全文获取类型
收费全文 | 15797篇 |
免费 | 1574篇 |
国内免费 | 1567篇 |
专业分类
化学 | 1775篇 |
晶体学 | 52篇 |
力学 | 697篇 |
综合类 | 185篇 |
数学 | 986篇 |
物理学 | 2564篇 |
综合类 | 12679篇 |
出版年
2024年 | 163篇 |
2023年 | 470篇 |
2022年 | 570篇 |
2021年 | 632篇 |
2020年 | 450篇 |
2019年 | 430篇 |
2018年 | 275篇 |
2017年 | 412篇 |
2016年 | 415篇 |
2015年 | 492篇 |
2014年 | 915篇 |
2013年 | 808篇 |
2012年 | 987篇 |
2011年 | 1431篇 |
2010年 | 1060篇 |
2009年 | 1124篇 |
2008年 | 1189篇 |
2007年 | 1017篇 |
2006年 | 785篇 |
2005年 | 587篇 |
2004年 | 577篇 |
2003年 | 572篇 |
2002年 | 493篇 |
2001年 | 472篇 |
2000年 | 423篇 |
1999年 | 305篇 |
1998年 | 266篇 |
1997年 | 244篇 |
1996年 | 248篇 |
1995年 | 181篇 |
1994年 | 200篇 |
1993年 | 152篇 |
1992年 | 128篇 |
1991年 | 111篇 |
1990年 | 120篇 |
1989年 | 100篇 |
1988年 | 43篇 |
1987年 | 37篇 |
1986年 | 18篇 |
1985年 | 9篇 |
1984年 | 3篇 |
1983年 | 5篇 |
1982年 | 3篇 |
1980年 | 5篇 |
1962年 | 1篇 |
1959年 | 3篇 |
1958年 | 2篇 |
1957年 | 2篇 |
1948年 | 1篇 |
1926年 | 1篇 |
排序方式: 共有10000条查询结果,搜索用时 6 毫秒
191.
提出了控制电位电解和恒电流电解两类电解沉积的压电频移分析法测定的理论公式,用实验结果验证了它的正确性. 相似文献
192.
通过自由基共聚合合成了含有高二阶非线性光学活性偶氮单元的侧链液晶共聚物。共聚物的液晶转变温度为DSC测定,实验证明当偶氮单元含量超过40mol%时,共聚物的液晶性消失。通过高压电场对该聚合物膜进行针尖电晕极化取向,并由紫外测试给出了聚合物膜的取向参数及其稳定性,对液晶聚合物的非线性光学性质进行了初步的研究。 相似文献
193.
194.
铜(II)-5-取代邻菲啰啉-二氧四胺大环三元体系的稳定性研究 总被引:1,自引:0,他引:1
The stability of copper (Ⅱ)-13-(2'-Hydroxy-3',5'-substituted benzyl)-1,4,8,11-tetraazacyclotetradecane-12, 14-dione(RTADO-14) binary complex compounds and of copper (Ⅱ)-5-substituted-1,10-phenanthrolines(R'TADO)-RTADO-14 ternary complex compounds was studied by means of pH titration method at 25.0±0.1 ℃ and I=0.1mol?dm-3KNO3. The formation constants of binary and ternary complexes were obtained. The structures of the binary and ternary complxes and the effects fo substituents on macrocyclic ligands and on R'Phen were also discussed. 相似文献
195.
The barium titano-silicate phosphors doped with Eu3+ were synthesized by high temperature solid state reaction. The structures of as-synthesized samples were characterized by powder XRD. The maximum peaks of emission spectra of Ba2TiSi2O8 and Ba2TiSi2O8∶Eu3+ were respectively located at 450 and 618 nm, coming from the transitions of charge-transfer bands of Ti4+-O2- and forced electric-dipole transition 5D0-7F2 of Eu3+. The luminous mechanisms of Ba2TiSi2O8 and Ba2TiSi2O8∶Eu3+ were suggested. The effects of concentration of Eu3+ on the luminous performance of Ba2TiSi2O8∶Eu3+ were also studied and the results showed that the optimum concentration of Eu3+ was 0.12 mol per mole of matrix. 相似文献
196.
用 p H法在 (2 5.0± 0 .1 )℃ ,I=0 .1 mol· dm-3 KNO3 条件下 ,测定 Cu( ) - 4 - (喹啉 - 8′-甲基 ) - 1 ,4,7,1 0 -四氮杂环十三烷 - 1 1 ,1 3-二酮 -α-氨基酸或 5-取代邻菲罗啉两类三元配合物的稳定常数 ;研究了带甲基喹啉侧基大环多胺配体与 Cu( )离子的配位能力、配位方式 ;发现这两类三元体系配合物有特殊的稳定性 ;而且它们的稳定性与配体α-氨基酸及 5-取代邻菲罗啉酸碱强度之间的直线自由能关系的变化趋势相反 ;探讨了 Cu( )和 5-取代邻菲罗啉之间的 d- p反馈π键及其取代基 Hammett诱导效应的关系。 相似文献
198.
199.
Equilibrium geometries of 16 possible isomers for C74(BN)2 were studied by INDO series of methods, to indicate that the most stable three geometries are those where boron and nitrogen atoms substitute carbon atoms located at the same hexagon near the longest axis of C78 (C2v) to form B-N-B-N unit. Electronic spectra of C74(BN)2 were investigated with INDO/CIS method. The reason for the red shift of UV absorptions for C74(BN)2 compared with those of C78 (C2v) was discussed. IR spectra for 9,8,28,29-C74(BN)2 and 28,29,30,31-C74(BN)2 were calculated on the basis of AM1 geometries. 相似文献
200.
稀土红色荧光粉SrZnO2∶Eu3+的发光性能 总被引:4,自引:0,他引:4
A series of novel luminescent materials, SrZnO2∶M (M=Eu3+, or Eu3+ + Li+) have been synthesized by high-temperature solid-state reaction. The structure and luminescence properties of SrZnO2∶Eu3+ phosphor were studied through XRD, photoluminescence and Raman spectroscopy. The excitation spectra show a broad intense band and a number of small peaks corresponding to the inner 4f-shell excitations of Eu3+ (the strongest one is at 395 nm for 7F0-5L6). After SrZnO2∶Eu3+ phosphor was co-doped with Li+ ions, its charge transfer band extended to longer wavelengths. This resulted in increase of luminescent quantum efficiency of the sample. SrZnO2∶Eu3+,Li+ phosphor can be efficiently excited by longer UV. From the fluorescence spectrum of SrZnO2∶Eu3+ phosphor, apart from transition emissions of 5D0→ 7FJ (J=0~4), the transition emissions from 5D1 → 7FJ (J=0~2) have been observed. For the SrZnO2∶Eu3+ phosphor, under excitation of UV, the dominant emission is at about 612 nm, due to the 5D0→ 7F2 hypersensitive transition. The incorporation of Li+ ions greatly enhanced the luminescence intensity and made emission peak from 5D0 → 7F2 transition red-shifted. 相似文献