线性调频信号低旁瓣脉压窗函数的优化设计

由于线性调频(LFM)信号的幅度谱不是标准的矩形形状,常用的窗函数有时无法将脉压旁瓣降得足够低,因此提出了LFM 信号低旁瓣脉压窗函数的优化设计方法。首先,将频域窗函数的求解表示为一个最优化问题,即在保证设计窗函数下的脉压主瓣与期望主瓣的差别小于给定值的条件下,使设计窗函数下的脉压旁瓣尽可能低;然后,将问题表示为标准二阶锥规划形式并求解。仿真实例表明,设计窗的脉压旁瓣显著低于海明窗的脉压旁瓣,设计窗脉压主瓣的无约束部分有所展宽,两个窗函数下脉压信噪比相同。     

球型毫米波金属桁架天线罩研究

从球形毫米波天线罩的空间分块设计、金属桁架和连接节点设计、透波窗口设计以及安装架设方式等方面进行了详细论述,并通过一直径7 m、工作在20 GHz的金属空间桁架天线罩的设计实例和实验研究,证明文中所用方法行之有效,可推广应用于各种大型天线罩的电性能分析和选形设计。     

激光陀螺捷联惯导尺寸效应误差分析与补偿

在高动态条件下,加速度计尺寸效应已成为影响激光陀螺捷联惯导系统精度的重要误差源.文中从理论上分析了尺寸效应的产生机理,认为尺寸效应的产生是由于加速度计测量点不一致而引起,分析了激光陀螺机械抖动引起的尺寸效应误差.对加速度计组件在一般安装关系下的尺寸效应误差模型进行了推导.对于加速度计非正交安装情形,在常规静态标定模型基础上,推导了考虑尺寸效应后的动态标定模型.以导航速度为观测量,建立了加计组件尺寸效应误差补偿的一般模型方程.一系列的试验证明,尺寸效应补偿有效地提高了导航精度.     

激光陀螺用压电陶瓷材料的制备与研究

通过文献调研设计了压电陶瓷配方,使用传统固相法制备目标压电陶瓷以达到大应变要求,以应用于激光陀螺激光稳频器中,通过r(Zr)/r(Ti)系列实验可得r(Zr)/r(Ti)=46/54组成在1 180℃烧结时获得最佳的压电介电性能,即压电常数d33≈640pC/N,弹性刚度系数cE11=60.61GPa,相对介电常数εT33/ε0≈3 300,介电损耗tanδ≈1.85%,机电耦合系数kp=0.655,居里温度TC=272℃。X线衍射(XRD)分析确认相界组成为r(Zr)/r(Ti)=46/54,扫描电镜(SEM)表明烧结温度对陶瓷晶粒尺寸有显著影响,在1 180~1 200℃之间晶粒尺寸显著增大。     

高马赫飞行器迎风面与攻角对光学窗口周围流场的影响分析

为了提高高马赫飞行下光学窗口的光学性能,对比分析了基于气动光学效应三种飞行器模型不同攻角的马赫数场、密度场、温度场和压力场的流场结构及对光学性能的影响.首先, 根据飞行器与来流的迎风面,建立了三种飞行器典型模型;继而, 给出了0、5和10攻角飞行工况;然后,建立了基于Navier-Stokes方程和湍流模型的三种攻角流场分布;最后, 对比分析了宽平头体飞行器中三种攻角温度场作用下的光学系统传递函数.结果表明,马赫数场与密度场、温度场与压力场分别具有相似分布形式;相同飞行速度和攻角下,大迎风面的飞行器光学窗口周围温度与压力较小迎风面大;相同飞行器,较大攻角对应较大流场强度,攻角为0、5和10时传递函数分别为0.188,0.097和0.028.此分析结果可为高马赫飞行下光学窗口优化提供一定的理论依据.     

