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1.
Hisashi Mikami 《国际流体数值方法杂志》1987,7(6):603-619
The piecewise linear method (PLM) based on time operator splitting is used to solve the unsteady compressible Euler equations describing the two-dimensional flow around and through a straight wall inlet placed stationary in a rapidly rotating supersonic flow. The PLM scheme is formulated as a Lagrangian step followed by an Eulerian remap. The inhomogeneous terms in the Euler equations written in cylindrical coordinates are first removed by Sod's method and the resulting set of equations is further reduced to two sets of one-dimensional Lagrangian equations, using time operator splitting. The numerically generated flow fields are presented for different values of the back pressure imposed at the downstream exit of the inlet nozzle. An oblique shock wave is formed in front of the almost whole portion of the inlet entrance, the incoming streamlines being deflected towards the higher pressure side after passing through the oblique shock wave and then bending down to the lower pressure side. A reverse flow appears inside the inlet nozzle owing to the recovery pressure of the incoming streams being lower than the back pressure of the inlet nozzle. 相似文献
2.
The electrode kinetic parameters of the In(III)/In(I) couple in acidic 4M bromide solution have been determined by means of the rotating disc electrode technique.
Die elektrochemisch-kinetischen Parameter des In(III)/In(I)-Redoxsystems in Bromidlösung (Kurze Mitteilung)
Zusammenfassung Die elektrochemisch-kinetischen Parameter am In(III)/In(I)-Redoxsystem wurden in saurer 4-M-Bromidlösung mittels der rotierenden Scheibenelektrode bestimmt.相似文献
3.
An experimental study on the enhancement of soft X-ray emission from a pinch plasma has been carried out by using a rotating plasma for pre-ionization. The rotating plasma is produced by a pulsed J×B cross-field discharge between coaxial electrodes, and subjected to a pinch discharge. Under an optimized discharge condition, it has been observed that UV emission of 251.6 nm (Ar III) soft X-ray intensity increases with increasing applied axial magnetic field B. At 400 G, the X-ray intensity is enhanced by a factor of 3 compared to that without the rotating plasma. It is considered that this result is due to the improved characteristics of the pre-ionization rotating plasma, which influences the uniformity and stability of subsequent pinch plasma. 相似文献
4.
This paper focuses on extracting depth information with an aperture-rotating camera. Compared with previous work, the proposed method is applicable for arbitrary rotation angle by making use of pixel registration to get pixel shift angle, and calculating the pixel shift along this angle. Besides, consumption time for shift angle is reduced by means of sampling. Compared with point-by-point method, the proposed method reduces the computation time from about 1 h to 1 min for a 15-megapixel image. Experimental results of a scene named “bottles” show that the depth value has a margin of error of 5%. Proposed method makes it possible to extract depth information with a single camera and expands the application of DSLR camera. 相似文献
5.
Pattern dynamics plays a fundamental role in biological functions from cell to organ in living systems, and the appearance of rotating waves can lead to pathological situations. Basic dynamics of rotating waves of contraction-relaxation activity under local perturbation is studied in a newly developed protoplasmic droplet of the Physarum plasmodium. A light pulse is applied by irradiating circularly a quarter of the droplet showing a single rotating wave. The oscillation pattern changes abruptly only when the irradiation is applied at a part of the droplet near the maximal contraction. The abrupt changes are as follows: the rotating wave disappears or is displaced when the irradiation area is very close to the center of the rotating wave, while new rotating waves are created when the irradiation area is far from the center of the rotating wave. These results support the hypothesis that the phase response curve has a discontinuous change (type 0 resetting) from delay to advance around the maximal contraction. The significance of the results is discussed in relation to “vulnerability” in excitable media and biological systems in general. 相似文献
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Summary The mechanism of the cathodic reduction of In(III) at gold has been studied by rotating disc and ring-disc voltammetry in highly concentrated aqueous ZnCl2 solutions. At concentration of the base electrolyte higher than 7 mol dm–3, the voltammetric curves recorded at the disc electrode split into two well-separated waves which correspond to the successive charge transfer reactions: In(III) + 2e– In(I) and In(I) + e– In. By the use of coulometric and potentiometric techniques, the formal potentials of the In(III)/In(I), In(III)/In and In(I)/In redox couples as well as the equilibrium constants of the reproportionation reaction In(III) + 2 In 3 In(I) has been determined and discussed. The kinetic parameters of the In(III)/In(I) electrode reaction have been also evaluated and discussed.
