用HZSM-5催化剂直接合成对甲乙苯的研究

本文用适当处理的HZSM-5催化剂进行甲苯乙烯烃化直接合成对甲乙苯,该催化剂经 过 200小时的长运转试验表明具有良好反应性能。还探讨了 HZSM-5沸石催化剂的表面酸 性质及微孔有效扩散系数与其择形催化的关系。 1.实验部分 1.1 催化剂制备 由本实验室用氨水合成的 ZSM-5与粘结剂 Al2O3混合成型,经硝酸铵溶液交换,制得 HZSM-5催化剂,再经适当处理制得五种不同性能的 HZSM-5催化 剂。 1.2 烷基化反应 该反应是在常压小型固定床积分反应器中进行,以甲苯转化率CT(mol%)表示催化剂活性;以产物中对甲乙苯与甲乙苯总和之比Sp(%)表示对位选…     

A Multi-component Matrix Loop Algebra and Its Application

A set of multi-component matrix Lie algebra is constructed. It follows that a type of new loop algebra A^- M-1 is presented. An isospectral problem is established. Integrable multi-component hierarchy is obtained by Tu pattern, which possesses tri-Hamiltonian structures. Furthermore, it can be reduced to the well-known AKNS hierarchy and BPT hierarchy. Therefore, the major result of this paper can be regarded as a unified expression integrable model of the AKNS hierarchy and the BPT hierarchy.     

2-碘-N-甲基苯磺酰胺的合成新方法和分子结构

选用新方法合成了2-碘—N-甲基苯磺酰胺，通过^1H NMR,^13C NMR,^13C DEPT NMR(Distortionless Enhancement by Polarization Transfer NMR)和MS确证的其结构。     

Indriect Determination of CTMAB with Sodium Chloride and Ammonium Thiocyanate by Floatation and Separation of Zine

A new method for indirect determination of cetyl-trimethyl ammonium bromide (CTMAB) with NaCl and NH4SCH by floatation and separation of zinc has been studied.The study shows that Zn(Ⅱ） can associate with NH4SCN and CTMAB to form insoluble ternary ion-association complex,and the precipitate can float on the surface of the liquid phase.A good linear relationship is observed between the floatation yield(E%) of Zn(Ⅱ） and the amount of CTMAB.On the ground,CTMAB Can be indirectly determined by determining E% of Zn(Ⅱ）.The results were satisfactory.     

Proton Fraction in Neutron Star Matter and Three-Body Force Effects

The three-body force effects on the equation of state and its iso-spin dependence of asymmetric nuclear matter and on the proton fraction in neutron star matter have been investigated[1] within Brueckner Hartree-Fock (BHF) approach by using a microscopic three-body force. It is shown that, even in the presence of the three-body force, the empirical parabolic law of the energy per nucleon vs. isospin asymmetry β=(N-Z)/A is fulfilled in the whole asymmetry range 0 ≤β ≤1 and also up to high density. The three-body force provides a strong enhancement of symmetry energy at high density in agreement with relativistic approaches. Thecalculated proton fraction in β stable neutron star matter is given in Fig.l, where the thick solid line is the BHF prediction using AV18 TBF, while the dotted one is the BHF result using AVis. The thin solid line is the prediction of the Dirac-Brueckner approach taken from Ref.[2]. The results extracted according to the phenomenological paramete rizations of the symmetry energy suggested in Ref.[3] are also plotted. It is seen from     

邻域并与泛圈图

本文中 ,我们用邻域并对泛圈图进行深入的研究 ,主要取得了“2连通 n( n≥ 3 )阶图 G,满足下列条件之一 ,则 G是泛圈图 : :δ≤ ( n-7) /3 ,N C≥ ( 2 n-3 ) /3 ; :( n-6) /3≤ δ≤ ( n+2 ) /3 ,N C≥ 2 n/3 ; :δ≥ ( n+3 ) /3 ,N C≥ ( 2 n-3 ) /3 .当 3≤ n≤ 14时 ,N C≥ 2 n/3”     

Crystal Structure of Adduct 2-Phenyl-imidazo [ 4,5-f ] 1,10-phenanthroline Methanol

The structure of the title adduct comprises a phenanthroline derivative 2-phenyl-imidazo[4,5-f]1,10-phenanthroline and a methanol.The composition of the crystalline adduct was characterized as C19H12N4.CH3OH.It belongs to orthorhombic system,space group Pna21 with a=1.3693(4)nm,b=2.2988(7)nm,c=0.51338(15)nm,V=1.6160(8)nm^3.Z=4,and final R1=0.0423.wR2=0.1012 .Crystal structure shows that all the 19 carbon atoms and 4 nitrogen atoms are coplanar.The bond length data indicated that a very extensive conjugation system was formed.This conjugation makes the compound being a potentially excellent energy transformer used for luminescent materials.     

浅谈中外高等教育评价的特点和主要差异

1欧洲高等教育评价的特点 从20世纪80年代起,欧洲各国普遍开始重视高等教育的质量问题.在高等教育评价活动的过程中,逐渐形成了著名的三种模式:法国模式、荷兰模式和英国模式,对其它国家产生了很大的影响.这三种模式概括起来有以下特点:     

苯并18-冠-6配合物[K(B18-C-6)]SCN的合成与结构分析

苯并 18 -冠 - 6 (B18- C- 6 )与 K2 [Cd(SCN) 4 ]反应 ,得到了 [K(B18- C- 6 ) ]SCN配合物。通过元素分析、红外光谱、单晶 X射线衍射进行了结构分析。该配合物为单斜晶系 ,空间群 P2 (1) / c,晶体学数据 :a=0 .996 0(3) nm,b=2 .5 0 97(7) nm,c=0 .8374 (2 ) nm,β=10 6 .5 19(5 )°,V=2 .0 0 6 7(10 ) nm3 ,Z=4 ,F(0 0 0 ) =86 4,R1=0 .0 4 2 9,w R2 =0 .0 5 75。结构分析表明 ,该配合物由一个 [K(B18- C- 6 ) ]配阳离子和一个 SCN阴离子组成 ,配合物的两个分子通过 K+ - π相互作用形成一维链状结构