Search for a Steric Penultimate Effect: Copolymerization of 2,3,4-Trimethyl-3-pentyl Methacrylate with Styrene

The hindered monomer, 2,3,4-trimethyl-3-pentyl methacrylate (I), was synthesized for penultimate effect studies. Since it readily homopoiymerized (km¹¹¹≠ 0) and readily copolymerized with styrene, copolymerizations of I with styrene were carried out at 60°C in benzene with AIBN as initiator. The conversion to copolymer and the copolymer composition were determined by using GLC techniques. Composition-conversion data was analyzed by performing a computerized nonlinear least-squares fitting to the integrated form of the penultimate model equation. The experimental design included the use of optimized M¹°/M²° ratios. The penultimate reactivity ratios calculated from these data were r¹′ = 0.23, r¹′= 0.59, r² = 0.59, r²′ = 1.34. Thus, when I is the penultimate unit, a terminal styryl radical prefers to add styrene, whereas when styrene is the penultimate unit, terminal styryl radicals prefer to add I. These results constitute the best evidence for a steric penultimate effect yet available in the literature from composition-conversion studies. However, the case is not yet proved. Further studies to strengthen this conclusion are proposed.     

Polymerization of Acrylonitrile Initiated by the System Tetramethyl-2-tetrazene and p-Toluenesulfonic Acid

The polymerization of acrylonitrile (AN) initiated by tetramethyl-2-tetrazene (TMT) and p-toluenesulfonic acid (TSA) in dimethylformamide (DMF) was studied. The polymerization was confirmed to proceed through a radical mechanism. The initial rate of polymerization R was expressed by the equation: R_p = k[TMT]^0.6 [TSA]^0.46 [AN]^1.35. The overall activation energy for the polymerization was estimated as 20.7 kcal/mole. In the absence of monomer, the reaction of TMT with TSA was also studied kinetically by measuring the evolution of nitrogen. From these results and ESR measurement of the TMT/TSA system, a possible initiation mechanism is proposed.     

Synthesis of Polylactide: Effect of Dispersion of the Initiator

The ring opening polymerization of L-lactide was studied in bulk using stannous octoate as initiator. In some experiments, triphenylphosphine, a Lewis base was also used as co-initiator. The polymerization was carried out at 130°C up to 29 h. The monomer was used after recrystallizing three times with dry toluene. Experiments were carried out using a wide range of monomer to initiator ratio. The averages and distributions of molar masses of resulting PLA have been determined by means of size exclusion chromatography, SEC. It is shown that the (mode, process) procedure of dispersion of the catalyst in polymerization system affects the molar mass distribution of the product as is evidenced by the bimodality or even trimodality observed in the SEC chromatograms.     

载银sod基纳米分子筛的合成及抗菌性能

采用两步法合成了 sod 基系列分子筛(EMT、FAU、SOD),并通过离子交换法引入 Ag⁺得到载银分子筛,通过 X 射线衍射(XRD)、扫描电子显微镜(SEM)证明离子交换前后分子筛骨架结构和晶粒尺寸没有发生明显变化;通过红外光谱(IR)、热重(TG)证明制得的载银分子筛具有良好的稳定性;对获得的载银分子筛进行了Ag⁺释放实验与抗菌能力测试,考察了分子筛种类和晶粒尺寸对抗菌性能的影响。结果表明具有笼状结构的FAU与EMT分子筛因可储存更多的Ag⁺而具有更好的抗菌性能,而具有超笼结构的 FAU 分子筛抗菌性能最优。通过对比不同晶粒尺寸载银 FAU 分子筛抗菌数据发现,晶粒尺寸为 100 nm 的载银FAU分子筛因外表面丰富的抗菌活性位点以及其内部可以储存并不断释放 Ag⁺而具有最优的抗菌性能和抗菌寿命。而晶粒尺寸为10 nm的载银FAU分子筛由于晶粒尺寸较小、外比表面积大、扩散路径短,Ag⁺的释放速率最快,抗菌效率最高。