Mechanismus und Kinetik der Reduktion von In(III)-Ionen an der Goldelektrode in hochkonzentrierten wäßrigen ZnCl2-Lösungen
Zusammenfassung Es wird der Mechanismus der Reduktion von In(III)-Ionen in hochkonzentrierten ZnCl2 Lösungen mittels der Scheiben- und Ring-Scheiben-Elektrode aus Gold untersucht. Wenn die Konzentration des Grundelektrolyten 7 mol dm–3 übersteigt, verteilen sich die erhaltenen Stromspannungskurven auf zwei gut gestaltete Stufen, die den konsekutiven Durchtrittsreaktionen In(III) + 2e– In(I) und In(I) + e– In entsprechen. Aufgrund der coulometrischen und potentiometrischen Messungen werden die Formal-Standardpotentiale der In(III)/In(I)-, In(III)/In-und In(I)/In-Redoxpaare, die Gleichgewichtskonstanten der Reproportionierungsreaktion In(III) + 2 In 3 In ermittelt. Die kinetischen Parameter der Durchtrittsreaktion In(III)/In(I) werden bestimmt und diskutiert.相似文献
9.
The mediation effect of polyaniline-coated platinum electrodes on the reduction of iron(III) ions was studied by the cyclic voltammetry and rotating disk electrode methods. The rate constants of the cross reaction between iron(III) ions and polyaniline (PA) were found to depend upon the amount of PA coated on the electrode. On the basis of the rate constants the PA-coated electrode mediates the reduction of iron(III) ion efficiently and behaves as well as a metallic electrode. 相似文献
10.
The mechanism of the indium electrodeposition on gold from acidic KBr solutions has been investigated by means of the rotating ring-disc electrode technique. The measurements showed that the overall electrode reaction In(III) + 3 e In consists of two successive charge transfer steps, i.e. In(III) + 2 e In(I) and In(I) + e In, with soluble monovalent indium as an intermediate. The current efficiency for In(I) generation under steady-state conditions is 100% in the case of low disc current densities. The disproportionation of In(I) in the bulk of solution occurs in slightly acidified solutions,pH=2, in addition to the In(I) electrochemical reduction. Based on the ring current transients, it was established that the two-electron transfer step is preceded by the formation of a thin passive film of indium metal.
Untersuchung der elektrochemischen Reduktion von In(III)-Ionen an Gold in sauren Bromidlösungen mit der rotierenden Ring-Scheiben-Elektrode
Zusammenfassung Mit Hilfe der rotierenden Ring-Scheiben-Elektrode wurde der Mechanismus der kathodischen Abscheidung von Indium auf Gold in sauren KBr-Lösungen untersucht. Aus den Messungen folgt, daß die Bruttoreaktion In(III) + 3e In über zwei aufeinanderfolgende Durchtrittsreaktionen, In(III) + 2 e In(I) und In(I) + e In, mit löslichem einwertigem Indium als Zwischenprodukt abläuft. Bei kleinen Stromdichten werden die In(I)-Ionen mit 100%iger Stromausbeute erzeugt. In schwächer sauren Lösungen (pH=2) konnte außer der elektrochemischen Reduktion von In(I) zusätzlich dessen Disproportionierung innerhalb der Lösung ermittelt werden. Auf Grund der Ringstrom-Zeit-Kurven wurde auch festgestellt, daß die Bildung von einer dünnen In-Metallschicht, die ein passives Verhalten aufweist, dem Zweielektronenübergang vorangegangen ist.相似文献