铷原子频标中的微波动功率频移

根据的测量，在铷原子频标中微波功率频移系数总是正的。已有的关于微波功率频移的解释无法解释此现象。本文从微波场引起交流Ｚｅｅｍａｎ效应的观点出发，解释了这一现象。     

Calculation of Elastic Scattering Properties in an Ultra-Cold ^85Rb-^85Rb Vapour

We report the calculation of the same-species elastic scattering properties for the ultracold rubidium-rubidium (^85Rb-^85Rb) system and the results are compared with other theoretical and experimental results in detail. We present an improved potential for triplet ground states of the Rb2 molecule, and calculate the scattering lengths αt and the effective range re using WKB and Numerov methods for two rubidium-85 collisions in the triplet state. Also, we investigate the convergence of these scattering properties, i.e. the dependence on core radius and K^0 parameter using quantum defect theory and the analytic calculations of scattering length obtained by Szmytkowski. In addition, we present evaporative cooling and other results that include phase shift and cross section at zero energy limit.     

离心洗脱法在Rb蛋白与细胞分化关系研究中的应用

离心洗脱技术可分离到ＨＬ６０细胞周期中同步的Ｇ０／Ｇ１期细胞，被视黄酸诱导的Ｇ０／Ｇ１细胞可以进行一个正常的细胞周期，Ｒｂ蛋白磷酸化平随细胞周期而变化，但不能进入第二个细胞周期，细胞开始分化，Ｒｂ蛋白磷化水平的降低，是由于ＲＡ首先诱导细胞分化，使细胞生长停止，分化的细胞失去磷酸化蛋白能力的结果。     

硝酸铷在醇水混合溶剂中的溶解度

本文通过简单精确的分析方法测定了硝酸铷在水、水＋甲醇以及在水＋乙醇中在不同温度下的溶解度。在甲醇和乙醇存在的情况下，硝酸铷在水的溶解度都明显降低。通过四参数方程对试验数据拟和，取得了满意的结果。同时也测定了三元体系在“饱和”和“非饱和”状态下的折光率，并对折光率和醇及盐的浓度进行关联。     

RbBr/CsBr-CH3OH/C2H5OH-H2O三元体系的溶解度

采用自制的相平衡研究装置, 测定了RbBr-CH3OH/C2H5OH-H2O和CsBr-CH3OH/C2H5OH-H2O四个三元体系在25、35、45 ℃三个温度下的平衡溶解度;同时得到了四个三元体系饱和溶液中不同盐浓度下的折光率数据. 实验结果表明,在所有的体系中, 随着甲醇或乙醇质量分数的增加, RbBr和CsBr 在水中的溶解度逐渐降低; 并且折光率也逐渐减小. 用经验关联方程对溶解度进行了拟合, 同时给出了CH3OH 和C2H5OH 分别对RbBr和CsBr的盐析率曲线.     

微波消解-电感耦合等离子体质谱法测定低品位锂云母中的铷和铯

建立了微波消解-电感耦合等离子体质谱法测定低品位锂云母中铷和铯含量的方法。通过试验确定了最佳的样品处理条件,以铑为内标校正基体干扰,确定方法对铷和铯的检出限(3s)分别为0.032,0.018μg·L^-1,标准曲线线性相关系数均大于0.999 7。对实际样品进行11次测定,相对标准偏差(n=11)为2.3%~4.6%;加标回收试验的回收率为96.5%~105%。经国家标准品验证,本方法的测定值与标准值相符。该方法快速准确,能满足低品位锂云母中铷和铯的分析要求。     

双冠醚研究 Ⅷ. 席夫碱型双冠醚苦味酸铷配合物的合成及其晶体结构

本文合成了间亚苯基桥接的席夫碱型双-(苯并15-冠-5)苦味酸铷配合物以及测定了其晶体结构.实验证明该晶体属单斜晶系,P2₁/n空间群,晶胞参数:a=19.3049(49)Å,b=20.4544(39)Å,c=25.4375(75)Å,β=107.925(21)°,V=9556.90ų,F(000)=4175.41(e),Dc=1.455g/cm³.对8172个可观测反射精修所有的结构参数,最后偏离因子R=0.0781.此双冠醚以反-反式构型与Rb⁺离子形成4:2(冠醚单元:阳离子)分子间夹心结构配合物,Rb₁和Rb₂分别与两个双冠醚分子中不同取向的醚环的十个氧原子配位.Rb-O平均键长为2.986和2.998Å,并与席夫碱型双冠醚苦味酸钾配合物进行比较.     

87Rb-Ar光谱灯光谱特性和滤光效果研究

通过超精细光谱测量,研究灯泡和滤光泡均充入氩气情形下,铷光谱灯的光谱特性和同位素滤光效果.研究结果表明,充氩气的铷光谱灯谱线轮廓存在一定程度的变形,为了减轻这种变形,谱灯的工作温度应适当降低.此外,滤光泡气压、长度和工作温度对滤光效果有显著影响.根据研究结果,优化了谱灯和滤光泡的设计参数和工作参数.将优化后的铷光谱灯和滤光泡用于铷原子频标,显著改善了短期频率稳定度.     

Spatiotemporal variations of Zr/Rb ratio in three last interglacial paleosol profiles across the Chinese Loess Plateau and its implications for climatic interpretation

The ratio of Zirconium to Rubidium （Zr/Rb） is suggested to be a better proxy for the East Asian winter monsoon strength than the widely-used grain size distribution. The rationale for the Zr/Rb proxy relies on the following assumptions： （1） Grain size fractionating characteristics during eolian dust transport should be archived in the Zr/Rb ratio records and this assumption is based on the premise that Zr is preferentially enriched in coarser grain size fraction while Rb tend to be enriched in finer grain size fraction; and （2） post-depositional weathering does not change the Zr/Rb ratio due to the immobility of these two elements. To examine these two assumptions, three last interglacial paleosols （S1） from Dingxi, Tianshui and Lantian, along a NW-SE transect across the Chinese Loess Plateau, were geo- chemically investigated. Our results show that the Rb concentration exhibits an increasing trend along the NW-SE transect both in the paleosol （S1） and the measured portions of the loess units （L1 and L2）, being supportive to the assumption that Rb is enriched in the fine particles. But we also found that Rb loss did occur to some extent in the three profiles, contradicting to the presumption of Rb immobility during pedogenic processes. The Zr concentration exhibits an expected decreasing trend in the measured portions of the loess units and an unexpected increasing trend in the paleosol along the NW-SE transect. Moreover, the ratios of Zirconium to Hafnium （Zr/Hf） show different variation patterns between interglacial and glacial, implying that Zr-bearing minerals and their resident grain size fractions are probably not identical during interglacial and glacial. Thus, the assumption that Zr is enriched in coarse grain size fraction can no longer hold. We conclude that the final Zr/Rb value is not only dependent on grain size sorting processes but also on post-depositional alteration and source prove- nance. Under enhanced chemical weathering, especially when chemical index of alterat