全文获取类型
收费全文 | 5639篇 |
免费 | 499篇 |
国内免费 | 894篇 |
专业分类
化学 | 4059篇 |
晶体学 | 103篇 |
力学 | 32篇 |
综合类 | 32篇 |
数学 | 248篇 |
物理学 | 1403篇 |
综合类 | 1155篇 |
出版年
2024年 | 20篇 |
2023年 | 108篇 |
2022年 | 127篇 |
2021年 | 138篇 |
2020年 | 280篇 |
2019年 | 234篇 |
2018年 | 215篇 |
2017年 | 237篇 |
2016年 | 248篇 |
2015年 | 198篇 |
2014年 | 304篇 |
2013年 | 702篇 |
2012年 | 424篇 |
2011年 | 375篇 |
2010年 | 267篇 |
2009年 | 345篇 |
2008年 | 335篇 |
2007年 | 381篇 |
2006年 | 290篇 |
2005年 | 224篇 |
2004年 | 247篇 |
2003年 | 205篇 |
2002年 | 175篇 |
2001年 | 154篇 |
2000年 | 123篇 |
1999年 | 99篇 |
1998年 | 94篇 |
1997年 | 98篇 |
1996年 | 72篇 |
1995年 | 82篇 |
1994年 | 40篇 |
1993年 | 30篇 |
1992年 | 29篇 |
1991年 | 28篇 |
1990年 | 26篇 |
1989年 | 15篇 |
1988年 | 20篇 |
1987年 | 4篇 |
1986年 | 5篇 |
1984年 | 3篇 |
1983年 | 3篇 |
1982年 | 2篇 |
1981年 | 3篇 |
1980年 | 2篇 |
1979年 | 2篇 |
1978年 | 5篇 |
1977年 | 2篇 |
1976年 | 3篇 |
1974年 | 3篇 |
1973年 | 3篇 |
排序方式: 共有7032条查询结果,搜索用时 15 毫秒
111.
利用荧光猝灭法,研究了不同温度、酸度下,Cu2+和 Fe3+与明胶的相互作用.计算了猝灭常数和结合常数.紫外光谱和显微红外光谱的测定结果表明,Cu2+、Fe3+与明胶分子中的酰胺键发生了作用.探讨了猝灭机理.计算出的热力学函数表明,在Cu2+、Fe3+与明胶的相互作用过程中熵变起主要的作用. 相似文献
112.
113.
山楂果和桑枝提取物中总黄酮含量的Fe(phen)2+3探针共振瑞利散射法测定 总被引:2,自引:0,他引:2
在pH值约为8.0的BR缓冲介质中,桑色素、槲皮素和芦丁等黄酮类物质能与Fe(phen)2+3反应形成离子缔合物,此时将引起共振瑞利散射(RRS)显著增强,最大RRS波长均位于310 nm. 在一定范围内散射强度(ΔI)与黄酮类物质的浓度成正比,据此可以建立用Fe(phen)2+3测定某些黄酮类物质的新RRS法. 对桑色素、槲皮素和芦丁的检出限(3σ/K)分别为1.25×10-7 mol/L(37.74 μg/L),1.80×10-7 mol/L(54.42 μg/L),2.72×10-7 mol/L(167.30 μg/L). 研究了反应的适宜条件和影响因素,考察了共存物质的影响. 结果表明,方法有较好的选择性.分别以芦丁和桑色素为对照品测定了中药材山楂果和桑枝中的总黄酮含量,对反应机理进行了初步探讨. 相似文献
114.
Marcel Meiland 《Tetrahedron letters》2009,50(4):469-3893
MS and 1H, 13C and 11B NMR results are presented revealing the formation of cyclic seven-membered boronate structures at trans-1,2-diol moieties of carbohydrates providing new opportunities for the activation, protection and analysis of glucopyranose-based oligomers and polymers such as cellulose or starch. ‘Coordination-induced shifts’ in 13C NMR spectra were identified for the esterification by boronic acids of carbohydrates, which can be applied for further studies. 相似文献
115.
116.
