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101.
In this study, single‐mode microwave heating was applied in epitaxial growth of b‐oriented MFI seed monolayer prepared by facile manual assembly, resulting in the formation of well‐intergrown and highly b‐oriented MFI film with few twins. It exhibited a precise molecular sieving property at a reaction temperature no higher than 100 °C within 2 hours, therefore making it possible for easy operation in an open environment. The capability for concurrent suppression of undesired out‐of‐plane twin growth and promotion of in‐plane epitaxial growth rate under mild reaction conditions was attributed to the obvious superiority of single‐mode microwave heating in comparison with conventional multi‐mode microwave heating in aspects of microwave field uniformity and intensity. Our research indicated that the single‐mode microwave heating technique could potentially be a useful tool for improving the microstructure and therefore the performance of diverse zeolite films. 相似文献
102.
A. Marcilla A. Gómez-Siurana S. Menargues 《Journal of Thermal Analysis and Calorimetry》2007,87(2):519-527
A study of the catalytic degradation of EVA
copolymers under air atmosphere has been carried out using thermogravimety
(TG). Three commercial EVA copolymers and five zeolites and related materials
catalysts have been selected. The degradation process in air atmosphere involves
four main decomposition steps (as observed in TG), being more complex than
the corresponding process in inert atmosphere. The presence of MCM-41, HY
and H-β does not seem to noticeably affect to the overall degradation
temperature, despite the temperature of maximum reaction rate for the second
decomposition step being slightly displaced towards lower temperatures. Contrarily,
the presence of HZSM-5 and HUSY zeolites seems to displace the main stage
of the oxidative degradation process towards higher temperatures. Moreover,
the relative importance of the second and third decomposition step is different
depending on the amount and the nature of the zeolite mixed with the EVA sample.
The results obtained show that the presence of the catalyst also enhances
the formation of the carbonous residue. 相似文献
103.
C4/C5烃催化裂解制低碳烯烃的研究进展 总被引:2,自引:0,他引:2
从催化剂类型、裂解工艺、催化裂解的影响因素和裂解机理4个方面对国内外C4/C5烃催化裂解制低碳烯烃的研究进行了综述。催化裂解制低碳烯烃催化剂主要采用ZSM-5分子筛系列催化剂,在此基础上发展了酸改性或水热改性高硅ZSM系列分子筛及介孔MCM-41分子筛。总结了国内外C4/C5烃的裂解工艺,认为影响催化裂解的主要因素是裂解原料、催化剂类型及工艺条件。目前,裂解机理主要是自由基与碳正离子机理相结合的机理。并简述了本课题组目前有关C4烷烃催化裂解的主要研究进展。 相似文献
104.
天然沸石在水污染控制中的应用 总被引:20,自引:0,他引:20
本文综合评述了天然沸石在水污染控制中的应用,包括去除城市废水和工业废水中的氮和磷、放射性废水中的铯和锶以及工业废水中的重金属等。 相似文献
105.
甲醇两步制芳烃反应中低碳烯烃芳构化反应稳定性优异,为分析其内在机制,制备了不同硅铝比(nSiO2/nAl2O3)及Zn负载量的ZSM-5催化剂,以丙烯芳构化为模型反应,分析ZSM-5表面酸性对低碳烯烃芳构化反应性能的影响规律,并探究反应微观特性。发现当硅铝比由150降至75时,增加的酸密度促进了烯烃氢转移芳构化过程,使芳烃选择性由31.0%增至34.4%,但丙烯直接参与的氢转移过程也被强化,使丙烷产物选择性由28.2%增至36.0%。引入Zn助剂可将部分Br?nsted酸转变为ZnLewis酸,强化烯烃脱氢芳构化过程,使芳烃选择性进一步显著增加到62.4%。丙烯芳构化过程中芳烃烷基化深度比甲醇芳构化过程低,提升总芳烃选择性的同时,也明显抑制了难溶性积碳的形成,使反应稳定性明显提升。由此得出,甲醇两步制芳烃过程中甲醇制低碳烯烃过程对甲醇的预先消耗,抑制了低碳烯烃芳构化反应芳烃产物的深度烷基化,是该反应表现出优异稳定性的重要原因。 相似文献
106.
Dr. Zhengxing Qin Dr. Georgian Melinte Prof. Jean‐Pierre Gilson Prof. Maguy Jaber Prof. Krassimir Bozhilov Dr. Philippe Boullay Dr. Svetlana Mintova Prof. Ovidiu Ersen Dr. Valentin Valtchev 《Angewandte Chemie (International ed. in English)》2016,55(48):15049-15052
Zeolites are widely used in many commercial processes, mostly as catalysts or adsorbents. Understanding their intimate structure at the nanoscale is the key to control their properties and design the best materials for their ever increasing uses. Herein, we report a new and controllable fluoride treatment for the non‐discriminate extraction of zeolite framework cations. This sheds new light on the sub‐structure of commercially relevant zeolite crystals: they are segmented along defect zones exposing numerous nanometer‐sized crystalline domains, separated by low‐angle boundaries, in what were apparent single‐crystals. The concentration, morphology, and distribution of such domains analyzed by electron tomography indicate that this is a common phenomenon in zeolites, independent of their structure and chemical composition. This is a milestone to better understand their growth mechanism and rationally design superior catalysts and adsorbents. 相似文献
107.
