全文获取类型
收费全文 | 8643篇 |
免费 | 746篇 |
国内免费 | 803篇 |
专业分类
化学 | 1950篇 |
晶体学 | 50篇 |
力学 | 950篇 |
综合类 | 81篇 |
数学 | 1605篇 |
物理学 | 1168篇 |
综合类 | 4388篇 |
出版年
2024年 | 37篇 |
2023年 | 84篇 |
2022年 | 164篇 |
2021年 | 175篇 |
2020年 | 183篇 |
2019年 | 181篇 |
2018年 | 203篇 |
2017年 | 262篇 |
2016年 | 253篇 |
2015年 | 285篇 |
2014年 | 417篇 |
2013年 | 543篇 |
2012年 | 483篇 |
2011年 | 536篇 |
2010年 | 383篇 |
2009年 | 463篇 |
2008年 | 435篇 |
2007年 | 541篇 |
2006年 | 477篇 |
2005年 | 450篇 |
2004年 | 415篇 |
2003年 | 417篇 |
2002年 | 366篇 |
2001年 | 284篇 |
2000年 | 289篇 |
1999年 | 276篇 |
1998年 | 199篇 |
1997年 | 229篇 |
1996年 | 170篇 |
1995年 | 149篇 |
1994年 | 144篇 |
1993年 | 104篇 |
1992年 | 95篇 |
1991年 | 91篇 |
1990年 | 81篇 |
1989年 | 63篇 |
1988年 | 55篇 |
1987年 | 39篇 |
1986年 | 43篇 |
1985年 | 21篇 |
1984年 | 16篇 |
1983年 | 4篇 |
1982年 | 13篇 |
1981年 | 8篇 |
1980年 | 9篇 |
1979年 | 14篇 |
1978年 | 11篇 |
1977年 | 9篇 |
1976年 | 5篇 |
1972年 | 4篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
煤直接液化油中混合酚的分离研究 《燃料化学学报》2019,47(11):1298-1304
利用分子筛择形特点,对煤直接液化油中的混合酚实施高效分离。本研究选取间甲酚和对甲酚作为分离煤直接液化油馏分段混合酚的模型化合物,采用化学液相沉积法对HZSM-5吸附剂的孔口结构进行改变,分析分子筛硅铝比及颗粒粒径对模型化合物间甲酚和对甲酚吸附分离性能的影响,以获得高性能固相吸附剂,并将其应用于180-190℃馏分段混合酚分离。结果表明,当分子筛硅铝比为25、粒径为3-5 μm时,分子筛的孔口结构调节效果最优;当正硅酸乙酯的最小用量为0.2 mL/g时,固相吸附剂的吸附量为0.03 g/g,对甲酚选择性高于95%。由于外表面沉积物对吸附剂的孔口结构变化,导致对甲酚选择性的提高。进一步采用HZSM-5(1)吸附剂对真实煤直接液化油混合酚的分离中发现,苯酚和对甲酚的选择性均达到100%。 相似文献
2.
Hideaki Murasugi Dr. Shohei Kumagai Dr. Hiroaki Iguchi Prof. Dr. Masahiro Yamashita Dr. Shinya Takaishi 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(42):9885-9891
Crystal structures of a series of organic–inorganic hybrid gold iodide perovskites, formulated as A2[AuII2][AuIIII4] [A=methylammonium (MA) ( 1 ) and formamidinium (FA) ( 2 )], A′2[I3]1−x[AuII2]x[AuIIII4] [A′=imidazolium (IMD) ( 3 ), guanidinium (GUA) ( 4 ), dimethylammonium (DMA) ( 5 ), pyridinium (PY) ( 6 ), and piperizinium (PIP) ( 7 )], systematically changed depending on the cation size. In addition, triiodide (I3−) ions were partly incorporated into the AuI2− sites of 3 – 7 , whereas they were not incorporated into those of 1 and 2 . Such a difference comes from the size of the organic cation. Optical absorption spectra showed characteristic intervalence charge-transfer bands from AuI to AuIII species, and the optical band gap increased as the size of the cation became larger. 相似文献
3.
