首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   765篇
  免费   43篇
  国内免费   53篇
化学   251篇
力学   4篇
综合类   2篇
数学   71篇
物理学   79篇
综合类   454篇
  2024年   1篇
  2023年   15篇
  2022年   65篇
  2021年   65篇
  2020年   21篇
  2019年   17篇
  2018年   19篇
  2017年   22篇
  2016年   19篇
  2015年   28篇
  2014年   57篇
  2013年   41篇
  2012年   42篇
  2011年   30篇
  2010年   32篇
  2009年   34篇
  2008年   34篇
  2007年   37篇
  2006年   35篇
  2005年   30篇
  2004年   26篇
  2003年   38篇
  2002年   25篇
  2001年   12篇
  2000年   18篇
  1999年   16篇
  1998年   18篇
  1997年   10篇
  1996年   7篇
  1995年   8篇
  1994年   3篇
  1993年   6篇
  1992年   3篇
  1989年   5篇
  1988年   2篇
  1987年   1篇
  1986年   1篇
  1981年   2篇
  1980年   2篇
  1979年   10篇
  1976年   1篇
  1975年   2篇
  1974年   1篇
排序方式: 共有861条查询结果,搜索用时 15 毫秒
1.
王阳明的“心即理”思想,从本体论的角度来讲主要有两方面,即解说心与物的关系和心与理的关系,亦即“心外无物”、“心外无理”。从认识论的角度看,“心即理”的命题有着不少合理的成分;他的心学对我国近代社会的发展也有很大意义。  相似文献   
2.
心肌肥大是心肌细胞对多种刺激因素的复杂反应。心肌肥大可以分为三种:心肌的正常生长、运动诱导生理性心肌肥大和病理性心肌肥大。近年来,研究表明心肌的正常生长以及运动诱导的心肌生理性肥大,主要是通过IGF-PI3K-Akt信号通路进行信号转导。本文就IGF-PI3K-Akt信号转导通路的结构特点、调节过程作一综述。  相似文献   
3.
Lately, scientists have explored approaches to developing fluorescent and/or bioluminescent indicators to pinpoint cellular processes in single living cells. These analytical methods have become a key technology for visualizing and detecting what was otherwise unseen in live cells. The target signaling included second messengers, protein phosphorylations, protein–protein interactions, and protein localizations.  相似文献   
4.
Indole 3-acetic acid, a plant hormone auxin, regulates every aspects of plant growth and development. In the screening for specific inhibitors on auxin signaling using the transgenic Arabidopsis plant harboring the auxin-responsive reporter gene, terfestain A was found to be a novel inhibitor of auxin signaling from the culture of Streptomyces sp. F40. The structure of terfestatin A was determined to be p-terphenyl β-glucoside on the basis of spectroscopic analyses, chemical degradation, and total synthesis.  相似文献   
5.
Counterpoise-corrected potential energy surfaces of simple H-bonded systems   总被引:1,自引:0,他引:1  
Geometries and stabilization energies of various simple H-bonded complexes (water dimer, hydrogen fluoride dimer, formamide dimer, formic acid dimer) have been determined by a gradient optimization that eliminates the basis set superposition error (BSSE) by the counterpoise (CP) method in each gradient cycle as well as by the standard gradient optimization. Both optimization methods lead to different potential energy surfaces (PES). The difference depends on the theoretical level used and is larger if correlation energy is considered. Intermolecular distances from the CP-corrected PES are consistently longer, and this difference might be significant (∼0.1 ?); also angular characteristics determined from both surfaces differ significantly. Different geometries were obtained even when passing to larger basis sets (aug-cc-pVDZ). The standard optimization procedure can result in a completely wrong structure. For example, the “quasi-linear” structure of the (HF)2 (global minimum) does not exist at the standard MP2/ 6-31G** PES (where only cyclic structure was detected) and is found only at the CP-corrected PES. Stabilization energies obtained from the CP-corrected PES are always larger than these from the standard PES where the BSSE is added only a posteriori for the final optimized structure; both energies converge only when passing to a larger basis set (aug-cc-pVDZ). Received: 11 March 1998 / Accepted: 19 June 1998 / Published online: 4 September 1998 RID=" ID=" <E6>Acknowledgements.</E6> The project was supported by the Grant Agency of the Czech Republic (Grant No. 203/98/1166). RID=" ID=" <E5>Correspondence to</E5>: P. Hobza  相似文献   
6.
LnSrNiO4-λ系列复合氧化物的物化性质与对NO分解的催化性能   总被引:16,自引:3,他引:16  
用柠檬酸络合法合成了K2NiF4结构的LnSrNiO4-λ(Ln=La,Pr,Nd,Sm,Gd)系列稀土取代类钙钛石型复合氧化物催化剂,对该系列催化剂的固态物理、化学性质及其对NO分解的催化性能进行研究。结果表明,该系列复合氧化物催化剂对NO分解活性都很高,在此基础上对该系列复合氧化物中稀土元素对NO分解反应的取代效应进行了探讨。  相似文献   
7.
Molecular imprinting is a template polymerization technique that can easily provide synthetic polymers capable of molecular recognition for given target molecules. In addition to their highly specific recognition ability, we are attempting to introduce signaling functions to molecularly imprinted polymers, enabling them to respond according to specific binding events. Some of our work regarding such signaling molecularly imprinted polymers is presented here, including molecularly imprinted polymers that induce spectral shifts of target compounds because of binding. Such compounds include hydrogen-bonding-based fluorescent imprinted polymers and metalloporphyrin-based signaling molecularly imprinted polymers.  相似文献   
8.
The color of a complex number is defined as the number of vertices of the convex hull of powers of that number. This induces a coloring of the unit disk. The structure of the set of points where the color changes is investigated here. It is observed that there is a connection between this fractal set and some family of trinomial equations. Three algorithms for coloring the unit disk are described, the last one (related to the Farey sequence) arising out of a conjecture. This conjecture is formulated and proved in this presentation.  相似文献   
9.
NO的氧化是大气化学研究的重要课题.CIS-(NO)。是一氧化氮氧化过程的中间体,对其在低温基质条件下的形成和氧化过程研究前文风已作了报导.H。WhiffS等门曾用中压汞灯作为光解光源(220-320urn),研究了ets-(NO)。在Ar低温基质中的光解,产物为N。O和NZO3.CIS-(NO  相似文献   
10.
介绍了舰岸通信互连系统,阐述了不同编码方式.不同传输信令间的转换,以及互连中继系统的工作原理.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号