亚麻织物整理剂的研究(一)

本文研究了亚麻的结构与性能的关系,介绍了研制的非离子脂肪酰胺单双酯系亚麻织物整理剂的结构,应用效果以及技术经济效益。并得出了有意义的结论。     

高支苎麻织物形态记忆整理工艺

将形态记忆聚氨酯与交联剂、柔软剂等整理剂复配后,对经液氨处理的薄型纯苎麻平布进行抗皱免烫整理,通过试验得到足够的工艺参数和织物性能的数据,运用正交试验确定最佳的形态记忆整理工艺配方及烘干、焙烘工艺条件,分析苎麻织物进行形态记忆整理的作用机制。     

大口径离轴凸非球面的加工和检测

将光学系统波像差检验技术与子孔径拼接测试技术相融合提出了凸非球面系统拼接检测方法,对该方法的原理和实现步骤进行了分析和研究,并建立了合理的子孔径拼接数学模型.依次利用计算机控制光学表面成形技术和磁流变抛光技术对一包含大口径凸非球面的离轴三反光学系统的各反射镜进行加工,并对整个系统进行装调和测试.测定光学系统各视场的波像差分布,通过综合优化子孔径拼接算法和全口径面形数据插值求解得到大口径凸非球面全口径的面形信息.结合工程实例,对一口径为292mm×183 mm的离轴非球面次镜进行了系统拼接测试和加工,其最终面形分布的均方根值为0.017λ(λ=632.8 nm).     

亚麻织物整理剂的研究(二)

本文介绍了研制新型亚麻织物整理剂的合成路线与工艺流程以及主要设备。并对其分子结构进行了分析和讨论。确定了较佳技术指标。     

纯棉水刺非织造材料单向导湿整理工艺的优化

本研究采用含氟拒水整理剂(FG-910)对纯棉水刺非织造材料进行单面整理,使之具有亲疏水双侧结构,从而获得单向导湿功能.经分析可知,影响整理结果的有四个因子:整理液浓度、单位面积使用量、烘干温度和时间以及焙烘温度和时间.对这些因子进行分析,得出最佳整理方案为:整理液浓度40g/L,单位面积使用量为10g/m2,烘干条件为110℃×3min以及焙烘条件为160℃×2min.     

Imparting durable antimicrobial properties to cotton fabrics using quaternary ammonium salts through 4-aminobenzenesulfonic acid-chloro-triazine adduct

A 4-aminobenzenesulfonic acid-chloro-triazine adduct was successfully synthesized in a laboratory scale and treated with cotton fabrics in order to increase the anionic sites and thereby % exhaustion of cationic compounds. Two Quaternary Ammonium Salts (QAS) was investigated namely, Cetylpyridinum chloride (CPC) and Benzyldimethylhexadecyl ammonium chloride (BDHAC) which are widely accepted as strong antimicrobial agents. The reaction mechanism involved in the synthesis of the reactive adduct as well its application to cotton fabric were demonstrated in detail. The effects of application parameters, namely pH, temperature and liquor ratio were examined. The reaction efficiency was determined through monitored % exhaustion of the adduct by cotton fabric. Antimicrobial activity of the treated cotton sample was studied against Staphylococcus aureus according to AATCC test method 100-1999. Results obtained show that the treated fabric shows higher antimicrobial activity compared with the untreated fabric. The results depict also that % exhaustion decreases as the pH, temperature and liquor ratio increase. Moreover, the appropriate predictable empirical models were developed using Excel solver function incorporating interaction effects of all variables to predict the % exhaustion and the satisfactory results (R² > 0.98) were obtained.     

织物的喷气脱液方法

本文从液体在多孔介质中的渗流机理入手,运用流体动力学方法,分析了织物通过高速气流通道时。纱线间液体及纱线内纤维间液体的去除过程,建立了织物喷气脱液的力学模型。在对织物脱液效果及其影响因素分析讨论的基础上,对针织物试样进行了喷气脱液效果的实际测定,其结果与理论分析基本一致。     

苎麻织物树脂整理技术研究

从DTA分析用于艺麻织物树脂整理催化体系的选择，以及防脆化剂E-4和水溶性聚氨脂WPU的应用等三个方面介绍了提高苎麻织物树脂整理效果的新方法。     

Influence of finishing oil on structure and properties of multi-filament fibers from cellulose dope in NaOH/urea aqueous solution

Cellulose multi-filament fibers have been spun successfully on a pilot plant scale, from a cellulose dope in 7 wt% NaOH/12 wt% urea aqueous solution pre-cooled to −12 °C. Coagulation was accomplished in a bath with 10 wt% H₂SO₄/12 wt% Na₂SO₄ and then 5 wt% H₂SO₄ aqueous solution. By using different finishing oil, including H₂O, 4% glycerol aqueous solution, 2% polyvinyl alcohol (PVA) aqueous solution, 2% polyethylene glycol octyl phenylether (OP) aqueous solution, mobol and 2%glycerol/1%PVA/1%OP aqueous solution (PGO), we prepared six kinds of the cellulose multi-filaments, with tensile strength of 1.7–2.1 cN/dtex. Their structure and properties were investigated with scanning electron microscope (SEM), ¹³C NMR solid state, wide-angle X-ray diffraction (WAXD) and tensile testing. The cellulose fibers treated with PGO possessed higher mechanical properties and better surface structure than others. Interestingly, although the orientation of the cellulose multi-filaments is relatively low, the tensile strength of the single-fiber was similar to that of Lyocell. It was worth noting that the dyeability of the multi-filament fibers was superior to viscose rayon.     

光谱法分析醋酸纤维素胶板用滚光油的组分

采用高温灼烧、硅胶柱层析为分离方法,用傅里叶变换红外光谱法、X射线荧光光谱法作为分析手段,结合溶解与燃烧特性,对一种醋酸纤维素胶板表面处理用滚光油进行了剖析。得到的配方组成是正三十烷（19.06%）、油酸（3.64%）、硬脂酸钠（25.30%）、三氧化二铁与α型三氧化二铝（约50%）。