1，4-双(1′-苯基-3′-甲基-5′-氧代吡唑-4′-基)丁二酮-(1，4)合双铜(Ⅱ)配合物的合成、表征、非等温热分解反应动力学及电化学性质

The paper reported the synthetic procedure and character of Copper(Ⅱ) binuclear coordination compound of 1,4-bis-(1′-phenyl-3′-methyl-5′-pyrazolone-4′)-1,4-butanedione. The non-isothermal kinetic of the thermal decomposition of the complex has been studied from the TG-DTG curves by means of the Achar et al and Coats-Redfern methods. The electrochemical characterization of the complex were studied by means of powder microelectrodes technique.     

The Direct Resolution of the Enantiomers of Four Chiral Pesticides

Cellulose-tris(3,5-dimethylphenylcarbamate)(CDMPC) were synthesized as highperformance liquid chromatography (HPLC) chiral stationary phase(CSP). The successful resolution of four chiral pesticides on the CSP was realized and the influence of the temperature on the separation was studied.     

纳米晶PbTiO3负载CuO催化NO分解

A large specific surface area perovskite-type mixed oxide PbTiO₃ supported cupric oxide was synthesized as a catalyst for NO decomposition and characterized by techniques such as XPS, XRD, H₂-TPR before and after NO decomposition reactions. The catalytic properties were tested with a fix-bed micro-reactor. The results showed that the PbTiO₃ was inactive for the reactions, but 1wt % Cu/PbTiO₃ catalyst gave fairly good activities for NO decomposition at temperature as low as 473 K. Copper species were found well-dispersed but weakly interacted with the support before NO decomposition, and the NO decomposition caused significant change in the environment of the copper species, which became Cu(Ⅰ) and most probably incorporated into surface crystal lattice of the nano-sized PbTiO₃. In NO reaction, a large amount of oxygen atoms from the decomposition of NO penetrated into the nano-sized PbTiO₃ support and caused small expansion of crystal lattice. The transport of oxygen between the copper species and the catalyst support may be helpful to speed up the kinetic regeneration of active metal sites from oxygen occupancy and resulted in good catalytic performance.     

基于经验模态分解特征的无线电引信抗扫频式干扰方法

针对目前调频无线电引信在复杂电磁战场环境中对抗扫频式干扰能够力弱的问题,提出一种基于经验模态分解(empirical mode decomposition,EMD)特征的无线电调频引信对抗扫频干扰的方法.对基于目标和扫频干扰作用下的调频无线电引信检波端输出信号进行EMD分解,得到10层本征模态函数(intrinsic mode function,IMF)分量,提取每层IMF分量中本征模态函数能量占比、能量聚集度和Renyi熵特征,并利用主成分分析算法对于特征进行降维,保证累积解释差异在95%以上,以降维后的特征矩阵作为支持向量机的输入对目标和扫频式干扰信号进行分类识别.实测数据结果表明,所提方法能够有效对目标和扫频式干扰信号进行分类识别,分类识别精度可以达到98.06%±0.003 8,目标检测率达到96.65%±0.003 7,虚警率为3.35%±0.003 7.     

基于LMD和SSA-SVM的电机故障诊断

针对电机故障诊断问题,尤其电机轴承方面的诊断,提出了LMD分解和麻雀搜索优化算法（SSA）优化支持向量机（SVM）的故障诊断方法。第一步采取小波降噪和LMD算法相结合去处理原始信号,经过小波降噪后的原始故障信号会去掉一部分的干扰,再分解得到原始信号的一系列PF分量,接着使用相关性分析法选择出有效的PF分量进行信号重构,重构后的故障信号再次经过LMD分解得到的PF分量求出各自的能量熵,直接用能量图展现出来。接着将各个PF分量的能量熵组成一组组特征向量输入到支持向量机的故障诊断模型里。利用麻雀搜索算法在支持向量机（SVM）对于电机故障的分类的模型上进行惩罚参数和核参数的挑选和模拟,选择最合适的参数组合建立SSA-SVM故障诊断模型进行仿真实验,通过仿真实验验证该方法的故障诊断准确率高达99.2％,与PSO-SVM和SVM故障诊断模型进行比较分析,实验证明提出来的方案有着更适合的故障识别能力,对电机故障诊断有着很好的适应性和发展性。     

基于最小二乘法的空间坐标转换的非迭代算法

利用最小二乘法讨论三维空间的坐标转换问题,先对已知数据进行中心化处理使得坐标转换化为向量形式的最小二乘线性拟合问题,进而化为矩阵形式的最小二乘问题,最后得到法方程以及最小二乘解.如果已知数据量大且维数高,可通过奇异值分解确定相应的转换参数.和现有方法比较,方法的拟合过程不需迭代,简单易行.算例结果表明,拟合结果和原文数据吻合较好.     

分裂的正则Hom-Leibniz-Rinehart代数

作为Hom-Leibniz代数胚的代数类比, 本文引入Hom-Leibniz-Rinehart代数的概念. 证明了分裂的正则Hom-Leibniz-Rinehart代数$L$写成$L=U+\sum_{\gamma}I_\gamma$, 其中$U$为极大交换子代数$H$的子空间和$I_\gamma$为$L$的理想, 若$[\gamma]\neq[d]$, 满足$[I_\gamma, I_d]=0$. 随后分别发展了分裂Hom-Leibniz-Rinehart代数的根和权的连通技术.最后研究了紧致的正则Hom-Leibniz-Rinehart代数的结构.     

关于B-凸空间及其上黎斯算子West分解

给出 Ｂａｎａｃｈ空间列｛Ｘｉ｝ｉ＝１∞的 ｌｐ乘积Ｂ－凸的特征刻划, 证明Ｂ－凸空间上的每个黎斯算子可Ｗｅｓｔ分解,即分解成一个紧算子和一个拟幂 零算子的和．     

与星（m,r）——正交的（g,f）——因子分解

设ｇ和ｆ是定义图Ｇ的顶点集Ｖ（Ｇ）上的整值函数。本文证明了如下结果：设ｒ是一个正整数,Ｇ是一个（ｍｇ＋ｍ－１,ｍｆ－ｍ＋１）—图,且ｇ（ｘ）≥ｒ－１,对ｘ∈Ｖ（Ｇ）。若Ｈ是Ｇ的一个有ｍｒ条边的星,则Ｇ有（ｇ,ｆ）—因子分解与Ｈ（ｍ,ｒ）—正交。     

算法复杂性函数等价类A[F]中的分解性定理

证明了算法复杂性函数渐近优超等价类数学结构Ａ［Ｆ］中的分解性定理。对任意非免费算法复杂性函数类［ｆ］∈Ａ［Ｆ］及正整数ｎ,存在类［ｇ１］,［ｇ２］,…,［ｇｎ］∈Ａ［Ｆ］满足［ｇｉ］〈［ｆ］（ｉ＝１,２,…,ｎ）且［ｆ］＝Ｖｉ＝１＾ｎ［ｇｉ］。