缓凝砂浆螺旋输送理论研究

缓凝预应力筋包覆装置是将新型独特的缓凝材料应用于预应力混凝土体系的一种施工设备．通过对缓凝砂浆的流变性能分析，建立了螺旋输送物理模型，运用粘性流体力学的运动微分方程研究缓凝砂浆螺旋输送的速度场和流率，从而对其装置的设计和运行参数的合理选择提供了理论依据．     

Application of the essential work of fracture concept to nanostructured polymer materials

The first part of the paper deals with a critical discussion of the methodical basis of essential work of fracture (EWF) concept with respect to the specimen geometry (especially the notch depth) and application to polymers. In the second part, an in situ testing device, which combines a tensile testing machine with an optical strain-field measuring system, has successfully demonstrated possibility of characterization of fracture behaviour of polystyrene-polybutadiene block copolymers and block copolymer/homopolymer blends as examples of nanostructured polymer materials. It has been shown that knowledge of the time evolution of the strain field close to the crack tips leads to a simple verification of the basic precondition for the applicability of the EWF concept, the precondition “plastic zone coalescence-before-stable crack propagation”.     

Reaction of η5-cyclopentadienylbis(triphenylphosphine)cobalt(I) with alkadiynes. Preparation and reactions of bicyclic cobalt metallocycles and a stable trimethylsilyl-substituted mono-complexed alkadiyne. Comments on the mechanism of cobalt-catalyzed alkyne cooligomerization

Reactions of η⁵-cyclopentadienylbis(triphenylphosphine)cobalt(I) (5) with several 2,n-alkadiynes (2) were investigated. Each of these reactions leads initially to a material in which one of the acetylene functional groups is π-coordinated to cobalt; this complex then undergoes conversion to a metallocycle. In cases where the two acetylene functions are connected by three- and four-carbon bridges (2b, 2c), metallocycles formed by intramolecular reaction of two acetylene functions in the same molecule may be isolated. In cases where the acetylene functions are joined by larger or smaller bridges, the reactions are more complex, and both inter- and intramolecular metallocycles are formed. Reactions of 5 with 1,8-bis(trimethylsilyl)-1,7-octadiyne (16) gives an isolable crystalline mono-acetylene complex (17), this material is stable in the solid state but undergoes conversion to metallocycle (18) in benzene solution. The relationship of these results to the mechanism of the CpCo(CO)₂-catalyzed benzocycloalkene synthesis is discussed; it is suggested that intramolecular metallocycles are intermediates in reactions leading to benzocyclopentanes and -cyclohexenes, but intermolecular metallocycles are probably involved in reactions leading to benzocyclobutenes.     

Thermal characterization of portland cement-magnesia blends

Summary Due to growing environmental concerns and the need to use less energy-intensive building products, alternatives and improvements to Portland cement (PC) are being actively researched worldwide. Use of supplementary materials is now a common practice where PC is the predominant component of inorganic building products. This study aims to investigate the potential of magnesia (MgO), derived from a naturally occurring raw material magnesite, as a supplementary material. Results from mortar samples prepared with 10 and 20% replacements of ordinary Portland cement (OPC) by MgO are presented. DTA-TG was used to study and characterise the hydration behaviour of MgO in OPC environment after 3, 7, 14, 28, 56 and 90 days of moist curing. Microstructural and compressive strength determinations providing additional information on the influence of hydrated phases are also reported.     

PKI/CA互操作模型的应用研究

随着电子商务、电子政务、电子事务的不断发展，PKI／CA体系所带来的互操作问题制约了PKI／CA技术的应用。本文就PKI／CA互操作问题进行分析，对国内外已存在的几大互操作技术比较讨论，最后提出可行方案：混合式的树状／桥接CA模型结构。     

数字证书在学校管理中的应用

文章分析了计算机网络中的安全加密技术和数字证书体制，提出了将数字证书应用于如学生证、图书证、上机证、毕业证等的管理，并对学历证书数字化进行了分析。     

迫弹配用近炸引信杀伤能力分析

文章通过建立迫弹杀伤能力计算模型，结合靶场试验数据．时迫弹采用预制破片和近炸引信后的杀伤能力进行了深入的分析，得到了许多有益的结论。所建立的模型和得到的结论。对于正确评价产品性能．改进弹药设计以及指导部队作战都具有重要意义。     

沥青胶浆对沥青混合料高低温性能的影响

在沥青混合料设计中，对沥青胶浆在沥青混合料中的作用认识模糊，并且对沥青胶浆的作用重视不够。按照胶浆理论，将沥青胶浆作为沥青混合料构成中的重要部分，研究了粉胶比变化、纤维对沥青混合料高、低温性能的影响。研究表明，沥青混合料的性能不仅受沥青用量和填料量的影响，更重要的是受填料与沥青相对比例的影响；在沥青混合料设计时应注意结合工程实际作出相应的设计和控制；减少粉胶比，并加入适量纤维，可显著改善沥青混合料的低温柔性的低温松弛能力，同时也使沥青混合料的高温性能得到较大的提高。     

格列吡嗪控释微球的制备及体外释药性质

为研究口服药物控释微球的制备及其体外释药性质,以格列吡嗪为模型药物,采用喷雾干燥法制备具有恒速释药性质的微球.通过考察微球的收率、包封率以及体外释放特性,研究了载体材料、材料与药物比例以及药物释放环境对格列吡嗪控释微球释药性质的影响.结果表明,采用醋酸纤维素为载体材料,选用合适的配方,可制得具有零级释药动力学的格列吡嗪控释微球制剂,并且该制剂可以根据需要的条件在12 h或24 h内释放完毕.不同条件下微球的药物释放曲线线性拟合的相关系数在0.981～0.999之间.     

PMA微乳液对水泥砂浆早期强度影响

通过对聚合物聚丙烯酸甲酯(PMA)微乳液在水泥砂浆中的应用的研究，对比纯水泥砂浆的强度，发现聚合物PMA微乳液对水泥砂浆早期抗折、抗压强度影响很大，发现聚灰比为0．001时的抗折、抗压强度较普通砂浆提高40-92％，探索了丙烯酸甲酯度(MA)的聚合物微乳液掺入量对水泥胶砂强度的影响和作用机理，认为纳米级PMA微乳液颗粒均匀分散到水泥砂浆中，使水泥砂浆的孔隙率减小，孔径也减少很多且分布均匀，可以减少水泥砂浆微裂纹和缺陷。