Isomorphous inclusions of silicon, aluminum, and titanium in the germanate zeolite IPC-3

The zeolite IPC-3, isomorphous with germanate zeolite ASU-16, and its silicon, aluminum, and titanium analogs, were obtained in the presence of 1,6-diaminohexane as a template. It is possible to incorporate selectively the elements in different crystallographic positions, determined by the nature of the element, particularly its valency and its coordination number with respect to oxygen. Silicon takes tetrahedral positions in the IPC-3 lattice, Al either tetrahedral or octahedral positions, and Ti octahedral positions. Small amounts of the lithium cations facilitate tetrahedral coordination and increase the Al content in IPC-3. __________ Translated from Teoreticheskaya i éksperimental’naya Khimiya, Vol. 42, No. 4, pp. 246–251, July–August, 2006.     

Efficient organic photovoltaic cells based on thiazolothiazole and benzodithiophene copolymers with π‐conjugated bridges

New donor–π–acceptor (D–π–A) type conjugated copolymers, poly[(4,8‐bis((2‐hexyldecyl)oxy)benzo[1,2‐b:4,5‐b′]dithiophene)‐alt‐(2,5‐bis(4‐octylthiophen‐2‐yl)thiazolo[5,4‐d]thiazole)] (PBDT‐tTz), and poly[(4,8‐bis((2‐hexyldecyl)oxy)benzo[1,2‐b:4,5‐b′]dithiophene)‐alt‐(2,5‐bis(6‐octylthieno[3,2‐b]thiophen‐2‐yl)thiazolo[5,4‐d]thiazole)] (PBDT‐ttTz) were synthesized and characterized with the aim of investigating their potential applicability to organic photovoltaic active materials. While copolymer PBDT‐tTz showed a zigzagged non‐linear structure by thiophene π‐bridges, PBDT‐ttTz had a linear molecular structure with thieno[3,2‐b]thiophene π‐bridges. The optical, electrochemical, morphological, and photovoltaic properties of PBDT‐tTz and PBDT‐ttTz were systematically investigated. Furthermore, bulk heterojunction photovoltaic devices were fabricated by using the synthesized polymers as p‐type donors and [6,6]‐phenyl‐C₇₁‐butyric acid methyl ester as an n‐type acceptor. PBDT‐ttTz showed a high power conversion efficiency (PCE) of 5.21% as a result of the extended conjugation arising from the thienothiophene π‐bridges and enhanced molecular ordering in the film state, while PBDT‐tTz showed a relatively lower PCE of 2.92% under AM 1.5 G illumination (100 mW/cm²). © 2018 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2018 , 56, 1978–1988     

Solid‐state drawing of β‐nucleated polypropylene: Effect of additives on drawability and mechanical properties

Isotactic polypropylene (i‐PP) can crystallize in different crystal modifications. In this article, the effect of sepiolite (one‐dimensional) and carbon black (three‐dimensional) fillers on the solid‐state drawability of i‐PP is discussed. The cross‐hatched structure of thermodynamically most stable α‐crystal phase in i‐PP does not allow for perfect chain alignment during solid‐state drawing. The β‐phase i‐PP, obtained by addition of specific nucleating agents, crystallizes in a non‐cross‐hatched spherulitic structure and allows more easy drawing. Depending on the filler type, β–α transformation takes place at different draw ratios, as was observed by in situ wide‐angle X‐ray diffraction measurements. It was observed that β‐nucleated i‐PP has a lower yield stress and can be drawn further than i‐PP crystallized in the α‐crystal phase. If added in the right amount, both carbon black and sepiolite have a reinforcing effect on PP tapes. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2014 , 52, 1071–1082     

LED微阵列投影系统设计

为满足便携式投影仪的市场需求,设计了一种基于LED微型阵列的投影系统。该系统由显示单元和投影物镜构成。采用尺寸为12 mm×9 mm的自发光LED微型阵列作为系统的显示单元,利用光学设计软件设计了投影物镜。投影物镜采用反远距光学结构,全视场角为80°,焦距为8 mm,属于强光、广角镜头。在空间频率20 lp/mm处,该物镜的调制传递函数大于0. 85,畸变小于2%,符合投影系统的设计要求。该投影系统具有体积小,结构简单,投影效果好,易加工等诸多优势,可为第三代投影技术的发展提供参考。     

基于HV9910宽电压的自适应温度高亮度频闪灯

设计了一种基于HV9910的自适应温度宽电压范围的高亮度频闪灯,其利用HV9910的宽电压特性,可在10～50 V宽电压范围内高亮度工作。结合HV9910的LD端及二极管的热敏特性,使其根据内部温度变化调节频闪能量,并利用HV9910的内部电源给微功耗的MK6A12P单片机供电,使频闪灯具有过压保护及多种模式工作的功能。     

带有高精度片上电流感应器的自适应开关频率降压型DC-DC变换器

本文提出了一种基于电流模式的PWM降压型DC-DC变换器。在高精度片上电流感应器的作用下,当负载不同时自动选择开关频率,提高了系统效率,并获得良好的瞬态响应。电流感应器采用简单的开关技术省去了复杂的运算放大器,但获得了高精度,减少了功率损耗,节省了芯片面积。此外,为了避免启动时的浪涌电流,设计了一种新型的软启动电路。芯片采用了0.5μm标准CMOS工艺,面积3.38mm2,电流感应器的精度可以达到99.5%@200mA,在5-18V的宽输入电压范围内可以输出2A的负载电流。     

静态红外地平仪大角度测量模型及误差研究

卫星姿态变化时,静态红外地平仪的成像面与地平圆之间的夹角也会随着变化,因此会造成地平圆在地平仪成像面上成像的变化,进而导致地平仪大角度测量误差增大。为解决此问题,建立了随卫星姿态变化时地平圆在静态外红地平仪成像面上的成像模型,通过STK仿真对该模型进行验证,并给出了一种基于该模型的地平仪测量误差校正的方法,为卫星姿态测量与控制提供补偿和精度保证。     

宽带射频功放晶体管非线性输出电容研究

分析了GaN(氮化镓)HEMT(高电子迁移率晶体管)非线性输出电容Cout与宽带功放效率的关系。通过建立非线性电路模型分析得出,利用Cout控制漏极端电压电流波形能减轻对谐波阻抗的精确要求,使高效率阻抗区域扩大化,从而使宽带功放匹配变为可能。选用GaN HEMT器件设计2~3 GHz频段射频功率放大器,实测结果为该放大器最高漏极效率(DE)为81.7%,功率附加效率(PAE)78.3%,功率为40.75 dBm。在1 GHz带宽内PAE也可达65%以上。实测结果验证了原理分析的可靠性,提出的方法不仅可用于宽带GaN功率放大器设计,对其他类型的微波功放设计同样有借鉴作用。     

基于双同步斩波模式的LED声控灯驱动电源设计

提出了基于双同步斩波模式的微功耗LED声控灯驱动电源设计方法。该驱动电源用一个单片机控制两个开关管分别为主电源和待机电源提供工作电流。主电源采用全波斩波工作模式为LED灯组提供工作电流;待机电源采用半波斩波工作模式,从而大幅降低了待机功耗。该驱动电源结构简单,可在50~60 Hz频率的180~250 V的宽电压范围内工作,具有恒流驱动功能和微功耗特性,且稳定可靠和较高的性价比。