In this paper, a novel method has been established to determine levodopa with the detection system of potassium ferricyanide‐Fe(III). In the presence of potassium ferricyanide, it has been demonstrated that Fe(III) is reduced to Fe(II) by levodopa at pH 4.0. In addition, the in situ formed Fe(II) reacts with potassium ferricyanide to form soluble prussian blue (KFeIII[FeII(CN)6]). Beer's law is obeyed in the range of levodopa concentrations of 0.01–4.00 μg mL?1 at the maximal absorption wavelength of 735 nm. The linear regression equation is A = 0.0082 + 0.61365 C (μg mL?1) with a correlation coefficient of 0.9996. The detection limit (3σ/k) is 9 ng mL?1, and R.S.D. is 0.73% (n = 11). Moreover, the apparent molar absorption coefficient of indirect determination of levodopa is 1.2 × 105 Lmol?1cm?1. The parameters with regard to determination are optimized, and the reaction mechanism is discussed. This method has been successfully applied to determine levodopa in pharmaceutical, serum and urine samples. Analytical results obtained with this novel assay are satisfactory. 相似文献
117.
V.V. Politaev I.L. Shukaev V.A. Volotchaev B.S. Medvedev 《Journal of solid state chemistry》2010,183(3):684-580
A family of α-NaFeO2-type oxides NaxM(1+x)/3Sb(2−x)/3O2 (M=Ni, Co, Zn, Mg; x≈0.8 or 0.9) has been prepared by solid state reactions and characterized by powder XRD. At x=1, ordering occurs with tripling the unit cells and formula units. The powder patterns for Na3M2SbO6 (M=Ni, Co) comply with both trigonal P3112 cell and monoclinic C2/m cell. The Ni compound exhibits also a series of extremely weak reflections (I<0.3%) that need doubling of the c axis, and the final cell is C2/c, a=5.3048(3), b=9.1879(4), c=10.8356(7), β=99.390(5). These ambiguities are explained by stacking faults. The compounds absorb atmospheric moisture with c-axis expansion up to 29%. A delafossite-related superlattice Ag3Co2SbO6 has been prepared by ion exchange and refined: P3112, a=5.3842(2), c=18.6613(10). Ionic conductivity of the Na0.8Ni0.6Sb0.4O2 ceramics, 0.4 S/m at 300 °C, is greater than reported previously, presumably owing to the grain orientation produced by hot pressing. 相似文献
118.
Mudumala Veeranarayana ReddySomeshwar D. Dindulkar Yeon Tae Jeong 《Tetrahedron letters》2011,52(37):4764-4767
α-Aminophosphonates were synthesized in a simple and efficient method from the three-component condensation reaction of 5-amino 2,2-difluoro-1,3-benzodioxole, aromatic aldehydes, and diethyl phosphite by silica-supported boron trifluoride (BF3·SiO2) in ionic liquid ([bmim][HCl]) under solvent-free conditions at room temperature in good to excellent yields and short reaction times. The catalyst can be recovered and reused for several times without any significant loss of activity. It was observed that a homogeneous reaction medium proved beneficial for the yield of the reaction. 相似文献
119.
Bin Wang Zhi-Wei Miao Ru-Yu Chen 《Phosphorus, sulfur, and silicon and the related elements》2013,188(10):2739-2748
A series of naphthoquinone-fused phosphorus heterocycles was synthesized via a three-component Mannich-type reaction. 2-Chloroethoxylphosphorodichloridite was used as a phosphorus substrate to explore the structure–activity relationships of the 2-position of the heterocycles. One spiral heterocycle compound was structurally characterized by a single-crystal X-ray diffraction analysis. 相似文献
120.
Wu Tang Zhi-Hua Yu De-Qing Shi 《Phosphorus, sulfur, and silicon and the related elements》2013,188(10):2024-2029
Target compounds 3 were synthesized by the condensation of O,O-diethyl α-amino substitutedbenzyl phosphonates 1 and 4-methyl-[1,2,3]thiadiazole-5-carboxylic acid 2 in the presence of dicyclohexylcarbodiimide (DCC) as a dehydration reagent. Their structures were confirmed by spectroscopic data (IR, 1H NMR, 31P NMR, MS) and elemental analysis. The results of a preliminary bioassay (in vitro) indicated that some of the title compounds 3 possessed moderate to good herbicidal activities against dicotyledonous plants (Brassica campestris L) at the concentration of 100 mg/L, and most of these compounds exhibited higher herbicidal activities against dicotyledonous plants (Brassica campestris L) than monocotyledonous plants (Echinochloa crus-galli). Supplemental materials are available for this article. Go to the publisher's online edition of Phosphorus, Sulfur, and Silicon and the Related Elements to view the free supplemental file. 相似文献