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971.
The Dynamic Viscoelasticity of Polyethylene Based Montmorillonite Intercalated Nanocomposites 总被引:3,自引:0,他引:3
HongMeiYANG QiangZHENG 《中国化学快报》2004,15(1):74-76
The viscoelastic behavior of melts for two systems composed of intercalated nanocomposites based on low density polyethylene and 3 wt% loading of cetyltrimethylammonium bromide modified montmorillonite was studied. The results obtained through examining the dynamic storage module G‘ and dynamic loss module G“ values of the composite revealed that the dynamic viscoelastic properties of composite strongly depended on intercalation of polymer, and exhibited dramatically change with altering intercalation conditions. Only when modified montmorillonite content was about 3 wt%, the composite showed a trend of pseudo-solidlike at lower frequencies. 相似文献
972.
NorAishahSaidinaAmin DidiDwiAnggoro 《天然气化学杂志》2002,11(1):79-86
Ethylene oligomerization using ZSM-5 zeolite was investigated to study the role of Broensted acid sites in the formation of higher hydrocarbons,The oligomeriztion of olefins,dependent on the acidity of ZSM-5 zeolite ,is an important step in the conversion of natural gas to liquied fuels,The framework Si/Al ratio reflects the number of potential acid sites and the acid strength of the ZSM-5 catalyst,ZSM-5 with the mole ratio SiO2/Al2O3 equal to 30 was dealuminated for different periods of time according to the acidic ion-exchange method to produce ZSM-5 with various Si/Al ratios,The FT-IR analysis revealed that the integrated framework aluminum band,non-framework aluminum band,and silanol groups areas of the ZSM-5 zeolites decreased after being dealuminated,The performanc of the dealuminated zeolite was tested for ethylene oligomerization.The results demonstrated that the dealumination of ZSM-5 led to higher ethylene conversion,but the gasoline selectivity was reduced compared to the performance of a ZSM-5 zeolite ,The characterization results revealed the amount of aluminum in the zeolitic framework,the crystallinity of the ZSM-5 zeolite,and the Si/Al ration affected the formation of Broensted acid sites,The number of the Broensted acid sites on the catalyst active sites is important in the olefin conversion to liquied hydrocarbons. 相似文献
973.
974.
Wei Wang Jun-xiao Yang Bin He Zhong-wei Gu 《高分子科学》2007,(5):431-435
A novel method to prepare crosslinked polyethyleneimine(CPEI)hollow nanospheres was reported.Uniform silica nanospheres were used as templates,3-aminopropyl trimethoxysilane(APS)was immobilized on the surface of silica nanospheres as couple agent.Aziridine was initiated ring-opening polymerization with the amino groups in APS to form polyethyleneimine(PEI)shell layer.1,4-Butanediol diacrylate was utilized to crosslink PEI polymeric shell.The silica nanospheres in core were etched by hydrofluoric acid to obtain hollow CPEI nanospheres.The hollow nanospheres were characterized by X-ray photoelectron spectroscopy(XPS),transmission electron microscopy(TEM),and thermogravimetric analysis(TGA). 相似文献
975.
CRYSTAL STRUCTURE OF RhCl(dppm)_2·H_2O 总被引:1,自引:0,他引:1
<正> C50H46OP4ClRh, RhCl(dppm)2 · H2O, Mr = 922. 2, monoclinic, P21/2, a=10. 532(3), b=22.574(8), c=18. 641(8) A, β=93. 41(3)°, V = 4424 (3) A3, Z = 4, Dc=1. 386 g. cm-3, λ(MoKα) = 0. 71073A , F(000) = 1904. The structure was determined by direct methods and difference Fourier syntheses and refined by full-matrix least-squares to final R = 0. 037 and Rw = 0. 036 for 3432 (F> 6. 0σ(F) ) observed reflections. The structure of the title compound contains RhCl-(dppm)2 and non-coordinated H2O molecules. The rhodium atom is coordinated by one chlorine atom and four phosphorus atoms of two DPPM ligands forming a tetragonal pyramidal configuration. 相似文献
976.
The data of solubilities, densities and refractive indices of rubidium chloride or cesium chloride in the system CEHsOH-H2O were measured by using a simple accurate analytical method at different temperatures, with mass fractions of ethanol in the range of 0 to 1.0. In all cases, the presence of ethanol significantly reduced the solubility of rubidium chloride and cesium chloride in aqueous solution. The solubilities of the saturated solutions were fitted via polynomial equations as a function of the mass fraction of ethanol. The CsC1-C2H5OH-H2O ternary system appeared in two liquid phases: alcoholic phase and water phase, when the mass fractions of ethanol were in the range of 10.37% to 49.59% at 35 ℃. Density and refractive index were also determined for the same ternary systems with varied unsaturated salt concentrations. Values for both experiment and theory were correlated with the salt concentrations and proportions of alcohol in the solutions. The equations proposed could also account for the saturated solutions. 相似文献
977.
保护剂对K2PtCl6为前体合成纳米铂形状的影响 总被引:3,自引:0,他引:3
纳米粒子的性质不仅受到尺寸的影响,还与其形状密切相关,由于铂在催化及材料等领域中有重要应用,因此化学合成特定形状的纳米铂一直备受关注,具有特定表面结构的纳米粒子对于研究催化活性与表面原子结构的关系具有重要意义,目前立方体形状纳米铂已被合成,但高比例四面体形状纳米铂的合成研究很少有报道, 相似文献
978.
979.
Zhen Gang Liu Nan Li Li Yang Zhong Li Liu Wei Yu 《中国化学快报》2007,18(4):458-460
ZrCl4/Hantzsch 1,4-dihydropyridine is a mild and highly efficient reagent combination for the direct reductive amination.Weakly basic amines such as anilines substituted by electron-withdrawing group and heteroaromatic amines can be reductivelyalkylated with electron rich aldehydes and ketones under mild conditions to form the secondary amines in excellent yields. 相似文献
980.
氯化血红素作为模拟酶荧光免疫分析乙肝表面抗原 总被引:2,自引:0,他引:2
乙肝表面抗原的测定在临床诊断上是一项很重要的指标.现在一般采用酶联吸附免疫分析技术测定,但是酶本身性质不稳定且价格昂贵、操作繁琐;更重要的是大分子的酶作为标记物,由于空间位阻效应而阻碍抗原-抗体的免疫反应.所以,用小分子催化剂代替大分子酶的研究显得日益重要[1,2].近年来有关模拟酶在免疫分析中的应用已有报道[3,4].本文提出了以氯化血红素作为辣根过氧化物酶(HRP)的模拟酶来标记抗体,以盐酸硫胺素(维生素B1)作为供氢体,成功地实现了乙肝表面抗原(HBsAg)的夹心法荧光免疫分析.测定范围是2.5~500ng/wel… 相似文献