLLA分子量较大时PLLA更易形保持球晶特征且易形成环带球晶形貌,这与结晶速率与非晶组分的扩散速率匹配程度有关。低分子量的PDLLA使PLLA的最大生长速率对应的温度出现在较低温度。 相似文献
992.
The threat and global concern of energy crises have significantly increased over the last two decades. Because solar light and water are abundant on earth, photocatalytic hydrogen evolution through water splitting has been considered as a promising route to produce green energy. Therefore, semiconductor photocatalysts play a key role in transforming sunlight and water to hydrogen energy. To date, various photocatalysts have been studied. Among them, TiO2 has been extensively investigated because of its non-toxicity, high chemical stability, controllable morphology, and high photocatalytic activity. In particular, 1D TiO2 nanofibers (NFs) have attracted increasing attention as effective photocatalysts because of their unique 1D electron transfer pathway, high adsorption capacity, and high photoinduced electron–hole pair transfer capability. However, TiO2 NFs are considered as an inefficient photocatalyst for the hydrogen evolution reaction (HER) because of their disadvantages such as a large band gap (~3.2 eV) and fast recombination of photoinduced electron–hole pairs. Therefore, the development of a high-performance TiO2 NF photocatalyst is required for efficient solar light conversion. In recent years, several strategies have been explored to improve the photocatalytic activity of TiO2 NFs, including coupling with narrow-bandgap semiconductors (such as ZnIn2S4). Recently, microwave (MW)-assisted synthesis has been considered as an important strategy for the preparation of photocatalyst semiconductors because of its low cost, environment-friendliness, simplicity, and high reaction rate. Herein, to overcome the above-mentioned limiting properties of TiO2 NFs, we report a 2D/1D ZnIn2S4/TiO2 S-scheme heterojunction synthesized through a microwave (MW)-assisted process. Herein, the 2D/1D ZnIn2S4/TiO2 S-scheme heterojunction was constructed rapidly by using in situ 2D ZnIn2S4nanosheets decorated on 1D TiO2 NFs. The loading of ZnIn2S4 nanoplates on the TiO2 NFs could be easily controlled by adjusting the molar ratios of ZnIn2S4 precursors to TiO2 NFs. The photocatalytic activity of the as-prepared samples for water splitting under simulated solar light irradiation was assessed. The experimental results showed that the photocatalytic performance of the ZnIn2S4/TiO2 composites was significantly improved, and the obtained ZnIn2S4/TiO2 composites showed increased optical absorption. Under optimal conditions, the highest HER rate of the ZT-0.5 (molar ratio of ZnIn2S4/TiO2= 0.5) sample was 8774 μmol·g-1·h-1, which is considerably higher than those of pure TiO2 NFs (3312 μmol·g-1·h-1) and ZnIn2S4nanoplates (3114 μmol·g-1·h-1) by factors of 2.7 and 2.8, respectively. Based on the experimental data and Mott-Schottky analysis, a possible mechanism for the formation of the S-scheme heterojunction between ZnIn2S4 and TiO2 was proposed to interpret the enhanced HER activity of the ZnIn2S4/TiO2heterojunctionphotocatalysts.
相似文献
993.
Web3D新技术在现代远程教育中的应用 总被引:1,自引:0,他引:1
阐述了当前远程教育的弊端和将Web3D新技术应用于现代教育的优越性,研究了Web3D的具体技术及其在现代远程教育的应用,展望了现代远程教育中应用Web3D技术的美好前景. 相似文献
994.
公路环境仿真系统中三维地面模型简化 总被引:2,自引:1,他引:2
随着“虚拟现实”技术的进一步发展 ,它在公路管理中将会有较好的应用前景。但由于其需要依赖较为复杂的数字地面模型的支持 ,这必将制约其更为广泛的应用 ,基于这一情况 ,对公路环境仿真系统中三维地面模型的 DTMs模型及 TIN模型的简化技术作了一定的讨论 ,并提出了一些具体的、实用的算法。 相似文献
995.
李小松 《科技情报开发与经济》2006,16(15):280-281
介绍了一种简易数控直流电流源的设计。该电流源主要由数字控制部分和恒流源产生电路部分组成。其中单片机为系统的核心控制器,此外还包括键盘输入模块、LCD液晶显示模块以及DA转换模块。在电流源中主通路上,选了两个功率比较大的模拟器件LM338和TIP122,能稳定可靠地输出2A的最大电流。 相似文献
996.
在基于相位分析的三维测量系统中,为了准确地得到物体的高度,相位展开扮演着很重要的角色。传统的相位展开方法常常需要额外的投影图,而傅里叶变换轮廓术只需要采集一幅或两幅变形条纹图就可以实现对物体轮廓的测量,其方法速度快,易于实现。针对傅里叶变换轮廓术方法计算得到的截断相位分布,本文提出了一种利用截断相位与参考平面相位差值2π的整数倍数获得截断相位的正确级次,辅助相位展开的方法。当被测物体较复杂,或者相位截断次数较多时,该方法在已有参考平面相位的基础上虚拟新的相位平面,依次比较截断相位和虚拟相位,进行多次分级相位展开,结合多个展开相位结果,最终得到正确的展开相位。该方法展开速度快,展开错误不会蔓延传递。仿真和实物实验结果证明了该方法的可行性,说明该方法可用于傅里叶变换轮廓术中进行截断相位的快速展开。 相似文献
997.
This paper is concerned with the integration by parts formulae for the pinned or the standard Wiener measures restricted on
a space of paths staying between two curves. The boundary measures, concentrated on the set of paths touching one of the curves
once, are specified. Our approach is based on the polygonal approximations. In particular, to establish the convergence of
boundary terms, a uniform estimate is derived by means of comparison argument for a sequence of random walks conditioned to
stay between two polygons. Applying the Brascamp–Lieb inequality, the stochastic integrals of Wiener type are constructed
relative to the three-dimensional Bessel bridge or the Brownian meander.
Supported in part by the JSPS Grant (B)(1)14340029 相似文献
998.
999.
《科学通报(英文版)》2007,(16)
The photoluminescence quenching behaviors of 5D3-7FJ and 5D4-7FJ (J = 0―6) transitions of Tb3 in YBO3:Tb under 130―290 nm excitation were systematically investigated. The results revealed that the quenching concentrations of both 5D3-7FJ and 5D4-7FJ transitions of Tb3 in YBO3:Tb were mainly de-pendent on excitation wavelength. Particularly,the quenching concentrations of 5D4-7FJ transitions of Tb3 under 130―290 nm excitation were correlated with excitation bands of YBO3:Tb. The quenching concentrations of 5D3-7FJ transitions remained at low concentration (2%) under 186―290 nm excitation and then increased gradually with energy of incoming excitation photon when excited at 130―186 nm. This dependence should be involved in their excitation mechanisms and quenching pathway in particular excitation region. 相似文献
1000.
基于全局单应性变换的虚实注册方法 总被引:1,自引:0,他引:1
提出了一种基于全局单应性变换的三维注册方法,有效地解决了基于标识的三维注册系统中的误差积累问题.设计了一种新的对仿射变换鲁棒的特征点检测方法--边角点法,确保每个特征点位于多条直线的交点上,最大限度消除特征检测结果的随机性及其对特征匹配所造成的负面影响.采用基于全局单应性矩阵的虚实配准方法,利用前一帧所对应的全局单应性矩阵对初始图像作射影变换,并将变换后的图像与当前图像做特征匹配,直接建立当前帧与初始帧之间的单应性关系,从而解决了传统方法所存在的误差积累问题.实验结果表明本算法有效可行. 相似文献