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1.
对处于磁场中的近藤体系的闭合点环系统,其基态性质用单一杂质安德森模型哈密顿量加以研究;该哈密顿量是用平均场理论Slave—Boson技术求解。结果表明:由磁场感应的电流与系统字称和环的尺寸大小有很大关系,通过理论研究得出一些新的结论并探讨了一些相关问题。 相似文献
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Mana Ito Takashi Ishizone 《Journal of polymer science. Part A, Polymer chemistry》2006,44(16):4832-4845
Anionic polymerization of N‐methoxymethyl‐N‐isopropylacrylamide ( 1 ) was carried out with 1,1‐diphenyl‐3‐methylpentyllithium and diphenylmethyllithium, ‐potassium, and ‐cesium in THF at ?78 °C for 2 h in the presence of Et2Zn. The poly( 1 )s were quantitatively obtained and possessed the predicted molecular weights based on the feed molar ratios between monomer to initiators and narrow molecular weight distributions (Mw/Mn = 1.1). The living character of propagating carbanion of poly( 1 ) either at 0 or ?78 °C was confirmed by the quantitative efficiency of the sequential block copolymerization using N,N‐diethylacrylamide as a second monomer. The methoxymethyl group of the resulting poly( 1 ) was completely removed to give a well‐defined poly(N‐isopropylacrylamide), poly(NIPAM), via the acidic hydrolysis. The racemo diad contents in the poly(NIPAM)s could be widely changed from 15 to 83% by choosing the initiator systems for 1 . The poly(NIPAM)s obtained with Li+/Et2Zn initiator system possessed syndiotactic‐rich configurations (r = 75–83%), while either atactic (r = 50%) or isotactic poly(NIPAM) (r = 15–22%) was generated with K+/Et2Zn or Li+/LiCl initiator system, respectively. Atactic and syndiotactic poly(NIPAM)s (42 < r < 83%) were water‐soluble, whereas isotactic‐rich one (r < 31%) was insoluble in water. The cloud points of the aqueous solution of poly(NIPAM)s increased from 32 to 37 °C with the r‐contents. These indicated the significant effect of stereoregularity of the poly(NIPAM) on the water‐solubility and the cloud point in water © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 4832–4845, 2006 相似文献
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On the basis of a better analytical exploitation of acid-induced cloud point approach, a systematic study on the phase behaviour of acid aqueous solutions of anionic surfactants and factors affecting anionic surfactant-mediated extractions was performed. The anionic surfactants investigated were alkylsulphonates (ASS) with alkylchain lengths comprised between 8 and 16 carbon atoms. The critical hydrochloric acid concentration (minimal acid concentration required to separation in two liquid phases) was found to increase as alkylchain length of the anionic surfactant increased from 10 to 14. Non-acid-induced liquid-liquid phase separation was observed for sodium octanesulphonate (SOS) or sodium hexadecyl sulphonate (SHS) in the hydrochloric concentration range 0-10 M. Acid aqueous solutions of sodium decylsulphonate (SDeS) and sodium dodecylsulphonate (SDoS) separated into two liquid phases at temperatures ranging between 10 and 80 °C, while temperatures >35 °C were required for sodium tetradecylsulphonate. The influence on extraction efficiency and concentrating ability of experimental variables such as hydrophobicity and concentration of surfactant, nature and concentration of analyte, hydrochloric acid concentration, time and temperature of extraction and time of equilibration and centrifugation was examined. Advantages provided by anionic surfactant-mediated extractions over the use of non-ionic surfactants (cloud point extractions) are discussed. 相似文献
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Kanchi Suvardhan Kailasa Suresh Kumar Dasari Rekha Pantrangam Subrahmanyam Kapuvedi Kiran Bellum Jayaraj Surasura Ramanaiah Kandhukuri Janardhanam Pattium Chiranjeevi 《Mikrochimica acta》2007,157(3-4):237-244
Cloud point extraction was applied as a method for preconcentration of rhodium after formation of a complex with 2-propylpiperidine-1-carbodithioate
(2-PPC), and later determined by flame atomic absorption spectrometry using TritonX-114 as surfactant. Rhodium was complexed
with 2-PPC in an aqueous phase and kept for 15 min in a thermostatted bath at 40 °C. Separation of the two phases was accomplished
by centrifugation for 15 min at 4000 rpm. The chemical variables affecting the cloud point extraction were optimized and successfully
applied to rhodium determination in various water samples. Under optimized conditions, the preconcentration system (100 mL
sample) permitted an enhancement factor of 50. The detection limits obtained under optimal conditions was 0.052 ng mL−1. The extraction efficiency was investigated at different rhodium concentrations (7.0–42.0 μg mL−1), and good recoveries (96.42–99.14%) were obtained using this method. It has been applied to the determination of rhodium
in water and was compared with reported methods in terms of Student’s ‘t’-test and variance ratio ‘f’-test. 相似文献
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一种关系数据库中基于云模型关联规则的提取 总被引:2,自引:1,他引:2
为了发现有效的关联规则,属性在比较高的水平被范化,允许相邻属性值或者语言项的重量.这种软划分可以映射人类的想法,同时使发现的知识鲁棒.利用云模型的理论与方法求解数量关联问题,给出了一种云关联规则的定义,并提出了基于云模型理论支持度和置信度的计算方法,最后提出了一种提取算法Cloud model A.这种方法较好地软化了数量属性论域的划分边界,从而使得挖掘出的云关联规则更容易被人理解。 相似文献
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利用GMS-5 3个红外通道(2个分裂窗区通道和1个水汽通道)的亮温资料,依据各种云不同的辐射特征对其进行分类,由此识别出积雨云(Cb)、浓积云(Cg)、卷云(Ci)、积云(Cu)、中云(Cm)、密云(Dense)等6种主要云类以及雾(Fog)和晴空区域。结合安徽寿县地面观测基准站1998年6、7月份的地面观测资料,对分类结果进行了检验,得到了较为令人满意的结果,准确率接近70%。 相似文献