改性Y分子筛的酸碱性能及吸附性能的研究 总被引:2,自引:1,他引:2
吡啶、吡咯、苯、甲苯、乙苯作为探针分子,在Li+, Na+, K+, Cs+改性的Y型分子筛上进行吸附,用TPD及IR方法系统地研究了不同碱金属离子改性的Y型分子筛的酸碱性能和吸附性能的变化. 结果表明,按Li、Na、K、Cs的顺序, 随着碱金属离子半径的增大, 其L酸酸强度依次减弱,L碱的强度逐渐增强.由于改性Y型分子筛所含碱金属离子的不同,其对芳烃的吸附的强弱及吸附量的大小亦不同.随着骨架外的阳离子的半径逐渐增大,碱的强度逐渐增强,与芳烃的作用愈强烈,导致TPD脱附峰温增高及芳烃和侧链上的C-H伸缩振动谱带向低波数位移愈多.由于位阻的原因,对含同一种碱金属离子的分子筛来说,随着芳烃侧链C数的增加,芳烃的吸附量逐渐减小. 相似文献
108.
In the literature it was found that titanium oxide clusters of a few metal atoms encapsulated inside the micropores of zeolite Y exhibit large blue shifts in the Ti-O ligand-to-metal charge-transfer band as compared to non-encapsulated bulk titanium dioxide particles. This blue shift of the Ti-O absorption band is believed to have a negative effect on the photocatalytic activity of zeolite-encapsulated TiO2. We report here on circumventing this problem and increasing visible-light absorption by means of a red shift of the absorption band caused by addition of some organic molecular modifiers containing acidic OH groups that can strongly bind with titanol groups TiOH. In the studied series of zeolite-encapsulated TiO2 samples, the red shift of the optical spectrum follows the order: catechol > 4-aminobenzoic acid > benzoic acid. Also N-doping of zeolite-encapsulated TiO2 clusters by thermal treatment with urea leads to a red shift of the TiO2 absorption band that depends on the annealing and hydration conditions. By comparison to the degradation of phenol in aqueous solution, we have demonstrated that these changes in the absorption spectrum on addition of the organic modifier are also reflected in the photocatalytic activity of the samples; a greater increase in photocatalytic activity (about 30%) was observed for the additive catechol. 相似文献
109.
形貌、晶粒大小不同的ZSM-5分子筛的表征及催化性能的研究 总被引:12,自引:0,他引:12
对3种不同形貌、晶粒大小的ZSM—5分子筛催化剂进行了表征和催化性能的研究.用XRD、SEM和NH3—TPD等方法对ZSM—5分子筛进行表征,结果表明小品粒分子筛的结晶度优于大晶粒分子筛,其酸性随着晶粒的减小而增强.对于MTG反应,ZSM—5分子筛酸性、晶粒大小和晶体形貌等因素对其催化活性产生显著影响.小晶粒的ZSM—5分子筛更有利于C5 和C9 的生成,而大晶粒的ZSM—5分子筛对对二甲苯的选择性高.TG结果表明ZSM—5分子筛上积炭覆盖酸性中心是导致催化失活的主要因素. 相似文献
110.
The removal of heavy metal cations by natural zeolites 总被引:4,自引:0,他引:4
In this study, the adsorption behavior of natural (clinoptilolite) zeolites with respect to Co2+, Cu2+, Zn2+, and Mn2+ has been studied in order to consider its application to purity metal finishing wastewaters. The batch method has been employed, using metal concentrations in solution ranging from 100 to 400 mg/l. The percentage adsorption and distribution coefficients (Kd) were determined for the adsorption system as a function of sorbate concentration. In the ion exchange evaluation part of the study, it is determined that in every concentration range, adsorption ratios of clinoptilolite metal cations match to Langmuir, Freundlich, and Dubinin–Kaganer–Radushkevich (DKR) adsorption isotherm data, adding to that every cation exchange capacity metals has been calculated. It was found that the adsorption phenomena depend on charge density and hydrated ion diameter. According to the equilibrium studies, the selectivity sequence can be given as Co2+ > Cu2+ > Zn2+ > Mn2+. These results show that natural zeolites hold great potential to remove cationic heavy metal species from industrial wastewater. 相似文献