浅谈纳米光电子器件的发展现状

纳米光电子技术是一门新兴的技术，近年来越来越受到世界各国的重视，而随着该技术产生的纳米光电子器件更是成为了人们关汪的焦点。主要介绍了纳米光电子器件的发展现状。     

基于Hamaker假设的黏着接触弹性模型

为研究微纳米系统中的黏着接触问题，基于Hamaker假设和Lennard-Jones势能定律，通过积分方法得到了球体与平面间的黏着力，同时结合经典弹性理论建立了一种新型的球体与平面黏着接触的弹性模型，该模型可以同时得到平面轮廓随间距的变形过程及黏着力和平面变形量随间距的变化规律，当球体半径较大时，所建模型与基于Derjaguin近似的黏着模型给出的结果基本一致，随着球体半径的逐渐减小，两种模型的差异逐渐增大，这是由于Derjaguin近似的误差随球体半径的减小而增大引起的，因此，当球体的半径趋近纳米级时，基于Hamaker假设的黏着接触模型可以给出更加准确的结果。     

Fabrication of Dendrimer－like PAMAM Based on Silica Nanoparticles

A G 4.0 dendrimer-like poly (amido amine) (PAMAM) based on silica nanoparticles was fabricated via a divergent approach.It was built from γ-aminopropyi silica nanoparfides (APSN) core via repetitive addition of acrylate (MA) and hexylenediamine (HDA). FT-IR and EA were used to monitor the progress of dendrimer during each step. The amino group content of the resulting product increased from 0.49 to 3.72 mmol/g after the 4th generation. In addition, the percentage of grafting increased with increasing generation and reached to 65.9% after 4th generation. It was found that the resulting silica nanoparticles could be dispersed in methanol with a mean hydrodynamic particle diameter of 152.7 nm although the silica nanoparticles had agglomerated during the storage period.     

纳米氧化钛-乙二醇溶胶溶液的研究

选用了钛酸丁酯、硬脂酸和乙二醇作为表面活性剂，采用表面化学修饰和表面物理修饰2种方法修饰纳米氧化钛，然后分散在乙二醇溶剂中形成溶胶溶液．并通过红外光谱仪、紫外分光计、原子力显微镜，分析了表面化学修饰后的纳米氧化钛表面化学结构的变化，观测了纳米氧化钛溶胶在乙二醇溶剂中稳定性．试验结果表明表面活性剂与纳米氧化钛的表面的不饱和键之间形成了新的化学结构，粒子表面可能接枝上有机长链，提高了纳米粒子在溶剂中的相容性．表面化学修饰后的纳米氧化钛与乙二醇溶剂形成了较稳定的溶胶体系，而且纳米溶胶粒径较小．表面活性剂添加量与纳米粒子添加量控制在(1～1．2)：1时，可以获得纳米溶胶粒径较小，同时溶胶稳定性较好的纳米氧化钛-乙二醇溶胶体系．     

Atomic-scale simulation of nano-grains:structure and diffusion properties

Nanograins are characterized by a typical grain size from lto 100 nm.Mclecular dynamics aimubations have been carried out for the nanograin sphere with the diameters from 1.45 to 10.12 nm.We study the influence of grain size on structure and diffusion properties of the nanograins.The results reveal that as the grain size is reduced,the fraction of grain surface increases significantly,and the surface width is approximately constant；the diffusicn coefficlent is increased sharply,and the relation of the diffusion coefficient and the grain size is close to exponential relation below 10nm.     

蓝宝石R面上ZnO薄膜的NH3掺杂研究

以NH₃为掺杂源,利用金属有机化学气相沉积(MOCVD)系统在蓝宝石R面上生长出掺氮ZnO薄膜。通过XRD,SEM测量优化了其生长参数,在610℃和在80sccm的NH₃流量下生长出了〈1120〉单一取向的ZnO薄膜。经Hall电阻率测量,得知该薄膜呈现弱p型或高电阻率,并对其光电子能谱进行了研究。     

纳米Zr-V-O粉末的XRD及TG-DSC研究

利用机械合金化制备纳米Zr-V粉末，对制备过程的材料进行物相分析和热分析试验。初始粉末Zr（150μm）和V（150μm）元素粉末（纯度99．15％）按原子比1：2或1：1进行混合后在氩气气氛中放入SimoloyerCMol—2球磨仓中，按几种不同的试验条件进行球磨。同时在997K和1047K下热处理40min和1h，并对热处理前后的粉末进行了物相和TG-DSC实验分析。     

Raman properties embeddedof GaSb nanoparticlesin SiO2 films

The Raman shifts of nanocrystalline GaSb excited by an Ar^ ion laser at wavelengths 514.5, 496.5, 488.0, 476.5,and 457.9nm are studied by an SPEX-1403 laser Raman spectrometer respectively, and they are explained by phonon confinement, tensile stress, resonant Raman scattering and quantum size effects. The Stokes and anti-Stokes Raman spectra of GaSb nanocrystals strongly support the Raman feature of GaSb nanocrystals. The calculated optical spectra compare well with experimental data on Raman scattering GaSb nanocrystals.     

新型纳米纤维膜对地下水中重金属的过滤去除研究

采用扫描电镜表征了氯化聚氯乙烯静电纺丝纳米纤维膜的微观结构特征,并进行了去除地下水中铜、铅、镉等重金属阳离子的过滤试验,包括直接过滤、加土壤过滤、加硅藻土过滤和胶束强化过滤。结果表明,最佳的过滤工艺是胶束强化过滤,其最佳试验条件是10层膜过滤和5mmol/L的SDBS浓度,对铜、铅、镉的去除率分别超过73%,82%和91%。     

提高TiO_2光催化性能的研究进展

综述了近年来纳米TiO2光催化剂研究现状,光催化机理,及其改良的最新技术,包括对其的表征及表面改性,以提高纳米TiO2的光催化效率。