花键轴振动挤压成形试验研究

针对花键轴挤压成形制造效率低、模具所受载荷大的问题,采用了一种新的振动辅助挤压成形工艺,并进行了花键轴成形试验、微观组织分析和硬度测试,揭示了成形载荷的主要影响因素及金属流动规律。试验设备为振动挤压机床,采用模数为1.75、齿数为10的花键轴挤压模具对直径为17.9mm、材料为AISI1045A的棒料进行了振动挤压成形试验,模具每进给1mm便回程0.5mm,振动频率分别取10、15和20Hz。结果表明:相比于直接挤压,振动挤压成形过程的成形力可降低将近25%,原因是在模具回程过程中润滑油得以流入模具与坯料的接触面,重新生成油膜,从而减小了摩擦力;在试验频率范围内,成形载荷随振动频率的提高而增大;振动挤压成形花键轴具有表面质量高、成形速度快、材料流动均匀的优点,且沿轴向齿顶圆直径变化小,成形精度高;与传统的直接挤压成形相比,振动挤压成形花键轴齿型部位的硬度降低了近10%,有利于成形。     

Non-isothermal Decomposition Mechanism and Kinetics of LiClO4 in Nitrogen

The non-isothermal decomposition kinetics of LiClO4 in flow N2 atmosphere was studied.TG-DTA curves show that the decomposition proceeded through two well-defined steps below 900°C,and the mass loss was in agreement with the theoretica1 value.XRD profile demonstrates that the product of the thermal decomposition at 500°C is LiCl.For the decomposition kinetics study,the activation energies calculated with the Friedman method were considered as the initial values for non-linear regression and were used for verifying the correctness of the fitted models.The decomposition process was fitted by a two-step consecutive reaction:extended Prout-Tompkins equation[Bna,f (α) is (1?α)nα a] followed by a 1th order reaction(F1).The activation energies were (215.6±0.2) and (251.6±3.6) kJ/mol,respectively.The exponentials n and a for Bna reaction were (0.25±0.05) and (0.795±0.005),respectively.The reaction types and activation energies were in agreement with those obtained from the isothermal method,but the exponentials were optimized for better fitting and prediction.     

Estimation of Critical Temperature of Thermal Explosion for Trinitromethyl Explosives by Non-isothermal DSC

Two general expressions and their six derived formulae for estimating the critical temperature(Tb) of thermal explosion for energetic materials(EMs) were derived from the Semenov’s thermal explosion theory and eight non-isothermal kinetic equations via reasonable hypothesis. We can easily obtain the values of the initial temperature(T0i) at which DSC curve deviates from the baseline of the non-isothermal DSC curve of EMs, the onset temperature(Tei), the exothermic decomposition reaction kinetic parameters and the values of T00 and Te0 from the equation T0i or ei=T00 or e0+α1βi+α2βi2+···+αL–2βiL–2, i=1, 2, ···, L and then calculate the values of Tb by means of the six derived formulae. The results obtained with the six derived calculating methods for six trinitromethyl explosives: bis(2,2,2- trinitroethyl-N-nitro) ethylene diamine(BTNEDA), 2,2,2-trinitroethyl-4,4,4-trinitrobutyrate(TNETB), bis(2,2,2- trinitroethyl) formal(BNTF), bis(2,2,2-trinitroethyl-nitramine)(BTNNA), 2,2,2-trinitroethyl-2,2,2-trinitroethyl-N- nitroamino acetate(TNTNNA) and tetrakis [2,2,2-trinitroethyl] orthoester(TTNOE) agree well with each other.     

各类化学反应的标准平衡常数表达式

本文介绍从各类物质的化学势表达式出发,先得到各类化学反应的等温式,然后依据化学反应平衡条件和标准平衡常数的定义,系统而又完整地导出各类化学反应的标准平衡常数表达式。     

快速凝固结合严酷变形镁合金丝的组织与性能

采用快速凝固(RS)技术制备了厚度小于80μm,具有细微组织的Mg-6.0%Zn-1.0%Y-0.6%Ce-0.6%Zr合金薄带,薄带经往复挤压(RE)4道次后,制成Φ35 mm坯料,坯料被进一步正挤压(EX)成Φ2.08 mm~Φ1.55 mm表面光洁的细丝。用SEM和STEM分析组织,用In-stron 5500R和弯曲试验装置测试机械性能。细丝基体晶粒直径为~1μm。一类强化相颗粒的平均直径为0.25μm,另一类50 nm。变形态细丝抗拉强度和延伸率分别为335 MPa和13%;经过300℃保温10 min,然后水冷处理,抗拉强度和延伸率分别为403 MPa和12%。材料的临界弯曲直径为~6.28 mm,压应力是细丝弯曲断裂的控制因素。     

设计合成亚胺类化合物用于金属阳离子逻辑门识别及双控荧光分子开关构建

报道了首次设计合成希夫碱还原产物N,N-双(4-甲氧基苯)乙基-1,2-二胺受体分子L.通过考察L与12种金属阳离子作用时的荧光性质变化,发现Cu2+和Fe3+对L有显著的荧光猝灭作用,Zn2+和Cd2+对L有明显的荧光增强作用;因此可构建受体分子L对两对金属阳离子的"OR"逻辑门作用关系,形成逻辑识别体系.测定了Zn...     

惯性颗粒所见被动标量统计特性的DNS与模型研究

本文采用DNS方法,对惯性颗粒所见各向同性湍流中具有平均标量梯度的被动标量场统计特性进行了研究。结果表明：惯性对颗粒温度脉动强度,两相温度关联,自相关特性以及颗粒热流与两相交叉热流的统计特性具有明显的影响。在PDF方法的框架下,系统地推导了非等温气固两相流的PDF方程,且基于朗之万随机体系对方程进行了封闭,并利用前面的...     

ANS-OB氧枪等温流场模拟研究同轴环状伴流流场模型实验

为考察ANS-OB氧枪工作中发生烧损时的喷流特性,在等温条件下对模拟氧枪的同轴环状喷流在枪端面齐平、有30°和45°角缺损,以及环流不供气等4 种情况下实测了时均速度和紊流度分布,得出了在端面有缺损时造成环周上动量通量分布不均衡,喷流将向一侧发生偏斜;在vao/vmo等于0.14的条件下,环状伴流对喷流的总流特性仍有较大影响;喷流的紊流度在有伴流时明显增强.     

改进的条形基坑突涌判别式

将条形基坑隔水层视为匀质、连续构件，从坑底突涌的实际民政部及突涌机理出发，借助材料力学和结构力学理论，通过分析提出近似假设并建立比较符合情况的条形基坑突涌判别式，为判别突涌得供了有效、简易的计算方法。     

夏日酷装备

神秘商人来社区兜售新玩意啦!据说有了这些装备,你就能安心度过夏天。真有这么神奇?我们赶紧去瞧一瞧吧。天晒痕永衣这种泳衣的布料和普通泳衣大不相同,上面有数不清的微孔,可以让阳光穿透泳衣均匀地直射皮肤。有了它,你就不必担心游泳后皮肤上留下泳衣的痕迹了。