An attempt is made to find out the suitable entrainment and exit boundary conditions in laminar flow situations. Streamfunction vorticity formulation of the Navier–Stokes equations are solved by ADI method. Two‐dimensional laminar plane wall jet flow is used to test different forms of the boundary conditions. Results are compared with the experimental and similarity solution and the proper boundary condition is suggested. The Kind 1 boundary condition is recommended. It consists of zero first derivative condition for velocity variable and for streamfunction equation, mixed derivative at the entrainment and exit boundaries. Copyright © 2005 John Wiley & Sons, Ltd. 相似文献
4.
Eva Lesanska 《Applications of Mathematics》2002,47(5):411-426
The problem is to determine nonsensitiveness regions for threshold ellipsoids within a regular mixed linear model. 相似文献
5.
沈有根 《中国科学A辑(英文版)》2002,45(3):400-408
Using the membrane model which is based on brick wall model, we calculated the free energy and entropy of Garfinkle-Horne dilatonic black hole due to arbitrary spin fields. The result shows that the entropy of scalar field and the entropy of Fermionic field have similar formulas. There is only a coefficient between them. 相似文献
6.
M. Akbari A. Behzadmehr F. Shahraki 《International Journal of Heat and Fluid Flow》2008,29(2):545-556
Fully developed laminar mixed convection of a nanofluid consists of water and Al2O3 in horizontal and inclined tubes has been studied numerically. Three-dimensional elliptic governing equations have been solved to investigate the flow behaviors over a wide range of the Grashof and Reynolds numbers. Comparisons with previously published experimental and numerical works on mixed convection in a horizontal and inclined tube are performed and good agreements between the results are observed. Effects of nanoparticles concentration and tube inclinations on the hydrodynamics and thermal parameters are presented and discussed. It is shown that the nanoparticles concentration does not have significant effects on the hydrodynamics parameters. Heat transfer coefficient increases by 15% at 4 Vol.% Al2O3. Skin friction coefficient continually increases with the tube inclination, but the heat transfer coefficient reaches a maximum at the inclination angle of 45°. 相似文献
7.
本文用变换群理论对运动水平平板混合对流边界层流动的动量、能量和浓度扩散方程进行了分析,得到了与X4/(7-5n)成正比的壁面温度分布和浓度分布,同时壁面运动速度正比于X(3-n)/(7-5n)时存在相似性解.导出了相似性解方程,用四阶Runge-Kutta方法进行了计算,给出了Pr=0.72 和Sc,K1,K2,K3参数下的速度、温度和浓度分布,得出了各参数对流场、温度场的影响。 相似文献
8.
Tatsien Li 《Mathematical Methods in the Applied Sciences》2006,29(13):1543-1553
By means of a direct and constructive method based on the theory of semi‐global C2 solution, the local exact boundary observability and an implicit duality between the exact boundary controllability and the exact boundary observability are shown for 1‐D quasilinear wave equations with various boundary conditions. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献
9.
Gabriel N. Gatica Ernst P. Stephan 《Numerical Methods for Partial Differential Equations》2002,18(1):105-128
This article deals with an expanded mixed finite element formulation, based on the Hu‐Washizu principle, for a nonlinear incompressible material in the plane. We follow our related previous works and introduce both the stress and the strain tensors as further unknowns, which yields a two‐fold saddle point operator equation as the corresponding variational formulation. A slight generalization of the classical Babu?ka‐Brezzi's theory is applied to prove unique solvability of the continuous and discrete formulations, and to derive the corresponding a priori error analysis. An extension of the well‐known PEERS space is used to define an stable associated Galerkin scheme. Finally, we provide an a posteriori error analysis based on the classical Bank‐Weiser approach. © 2002 John Wiley & Sons, Inc. Numer Methods Partial Differential Eq 18: 105–128, 2002 相似文献
10.
一类新的非线性混合拟变分包含的灵敏性分析 总被引:2,自引:2,他引:0
李克俊 《四川师范大学学报(自然科学版)》2003,26(4):352-355
研究了一类新的非线性混合拟变分包含的灵敏性问题,通过使用预解算子及不动点技巧,证明了这类含参数的变分包含的解的存在唯一性及连续性,推广了近期有关文献的一些结果。 相似文献